Abstract
The need for developing metrological support for the measurement of gas components in metals and alloys and trace impurities in various industrial products (metallurgy, medicine, etc.) is analyzed. The authors examine the needs of industries for the development of more sensitive measurement methods and procedures, as well as an expanded nomenclature of reference materials having a lower error (uncertainty) of the certified characteristic than the certified characteristic error of currently existing type-approved composition reference materials. Reference materials developed for use in state regulation should be traceable to the primary standards of mass (molar) fraction and mass (molar) concentration: GET 196-2023 State Primary Standard for the units of the mass (molar) fraction and mass (molar) concentration of components in liquid and solid substances and materials based on spectral methods; GET 176-2019 State Primary Standard for the units of mass (molar, atomic) fraction and mass (molar) concentration of components in liquid and solid substances and materials based on coulometry; GET 217-2018 State Primary Standard for the units of mass fraction and mass (molar) concentration of inorganic components in aqueous solutions based on gravimetric and spectral methods; GET 208-2019 State Primary Standard for the units of mass (molar) fraction and mass (molar) concentration of organic components in liquid and solid substances and materials based on liquid and gas chromatography-mass spectrometry with isotope dilution and gravimetry.
The need for and ways of developing and creating a metrological support system for Raman spectrometry in the Russian Federation are analyzed, including to confirm the traceability of units for quantitative Raman analysis. To address these issues, GET 196-2023 includes sulfur, carbon, and hydrogen analyzers; an inductively coupled plasma mass spectrometer; and a Raman system. The composition and metrological characteristics of GET 196-2023 are presented. In addition, a draft state hierarchy scheme for instruments measuring mass (molar) fraction and mass (molar) concentration, as well as fluorescence, of components in liquid and solid substances and materials based on spectral methods has been developed and presented. The draft state verification scheme establishes the procedure and methods for transferring the units of the mass (molar) fraction (in absolute units) and mass (molar) concentration of components (grams per cubic decimeter; mole per cubic decimeter) from GET 196-2023 to measuring instruments with indication of measurement error and uncertainty. Also, secondary and working standards are used to transfer relative fluorescence units to measuring instruments.
Similar content being viewed by others
Notes
Arshin. Available at: https://fgis.gost.ru/fundmetrology/registry (accessed 07/19/2023).
Order of the Federal Agency for Technical Regulation and Metrology No. 605 of March 21, 2023 “On approval of the State Primary Standard for the units of the mass (molar) fraction and mass (molar) concentration of components in liquid and solid substances and materials based on spectral methods.”.
References
A. V. Sobina, G. I. Terentyev, A. Yu. Shimolin, and V. M. Zyskin, Al’m. Sovr. Metrol., No. 2(14), 26–34 (2018).
Dobrovolskiy, V.I., Oganyan, N.G., Prokunin, S.V.: Ref. Mater., 14. No 3–4, 51–56 (2018). https://doi.org/10.20915/2077-1177-2018-14-3-4-51-56
Dobrovol’skii, V.I., Stakheev, A.A., Stolboushkina, T.P.: Meas. Tech. 61(11), 1041–1044 (2019). https://doi.org/10.1007/s11018-019-01546-9
Shokhina, O.S.: M. Yu. Medvedevskikh M. P. Krasheninina S. G. Makarova A. I. Krylovb I. Yu. Tkachenkob A. Yu. Mikheeva ref. Mater. 13(1), 9–26 (2017). https://doi.org/10.20915/2077-1177-2017-13-1-9-26
N. P. Muravskaya, A. V. Ivanov, Ya. I. Ermakova, and I. N. Zyablikova, in: Proc. II International Scientific Conference “Reference Materials in Measurement and Technology” [in Russian], Yekaterinburg, Russia, September 14–18, 2015; Ural Scientific Research Institute of Metrology Publ., Yekaterinburg (2015); p. 46.
Chugunova, M.M., Gryazskikh, N.Y., Zyablikova, I.N., Ivanov, A.V., Shоbina, A.N.: Meas. Stand. Ref. Mater. 17(3), 35–44 (2021). https://doi.org/10.20915/2687-0886-2021-17-3-35-44
Ermakova, I.I., Ivanov, A.V., Zyablikova, I.N., Shobina, A.N.: Ref. Mater. 15(3), 23–32 (2019). https://doi.org/10.20915/2077-1177-2018-15-3-23-32
M. M. Chugunova, N. Yu. Gryazskikh, I. N. Zyablikova, A. V. Ivanov, and A. N. Shobina, In: S. V. Medvedevskikh, E. P. Sobina, O. N. Kremleva, and M. V. Okrepilov (eds.), Reference Materials in Measurement and Technology. RMMT, Springer, Cham. (2020); pp. 29–38. https://doi.org/10.1007/978-3-031-06285-8_3
Wasserman, A.M.: Opredelenie Gazov v Metallakh [Determination of Gases in Metals; in Russian. Nauka, Publ., Moscow (1976)
Fromm, E.: Gazy i Uglerod v Metallakh [Gases and Carbon in Metals; in Russian. Metallurgiya Publ, Moscow (1980)
S. B. Shubina, in: Abstracts of Papers XIV Ural Conference on Spectroscopy [in Russian], Zarechny, Russia, September 14–16, 1999; Association “Uralanalit” Publ., Zarechny (1999).
