Skip to main content
Log in

Surface Modification of Polymer Nanocomposites by Glow-Discharge Plasma Treatment

  • Published:
Materials Science Aims and scope

A systematic study was carried out to characterize the effects of Argon-ion plasma on nanocomposite polymer membrane. Nanoparticles of cobalt (Co) are synthesized by the chemical root. Nanocomposite polymeric membranes 20 μm in size were prepared by using solution casting and spin coating method. The argon-ion plasma treatment was done for these membranes. The membranes were characterized prior to and after plasma treatment to perform the comparative study by using different techniques, such as the optical microscopy, scanning electron microscopy, and Fourier-transform infrared spectroscopy. The results show that the plasma treatment is a quite efficient tool for improving the surface and chemical properties of composite membranes with unique characteristics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. M. R. Mohammadia, D. J. Fray, and M. C. Cordero-Cabrera, “Sensor performance of nanostructured TiO2 thin films derived from particulate sol–gel route and polymeric fugitive agents,” Sensors Actuators, B, 124, 74–82 (2007).

    Article  Google Scholar 

  2. Y. Sanchuan, L. Xuesong, L. Jingqun, et al., “Surface modification of thin-film composite polyamide reverse osmosis membranes with thermo-responsive polymer (TRP) for improved fouling resistance and cleaning efficiency,” Separ. & Purif. Technol., 76, 283–289 (2011).

    Article  Google Scholar 

  3. R. Agarwal, N. K. Agrawal, and R. Singh, “Low-temperature annealing of cadmium sulfide thin films for improving surfaceinterface properties,” Mater. Focus, 3, No. 3, 267–271 (2014).

    Article  Google Scholar 

  4. S. Yang, P. Jiang, and J. Tang, “Association of miR-502-binding site single nucleotide polymorphism of SET8 gene with non-small cell lung cancer risk in Chinese people,” J. Bionanosci., 7, 585–589 (2013).

    Article  Google Scholar 

  5. N. Ehlert, P. Mueller, M. Stieve, et al., “Mesoporous silica films as a novel biomaterial: applications in the middle ear,” Chem. Soc. Rev., 42, 3847–3861 (2013).

    Article  Google Scholar 

  6. G. Kedawat, B. K. Gupta, Kumar, et al., “Fabrication of a flexible UV band-pass filter using surface plasmon metal-polymer nanocomposite films for promising laser applications,” ACS Applied Materials & Interfaces, 6, No. 11, 8407–8414 (2014).

    Article  Google Scholar 

  7. N. K. Agrawal, R. Agarwal, Y. K. Vijay, and K. C. Swami, “Surface treatment of CoS/polymer nanocomposite membranes for improving wettability and surface energy,” J. Mat. Sci. Surf. Eng., 1, No. 3, 82–87 (2014).

    Google Scholar 

  8. A. Moreno, M. C. Goiato, D. M. D. Santos, et al., “Effect of different disinfectants on the microhardness and roughness of acrylic resins for ocular prosthesis,” Gerodontology, 30, 32–39 (2013).

    Article  Google Scholar 

  9. N. K. Agrawal, R. Agarwal, K. Awasthi, et al., “Surface modification of nanocomposite polymer membranes by ion plasma irradiation for improving biocompatibility of polymers,” Adv. Mat. Letters, 5, No. 11, 645–651 (2014).

    Google Scholar 

  10. W. R. Webb, T. P. Dale, A. J. Lomas, et al., “The application of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) scaffolds for tendon repair in the rat model,” Biomaterials, 34, 6683–6694 (2013).

    Article  Google Scholar 

  11. N. K. Agrawal., K. Awasthi, Y. K. Vijay, and K. C. Swami, “Synthesis and characterization of plasma treated TiO2 nanocomposite polymer membranes,” Adv. Electrochem., 1, No. 2, 98–104 (2013).

    Article  Google Scholar 

  12. B. Bagra, P. Pimpliskar, and N. K. Agrawal, “Biocompatibility, surface & chemical characterization of glow discharge plasma modified ZnO nanocomposite polycarbonate,” AIP Conf. Proc., 1591, 189–191 (2014).

    Article  Google Scholar 

  13. N. K., Agrawal R. Agarwal, Y. K. Vijay, and K. C. Swami, “Characterization of N2 Plasma treated nanocomposite polymer membranes,” J. Mat. Sci. Surf. Eng., 1, No. 1, 4–7 (2013).

    Google Scholar 

  14. O. B. Regan and M. Gratzel, “A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films,” Nature, 353, 737–742 (1991).

    Article  Google Scholar 

  15. S. Goel and S. K. Mathew, “Automated Detection, characterization, and tracking of sunspots from SoHO/MDI continuum images,” Solar Phys., 289, 1413–1431 (2014).

    Article  Google Scholar 

  16. N. K. Agrawal, M. Singh, Y. K. Vijay, and K. C. Swami, “Synthesis and characterization of colloidal TiO2 nanoparticles: through titanium chloride rich solutions,” Adv. Sci. Eng. Med., 6, No. 5, 595–602 (2014).

