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Measurement methods and problems in the reproduction of mass concentrations of total and free chlorine in natural and industrial water media

  • Physicochemical Measurements
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Measurement Techniques Aims and scope

Industrial and other sites, in which the mass concentration of total and free active chlorine must be monitored in natural and industrial water media, are indicated. The creation of reference working standards reproducing the size of the mass concentration unit of total and free chlorine is needed for assurance of measurement uniformity. Features of measurement methods and the reproduction of this unit are examined.

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References

  1. K. A. Smirnov, Molecular Theory of Solutions in Russian], Khimiya, Leningrad (1987).

    Google Scholar 

  2. A. Yu. Namiot, Handbook on the Solubility of Gases in Water [in Russian], Neftegasodobycha, Geokhimiya, Nedra, Moscow (1991).

    Google Scholar 

  3. MI 3238-2009, GSI. State Control Scheme for Means of Measurement of the Content of Components in Liquid and Solid Substances and Materials.

  4. GOST 26841-86, Pressurized Water-Chemical Operation of Atomic Power Stations with Large Scale Boiling Water Reactors. Norms for the Quality of the Main Contour Water Heat Carrier and Means for Providing Control and Protection for the System Contour.

  5. GOST 26280-84, Operation of Atomic Power Stations with Large Scale Boiling Water Reactors. Indices of the Water Quality in Auxiliary Systems.

  6. L. M. Zhivilova and Yu. A. Slobodskaya, “Automatic analyzers for indices of pressurized chemical reactor steam units and thermal power station water effluents,” Novoe Ross. Energ., No. 8, 34–48 (2008).

  7. Federal Law of March 30, 1999, No. 52-FZ, On Sanitary-Epidemiological Well-Being of the Population.

  8. Statute on State Sanitation-Epidemiological Normalization, confirmed by the Russian Federation Government July 24, 2000.

  9. SanPiN 2.1.4.1074-01, Drinking Water. Hygiene Requirements for the Water Quality in Centralized Drinking Water Supply Systems. Quality Monitoring.

  10. SanPiN 2.1.2.1188-03, Swimming Pools. Hygiene Requirements for Construction, Operation, and Water Quality. Quality Monitoring.

  11. SanPiN 2.1.5.980-00, Water Removal in Populated Areas, Sanitation Protection of Water Installations. Hygiene Requirements for the Protection of Surface Water.

  12. SanPiN 2.3.2.1280-02, Hygiene Requirements for Safety and Nutritional Value in Food Production.

  13. V. M. Bakhir, “Disinfection of drinking water: problems and solutions,” Pityevaya Voda, No. 1, 13–20 (2003).

  14. GSO 7106-94, Potassium Iodate. Active Chlorine Content Simulator.

  15. A. A. Ukolov, O. V. Karpov, and L. N. Bryanskii, “High-precision device for reproduction of the concentration unit for oxygen dissolved in water,” Izmer. Tekhn., No. 6, 62–63 (2009); Measur. Techn., 52, No. 6, 676–678 (2009).

  16. N. S. Frumina, N. F. Lisenko, and M. A. Chernova, Analytical Chemistry of Elements. Chlorine [in Russian], Nauka, Moscow (1983).

  17. L. M. Yakimenko, Manufacture of Chlorine, Caustic Soda and Inorganic Chlorine Products [in Russian], Khimiya, Moscow (1974), pp. 309–325.

    Google Scholar 

  18. G. V. Yagov, “Monitoring of residual active chlorine in drinking water,” Voda: Khim. Ekolog., No. 5, 30–36 (2010).

  19. ISO 7393-2:1985, Water Quality. Determination of Free Chlorine and Total Chlorine. Part 2: Colorimetric Method Using N,N-Diethyl-1,4-Phenylenediamine, for Routine Control Purposes.

  20. ISO 7393-3:2000, Water Quality. Determination of Free Chlorine and Total Chlorine. Part 3: Iodometric Titration Method for the Determination of Total Chlorine.

  21. GOST 18190-72, Drinking Water. Methods for the Determination of Residual Active Chlorine.

  22. MUK 4.1.965-99, Determination of the Concentration of Residual Free Chlorine in Drinking and Fresh Natural Water by a Chemiluminescence Method.

  23. Danial L. Harp, Current Technology of Chlorine Analysis for Water and Wastewater, Hach Company, USA (2002).

  24. GOST 6709-72, Distilled Water.

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Authors and Affiliations

  1. All-Russia Research Institute of Physicotechnical and Radio Measurements (VNIIFTRI), Mendeleevo, Russia

    O. V. Karpov, A. A. Ukolov & A. R. Garafutdinov

Authors
  1. O. V. Karpov
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  2. A. A. Ukolov
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  3. A. R. Garafutdinov
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Corresponding author

Correspondence to O. V. Karpov.

Additional information

Here we offer our readers a continuation of a selection of articles on the occasion of the UN International Year of Chemistry, under the slogan “Chemistry – our life, our future.” (For the start of this series see Measurement Techniques, Nos. 9 and 10, 2011.)

Translated from Izmeritel’naya Tekhnika, No. 11, pp. 51–55, November, 2011.

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Karpov, O.V., Ukolov, A.A. & Garafutdinov, A.R. Measurement methods and problems in the reproduction of mass concentrations of total and free chlorine in natural and industrial water media. Meas Tech 54, 1291–1297 (2012). https://doi.org/10.1007/s11018-012-9879-0

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  • DOI: https://doi.org/10.1007/s11018-012-9879-0

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