The effect of cobalt content in sintered magnets of the Nd(Pr) – Dy – Fe – Co – B system on the sintering temperature, at which the density is equal to 99% of the maximum value and the coercive force H ci is the highest, is determined. The main components forming the liquid phase in sintering of the materials are determined. It is shown that the addition of (Pr, Dy)(Fe, Co)2B2 intermetallic to alloy (Pr, Dy) – (Fe1 – y Co y ) ( y ≈ 0.5) during the operation of fine milling of sintered magnets has a positive effect on the value of H ci .
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W. C. Chang, T. B. Wu, and K. S. Liu, “The influence of sintering aids on the texture and remanence of Nd – Fe – B magnet alloys,” J. Magn. Magn. Mater., 78, 283–290 (1989).
K. H. J. Buscow, “New development in hard magnetic materials,” Rep. Progr. Physics, 54(9), 1125–1149 (1991).
F. Eisenkolb, Powder Metallurgy [Russian translation], Metallurgiya, Moscow (1959), 518 p.
E. N. Kablov, A. F. Petrakov, V. P. Piskorskii, et al., “Effect of dysprosium and cobalt on the temperature dependence of magnetization and phase composition of materials of the Nd – Dy – Fe – Co – B system,” Metalloved. Term. Obrab. Met., No. 4, 3–10 (2007).
V. P. Piskorskii, G. S. Burkhanov, O. G. Ospennikova, et al., “Effect of heat treatment on the properties of nanostructured magnetically hard Pr – Dy – Fe – Co – B materials,” Metally, No. 3, 84–91 (2010).
V. P. Piskorskii, R. A. Valeev, I. S. Tereshina, et al., “Magnetic properties and phase composition of materials of the Pr – Dy – Fe – Co – B system,” Perspekt. Mater., No. 3, 16–19 (2007).
V. P. Piskorskii, R. A. Valeev, I. V. Sychev, and S. V. Stepanova, “Effect of copper on magnetic properties and phase composition of Nd – Dy – Fe – Co – B material,” Zh. Funktsion. Mater., No. 8, 313–316 (2007).
V. P. Piskorskii, R. A. Valeev, N. V. Nazarova, et al., “Effect of samarium on magnetic properties and phase composition of Nd – Dy – Fe – Co – B materials,” in: Mining Informative-Analytical Bulletin [in Russian], Izd. MGGU, Moscow (2007), pp. 185–190.
Yu. B. Kuzma and N. F. Chaban, Binary and Ternary Boron-Containing Systems [in Russian], Metallurgiya, Moscow (1990), 317 p.
N. I. Ganina, A. M. Zakharov, V. G. Olenicheva, and L. A. Petrova, Phase Diagrams of Metallic Systems Published in 1987, Issue 32 [in Russian], VINITI, Moscow (1988), 626 p.
H. H. A. Smit, R. C. Thiel, and K. H. J. Bushow, “On the crystal-field-induced magnetic anisotropy in B-substituted RCo5 compounds,” J. Phys. F: Met. Phys., 18, 295–306 (1988).
J. Fidler, Analytical microscope studies of sintered Nd – Fe – B magnets,” IEEE Trans. Magn., MAG-21(5), 1955–1957 (1985).
H. Yamamoto, S. Hirosawa, S. Fujimura, et al., “Metallographic study on Nd – Fe – Co – B magnets, IEEE Trans. Magn., MAG-23(5), 2100–2102 (1987).
S. Arai, T. Shibata, N. Koshizuka, and M. Nagakura, “Magnetic properties and microstructure of (Nd, Dy) – (Fe, Co) – B system magnets,” IEEE Trans. Magn., MAG-23(5), 2299–2301 (1987).
S. Arai and T. Shibata, “Highly heat-resistant Nd – Fe – Co – B system permanent magnets,” IEEE Trans. Magn., MAG-21(5), 1952–1954 (1985).
S. Z. Zhou, C. Guo, and Q. Hu, “Magnetic properties and microstructure of iron-based rare-earth magnets with low-temperature coefficients,” J. Appl. Phys., 63(8), 3327–3329 (1988).
E. A. Ferreira, S. C. Silva, E. A. Péerigo, et al., “Microstructure and magnetic properties of PrFeCoBNb sintered magnets produced from HD and HDDR powders,” in: Sixth Int. Latin-American Conf. on Powder Technology, Nov. 07 – 10, 2007, Búzios – Rio de Janeiro, Brazil (2007), pp. 232–237.
V. P. Piskorskii, R. A. Valeev, I. V. Sychev, and E. B. Chabina, “Westendorf effect on Nd – Dy – Fe – Co – B magnets,” in: Mining Informative-Analytical Bulletin [in Russian], Izd. MGGU, Moscow (2005), pp. 362–368.
G. Schneider, E. Henig, F. Missel, and G. Petzow, “Microstructure of sintered Fe – Nd – B magnets,” Z. Metallkunde, 81(5), 322–329 (1990).
R. N. Faria, B. E. Davies, D. N. Brown, and I. R. Harris, “Microstructural and magnetic studies of cast and annealed Nd and PrFeCoBZr alloys and HDDR materials,” J. Alloys Comp., 296, 223–228 (2000).
Yi Chen, Jingkui Liang, Xiaoling Chen, and Quanlin Liu, “Phase equilibria in the ternary system Pr – Co – B,” J. Alloys Comp., 289, 96–98 (1999).
M. Sagawa, S. Fujimura, N. Togawa, et al., “New material for permanent magnets on a base of Nd and Fe,” J. Appl. Phys., 55(6), 2083–2087 (1984).
M. G. Talor, B. E. Davies, and I. R. Harris, “A comparative study of the sintering behavior of NdFeB and PrFeB for permanent magnet applications,” J. Magn. Magn. Mater., 242–245, 1375–1377 (2002).
V. P. Piskorskii, R. A. Valeev, A. V. Buzenkov, et al., “Effect of high concentrations of cobalt on the properties of Pr – Dy – Fe – Co – B magnets,” Perspekt. Mater., Special Issue (March), 268–271 (2008).
J. Fidler, T. Schrefl, S. Sasaki, and D. Suess, in: Proc. 11th Int. Symp. on Magnetic Anisotropy and Coercivity of Rare Earth Transition Metal Alloys, Sendai, Japan (2000), pp. S45–S54.
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Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 7, pp. 3 – 9, July, 2012.
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Petrakov, A.F., Piskorskii, V.P., Burkhanov, G.S. et al. Special features of Nd(Pr) – Dy – Fe – Co – B magnets with high content of Co. Met Sci Heat Treat 54, 323–329 (2012). https://doi.org/10.1007/s11041-012-9506-3
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DOI: https://doi.org/10.1007/s11041-012-9506-3