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Measurement of Carbon-Nanotube Adsorption of Energy-Carrier Gases for Alternative Energy Systems

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Measurement Techniques Aims and scope

We have developed a measurement technique and describe a test bench for experimental gravimetric study of the adsorption of energy-carrier gases at pressures of up to 0.15 MPa and temperatures of 77–670 K on CNT/C7H8 supramolecular structures based on carbon nanotubes and toluene molecules. We show that at pressure 0.1 MPa and temperatures of 273 and 178 K adsorption of methane is approximately 1.5 times higher on CNT/C7H8 structures than on pure carbon nanotubes.

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References

  1. I. Men’shchikov, A. Fomkin, A. Y. Tsivadze, et al., “Adsorption accumulation of natural gas based on microporous carbon adsorbents of different origin,” Adsorption, 23, 327–339 (2017).

    Article  Google Scholar 

  2. M. M. Dubinin, Adsorption and Porosity, Izd. VAKhZ, Moscow (1972).

    Google Scholar 

  3. T. A. Makal, J.-R. Li, W. Lu, and H.-C. Zhou, “Methane storage in advanced porous materials,” Chem. Soc. Rev., 41, 7761–7779 (2012).

    Article  Google Scholar 

  4. S. J. Mahdizadeh and S. F. Tayyari, “Influence of temperature, pressure, nanotube’s diameter and intertube distance on methane adsorption in homogeneous armchair open-ended SWCNT triangular arrays,” Theor. Chem. Acc., 128, 231–240 (2011).

    Article  Google Scholar 

  5. A. V. Shkolin, A. A. Fomkin, E. M. Strizhenov, and A. L. Pulin, “Adsorption of methane on model adsorbents formed from single-wall carbon nanotubes,” Fizikokhim. Pov. Zash. Mater., 50, 279–286 (2014).

    Google Scholar 

  6. A. Herbst and P. Harting, “Thermodynamic description of excess isotherms in high-pressure adsorption of methane, argon and nitrogen,” Adsorption, 8, 111–123 (2002).

    Article  Google Scholar 

  7. F. Dreisbach, H. Lösch, and P. Harting, “Highest pressure adsorption equilibria data: measurement with magnetic suspension balance and analysis with a new adsorbent/adsorbate-volume,” Adsorption, 8, 95–109 (2002).

    Article  Google Scholar 

  8. A. A. Fomkin and V. V. Serpinskii, “Study of adsorption of chlorotrifluoromethane on zeolite NaX in a broad range of pressures and temperatures,” Izv. AN SSSR. Ser. Khim., No. 9, 2108–2110 (1974).

  9. A. V. Shkolin and A. A. Fomkin, “Self-organization of supramolecular microporous structures based on carbon nanotubes and benzene,” Kolloid. Zh., 78, 800–807 (2016).

    Google Scholar 

  10. A. V. Shkolin and A. A. Fomkin, “Supramolecular microporous structures based on carbon nanotubes and coordinating cumene (C9H12) molecules,” Kolloid. Zh., 79, No. 5, 137–143 (2017).

    Google Scholar 

  11. N. B. Vargaftik, Tables on the Thermophysical Properties of Liquids and Gases [Russian translation], Nauka, Moscow (1972).

    Google Scholar 

  12. A. V. Kiselev and V. P. Dreving, Experimental Methods in Adsorption and Molecular Chromatography, Izd. MGU, Moscow (1973).

    Google Scholar 

  13. P. Malbrunot, D. Vidal, J. Vermesse, et al., “Adsorbent helium density measurement and its effect on adsorption isotherms at high pressure,” Langmuir, No. 13, 539–544 (1997).

  14. GOST R 54500.3–2011/ISO/MEK 98-3:2008, Guide to the Expression of Uncertainty in Measurement. Pt. 3. Uncertainty in Measurement.

  15. A. V. Shkolin and A. A. Fomkin, “Deformation of AUK microporous carbon adsorbent induced by methane adsorption,” Kolloid. Zh., 71, No. 1, 116–121 (2009).

    Google Scholar 

  16. A. A. Fomkin, “Adsorption of gases, vapors and liquids by microporous adsorbents,” Adsorption, 11, No. 3–4, 425–436 (2005).

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Correspondence to A. V. Shkolin.

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Translated from Izmeritel’naya Tekhnika No. 4, pp. 56–62, April, 2018.

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Shkolin, A.V., Fomkin, A.A. Measurement of Carbon-Nanotube Adsorption of Energy-Carrier Gases for Alternative Energy Systems. Meas Tech 61, 395–401 (2018). https://doi.org/10.1007/s11018-018-1440-3

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  • DOI: https://doi.org/10.1007/s11018-018-1440-3

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