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Inhibition of Carbon Steel Corrosion by Polyvinylpyrrolidone in Chloride-Acetate Solution and in Model Stratal Water

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The influence of polyvinylpyrrolidone (PVP) with molecular mass of 12 600 and 28 000 at concentrations of 0.2; 0.5 and 1.0 g/dm3 on the corrosion rate of 20 steel in the chloride-acetate solution and in the model stratal water was investigated by gravimetric and electrochemical methods. Under dynamic conditions maximum inhibition of the steel corrosion rate was observed at a PVP concentration of 0.5 g/dm3 in both environments. A further increase in inhibitor concentration to 1.0 g/dm3 reduces the degree of protection more significantly in chloride-acetate solution than in the stratal water. The PVP with a higher molecular mass reveals higher protective properties, which is typical of polymers capable of adsorbing both linearly and in a ball.

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References

  1. P. P. Vyrvynskyi, and V. L. Khomenko, Repair of Wells [in Ukrainian], National Mining University, Dnipropetrovsk (2003).

  2. V. S. Boiko, R. M. Kondrat, and R. S. Yaremijchyk (Eds.), Handbook on Oil and Gas Business [in Ukrainian], Kyiv-Lviv (1996).

  3. R. M. Kondrat, and O. R. Kondrat, “Analysis of the causes of salt deposits and methods of their control during the operation of gas and gas condensate wells,” Prospecting and Development of Oil and Gas Fields [in Ukrainian], 2, 27–31 (2008).

  4. M. Akrout, I. Bousselmi, E. Trinki, S. Maximovich, and F. Dalard, “Effect non-toxic corrosion inhibitors on steel in chloride solution,” J. of Mat. Sci., 39, Is. 24, 7341–7350 (2004); https://doi.org/10.1023/B:JMSC.0000048749.31437.b9

  5. A. Singh, K. R. Ansari, and M. A. Quraishi, “Inhibition effect of natural polysaccharide composite on hydrogen evolution and P110 steel corrosion in 3.5 wt% NaCl solution saturated with CO2: Combination of experimental and surface analysis,” Int. J. of Hydrogen Energy, 45, Is. 46, 25398–25408 (2020); https://doi.org/10.1016/j.ijhydene.2020.06.288

  6. S. A. Korniy, I. M. Zin, M. B. Tymus, O. P. Khlopyk, and M. Y. Holovchuk, “Steel corrosion inhibition by microbial polysaccharide and tartrate mixture,” J. of Bio- and Tribo-Corrosion, 8, Is. 1, art. no. 6 (2022); https://doi.org/10.1007/s40735-021-00605-5

  7. G. Palumbo, K. Kollbec, R. Wirecka, A. Bernasik, and M. Gorny, “Effect of CO2 partial pressure on the corrosion inhibition of N80 carbon steel by gum arabic in a CO2-water saline environment for shale oil and gas industry,” Materials, 13, Is. 19, art. no. 4245 (2020); https://doi.org/10.3390/MA13194245

  8. M.-O. Danyliak, and Yu. Ya. Rizun, “Gum arabic as an environmentally friendly inhibitor for corrosion protection of 09G2S steel in neutral media,” Mater. Sci., 58, No. 1, 47–53 (2022); https://doi.org/10.1007/s11003-022-00629-3

    Article  CAS  Google Scholar 

  9. S. A. Umoren, A. A. AlAhmary, Z. M. Gasem, and M. M. Solomon, “Evaluation of chitosan and carboxymethyl cellulose as ecofriendly corrosion inhibitors for steel,” Int. J. Boil Macromol., 117, 1017–1028 (2018); https://doi.org/10.1016/j.ijbiomac.2018.06.014

  10. Ye. P. Kovalchyk, O. V. Resetnyak, Selfogranized Layers on Solid Surface [in Ukrainian], Ivan Franko State Univ. Publ. House, Lviv (2006).

  11. F. Haaf, A. Sanner, and F. Straub, “Polymers of n-vinylpyrrolidone: Synthesis, characterization and uses,” Polymer Journal, 17, Is. 1, 143–152 (1985); https://doi.org/10.1295/polymj.17.143

  12. H. Gerengi, H. I. Ugras, M. M. Solomon, S. A. Umoren, M. Kurtay, and N. Atar, “Synergistic corrosion inhibition effect of 1-ethyl-1-methylpyrrolidinium tetrafluoroborate and iodide ions for low carbon steel in HCl solution,” J. of Adhesion Sci. and Techn., 30, Is. 21, 2383–2403 (2016); https://doi.org/10.1080/01694243.2016.1183407

  13. N. M. Velikonskaya, and A. A. Nadtochiy, Surface Phenomena and Dispersed Systems [in Ukrainian], State Metallurgical Academy of Ukraine, Dnipro (2018).

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Correspondence to L. A. Mahlatiuk.

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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 59, No. 2, pp. 117–122, March–April, 2023.

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Slobodyan, Z.V., Mahlatiuk, L.A., Kupovych, R.B. et al. Inhibition of Carbon Steel Corrosion by Polyvinylpyrrolidone in Chloride-Acetate Solution and in Model Stratal Water. Mater Sci 59, 242–248 (2023). https://doi.org/10.1007/s11003-024-00769-8

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  • DOI: https://doi.org/10.1007/s11003-024-00769-8

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