A method is proposed for evaluating nanoparticle dimensions based on the difference in atomization kinetics for true and colloidal solutions in graphite furnaces of atomic-absorption spectrometers. The method makes it possible not only to analyze the elemental composition of colloidal nanoparticles, but also to determine their dimensions. It is proven for spherical colloidal gold particles.
Similar content being viewed by others
References
NIST, Chemical Characterization of Nanoparticles (2009), www.nist.gov/cstl/analytical/organic/chemcharnano.cfm, accessed May 10, 2011.
A. D. Levin and Yu. M. Sadagov, RF Patent 2395796, “Method for estimating nanoparticle size in liquid media during analysis of their elemental composition,” Izobret. Polez. Modeli, No. 21 (2009).
A. D. Levin et al., “Problems of procedure support of biomedical nanotechnologies,” Measur. Techn., 53, No. 8, 869–877 (2010).
B. V. Lvov, “Interpretation of atomization mechanisms in electrothermal atomic spectrometry by the analysis of absolute rates of the process,” Spectrochim. Acta, Part B, 52, 1–23 (1997).
Yu. M. Sadagov, E. M. Rukin, and M. A. Karabegov, “Electrothermal atomic absorption spectrometry: from cells to rapid heating furnaces with ballast,” Metrologiya, No. 9, 25–45 (2007).
C. L. Chakrabartdi et al., “Atomization efficiency of a graphite furnace in atomic absorption spectrometry at high heating rates,” Canad. J. Chem, 65, 1079–1085 (1987).
Yu. V. Rogulskii, A. N. Bugai, and A. N. Kulik, “Effect of graphite furnace surface porosity on sample atomization,” Zh. Prikl. Spektrosk., 71, No. 2, 259–263 (2004).
A. N. Bugai, Yu. V. Rogulskii, and A. N. Kulik, “Kinetic model for access of free atoms in an electrothermal atomizer,” Zh. Prikl. Spektrosk., 72, No. 2, 241–246 (2005).
The work was carried out with financial support from the Federal Agency for Technical Regulation and Metrology.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Izmeritel’naya Tekhnika, No. 10, pp. 55–57, October, 2011.
Rights and permissions
About this article
Cite this article
Levin, A.D., Sadagov, Y.M. & Koroli, L.L. Determination of nanoparticle dimensions in colloidal solutions with elemental analysis in an electrothermal atomic-absorption spectrometer. Meas Tech 54, 1186–1190 (2012). https://doi.org/10.1007/s11018-012-9869-2
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11018-012-9869-2