By the methods of chronopotentiometry and cyclic voltammetry, we study the electrochemical characteristics of Fe65.58Cr7.92Mn1.98Mo3.96V0.1Cu0.05W0.01Ti0.06C4.69Si2.85B5.94P6.93, Fe64.38Cr4.5Mo4V0.1C5P7B10Si2.87, and Fe68.93Cr2Mo4Mn(Cu,W, Al)0.07C7P10B5Si2 bulk amorphous metallic alloys in 0.5 M aqueous solutions of sodium chloride, potassium hydroxide, and hydrochloric acid. It is shown that the surfaces of the alloys in the indicated aggressive aqueous solutions are characterized by high corrosion resistances. As temperature increases, the corrosion resistance decreases in the solutions of sodium chloride and potassium hydroxide but remains practically invariable in hydrochloric acid.
Change history
05 November 2018
The name of the last author should read O. V. Reshetnyak.
References
A. Makino, T. Hatanai, A. Inoue, and T. Masumoto, “Nanocrystalline soft magnetic Fe–M–B (M = Zr, Hf, Nb) alloys and their applications,” Mater. Sci. Eng., 226, 594–602 (1997).
I. Solomon and N. Solomon, “Effect of cobalt on the corrosion behavior of amorphous Fe–Co–Cr–B–Si alloys in dilute mineral acids,” Rev. Metalurg., 46, 389–395 (2010).
Z. Long, Y. Shao, G. Xie, P. Zhang, B. Shen, and A. Inoue, “Enhanced soft-magnetic and corrosion properties of Fe-based bulk glassy alloys with improved plasticity through the addition of Cr,” J. Alloys Comp., 462, 52–59 (2008).
B. R. Barnard, P. K. Liaw, M. D. Demetriou, and W. L. Johnson, “Oxidation behavior of metallic glass foams,” Corr. Sci., 50, 2135–2139 (2008).
J. Jayaraj, K.B. Kim, H.S. Ahn, and E. Fleury, “Corrosion mechanism of N-containing Fe–Cr–Mo–Y–C–B bulk amorphous alloys in highly concentrated HCl solution,” Mat. Sci. Eng.: A, 449–451, 517–520 (2007).
L. M. Boichyshyn, O. M. Hertsyk, M. A. Kovbuz, T. G. Pereverzeva, and B. Ya. Kotur, “Electrocatalytic evolution of hydrogen on amorphous Fe–Nb–B-rare-earth-metal electrodes from alkaline solutions,” Russ. J. Appl. Chem., 87, No. 1, 62–69 (2014).
O. M. Hertsyk, M. O. Kovbuz, T. H. Pereverzeva, A. K. Borysyuk, and L. M. Boichyshyn, “Influence of heat treatment and variable magnetic fields on the chemical resistance of amorphous alloys based on iron,” Mater. Sci., 50, No. 3, 454–460 (2014).
O. M. Hertsyk, M. A. Kovbuz, T. G. Pereverzeva, L. M. Boichyshyn, and B. Ya. Kotur, “An effect of low temperature processing on stability of physical and chemical properties of amorphous alloy Fe78.5Ni1.0Mo0.5Si6.0B14.0 ,” Russ. J Appl. Chem., 86, No. 6, 802–806 (2013).
O. M. Hertsyk, L. M. Boichyshyn, M. O. Kovbuz, Yu. O. Kulyk, and V. K. Nosenko, “Corrosion resistance of the Fe68.93Mn1Mo4Cr2C7P10B5Si2(Cu,W, Al)0.07 amorphous alloy in media with different aggressiveness,” Fiz.-Khim. Mekh. Mater., 51, No. 5, 114–120 (2015); English translation : Mater. Sci., 51, No. 5, 719–726 (2015).
N. S. Akhmetov, General and Inorganic Chemistry [in Russian], Vysshaya Shkola, Moscow (2001).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 53, No. 3, pp. 37–42, May–June, 2017.
Rights and permissions
About this article
Cite this article
Hertsyk, O.M., Kovbuz, M.O., Boichyshyn, L.M. et al. Influence of Alloying on the Corrosion Resistance of Bulk Amorphous Alloys Based on Iron. Mater Sci 53, 330–336 (2017). https://doi.org/10.1007/s11003-017-0079-6
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11003-017-0079-6