Safonova, E.A.: Practical experience of application of the hydrogen analyzer EMGA-621W ‘HORIBA’ for the analysis of copper rolled wire in ‘ELKAT’ ltd. Anal. Control 11(1), 59–60 (2007)
“Hydrogen in solid samples. Analytical methodology HORIBA JOBIN YVON,” Anal. Control, 11, No. 1, 52–58 (2007).
Yu, A.: Karpov and I. P. Alimarin. J. Anal. Chem. 34(7), 1402–1410 (1979)
Yu. A. Karpov, V. B. Baranovskaya, and M. N. Filippov, in: Abstracts of the XV Conference “High-Purity Substances and Materials. Receipt, Analysis, Application” [in Russian], Nizhny Novgorod, May 28–31, 2018; р. 6.
Mosichev, V.I., Kalinkin, I.P., Nikolaev, G.I.: Metally i Splavy. Analiz i Issledovanie. Analiticheskij Kontrol’ Sostava Materialov Chernoj i Cvetnoj Metallurgii [Metals and Alloys. Analysis and Research. Analytical Control of the Composition of Ferrous and Non-ferrous Metallurgy Materials; in Russian. Professional Publ, St. Petersburg (2007)
Zinina, O.T.: Selected Issues of Forensic. No, vol. 4. Medical, Examination, pp. 99–105 (2001)
B. L. Batista, Ja. L. Rodrigues, Ju. A. Nunes, V. C. de Oliveira Souza, and Jr. F. Barbosa, Anal. Chim. Acta, 639, No. 1–2, pp. 13–18 (2009). https://doi.org/10.1016/j.aca.2009.03.016
Kira, C.S., Sakuma, A.M., Gouveia, N.: J. Appl. Pharm. Sci. 4(5), 39–45 (2014). https://doi.org/10.7324/JAPS.2014.40507
Tarnowski, C.P., Ignelzi Jr., M.A., Morris, M.D.: J. Bone Miner. RES 17(6), 1118–1126 (2002). https://doi.org/10.1359/jbmr.2002.17.6.1118
Belozertsev, A.I., Cheremisina, O.V., El-Salim, S.Z., Manoilov, V.V.: Nauch. Priborostr., 27. No 2, 47–56 (2017). https://doi.org/10.18358/np-27-2-i4756
Tobias, R.S., Koningstain, I.A., Mortensen, O.S., et al.: Primenenie Spektrov Kombinatsionnogo Rasseyaniya [Application of Raman Scattering Spectra (The Raman Effect). In: Anderson, A., Petrov, K.I., Publ, M. (eds.) Russian Moscow (1977)
Loudon, R.: Adv Phys 13(52), 423–482 (1964). https://doi.org/10.1080/00018736400101051
S. I. Isaenko, in: Proc. 17th Scientific Conference of Institute of Geology Komi NC UrO RAS “Structure, Substance, History of the Lithosphere of the Timan-North Ural Segment” [in Russian], Syktyvkar, December 10–12, 2008; Geoprint Publ., Syktyvkar (2008); pp. 116–118.
Kiseleva, D.V.: Yearbook-2009, Tr. IGG UrO. RAS (157), 332–335 (2010)
Huang, N., Short, M., Zhao, J., Wang, H., Lui, H., Korbelik, M., Zeng, H.: Opt. Express 19(23), 22892–22909 (2011). https://doi.org/10.1364/OE.19.022892
Kalasinsky, K.S., Hadfield, T., Shea, A.A., Kalasinsky, V.F., Nelson, M.P.: Ja. Neiss A. J. Drauch G. S. Vanni P. J. Treado anal. Chem. 79, 2658–2673 (2007). https://doi.org/10.1021/ac0700575
A. A. Lykina, D. N. Artemyev, V. Kukushkin, I. A. Bratchenko, N. S. Alexandrov, and V. P. Zakharov, in: IV International Conference and Youth School “Information Technologies and Nanotechnologies” [in Russian], Samara, April 24–27, 2018; Enterprise “New Technology” Publ., Samara (2018); рp. 233–238.
Wang, J., Zhao, X., Li, D., Wen, Y., Wang, W., Wang, B., Xu, X., Bai, H., Liu, W.: Appl. Sci., 12. No 6, 3111 (2022). https://doi.org/10.3390/app12063111
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare no conflict of interest.
Additional information
Translated from Izmeritel’naya Tekhnika, Vol. 66, No. 8, pp. 4–11, August 2023. Russian DOI: https://doi.org/10.32446/0368-1025it.2023-8-4-11
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Original article submitted 06/13/2023. Accepted 08/04/2023
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Ivanov, A.V., Gryazskikh, N.Y., Chugunova, M.M. et al. GET 196-2023 State Primary Standard for the units of the mass (molar) fraction and mass (molar) concentration of components in liquid and solid substances and materials based on spectral methods. Meas Tech 66, 543–552 (2023). https://doi.org/10.1007/s11018-023-02266-x
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11018-023-02266-x
Keywords
- Measurement standard
- Spectral methods
- Raman spectrometry
- Mass spectrometry
- Fluorescence
- Gas components
- Mass (molar) fraction
- Concentration