    Article  Google Scholar 

  17. R. Rao, R. Sukla, K. Sahoo, and H. S. Panda, “Decolorization of aqueous solution containing organic synthetic-dye via darkcatalysis process using hydrothermally synthesized semiconductor-oxides nanotubes,” Adv. Sci. Eng. Med., 6, 173–183 (2014).

    Article  Google Scholar 

  18. N. K. Agrawal, R. Agarwal, Y. K. Vijay, and K. C. Swami, “Surface modification of Ag nanocomposite polymer membranes by glow discharge plasma,” J. Mat. Sci. Surf. Eng., 1, No. 1, 23–27 (2013).

    Google Scholar 

  19. M. Hatami, K. V. Rao, M. Ahmadipour, and V. Rajendar, “Formation of nanosize Ag- TiO2 composite by Sol-Gel method and investigation of band gap decline,” Adv. Sci. Eng. Med., 5, 1039–1045 (2013).

    Article  Google Scholar 

  20. N. K. Agrawal, R. Agarwal, Y. K. Vijay, and K. C. Swami, “Reactive polymer surfaces for cell colonization,” J. Mat. Sci. Surf. Eng., 1, No. 2, 32–35 (2014).

    Google Scholar 

  21. S. Shrivastava, T. Bera, S. K. Singh, et al., “Characterization of antiplatelet property of silver nanoparticle,” ACS Nano, 116, 15–23 (2009).

    Google Scholar 

  22. N. K. Agrawal, R. Agarwal, Y. K. Vijay, and K. C. Swami, “Enhancement of sterilization efficiency of polymer nanocomposite by argon plasma irradiation,” J. Bionanoscience, 8, No. 2, 108–115 (2014).

    Article  Google Scholar 

  23. A. Dandia, V. Parewa, S. L. Gupta, et al., “PC-ZnO nanocomposites as efficient and reusable catalyst for the synthesis of α , β -unsaturated compounds and aldimines,” Current Organic Chemistry, 18, No. 20, 2652–2664 (2014).

    Article  Google Scholar 

  24. N. K. Agrawal, R. Agarwal, S. Khandelwal, et al., “ZnO nanocomposites polystyrene membranes: plasma treatment & characterization,” Int. J. Eng. Research & Technol., 1, 104–107 (2014).

    Google Scholar 

  25. N. K. Agrawal, R. Agarwal, Y. K. Vijay, and K. C. Swami, “Plasma etching technology for surface and chemical modifications of aluminum and Poly Methyl Meth Acrylate (PMMA) nanocomposites,” Adv. Sci. Eng. Med., 6, No. , 698–703 (2014).

  26. L. Meihong, Y. Sanchuan, Q. Ming et al., “Impact of manufacture technique on seawater desalination performance of thin-film composite polyamide-urethane reverse osmosis membranes and their spiral-wound elements,” J. Mem. Sci., 348, 268–275 (2012).

    Google Scholar 

  27. N. K. Agrawal, Study of Enhancement in Bio-Adoptability & Biocompatibility of Nanocomposite Polymer Membranes by Plasma Treatment, Malaviya Nation. Inst. Technol, Ph. D. Thesis, Jaipur; India (2014).

  28. C. Oehr, “Plasma surface modification of polymers for biomedical use,” Nucl. Instr. Meth. Phys. Res., B, 40, 208 (2003).

    Google Scholar 

  29. N. K. Agrawal, R. Agarwal, D. Bhatia, et al., “Synthesis of Al & Ag nanoparticles through ultrasonic dissociation of thermal evaporation deposited thin films for promising clinical applications as polymer nanocomposite,” Adv. Mat. Lett., 6, No. 2, 98–105 (2015).

    Google Scholar 

  30. T. Kohma, D. Oyamatsu, and S. Kuwabata, “Preparation of selective microglucose sensor without permselective membrane by electrochemical deposition of ruthenium and glucose oxidase,” Electrochem. Comm., 9, 1012–1024 (2007).

    Article  Google Scholar 

  31. R. Agarwal, N. K. Agrawal, and R. Singh, “Cicerarietinum leaf extract mediated synthesis of silver nanoparticles and screening of its antimicrobial activity,” Adv. Sci. Eng. Med., 6, No. 2, 203–207 (2014).

    Article  Google Scholar 

  32. Agarwal, A. Mehta, S. Kachhwaha, and S. L Kothari, “Green synthesis of silver nanoparticles and their activity against mycobacterium tuberculosis,” Adv. Sci. Eng. Med., 5, No. 7, 709–714 (2013).

    Google Scholar 

Download references

Acknowledgments

The authors wish to thank and acknowledge Ms. Priti Agarwal for helping in synthesis of Co nanoparticles. The authors are also thankful to Dr. B. L. Choudary, Department of Physics, University of Rajasthan, for the SEM analysis and to the Jawaharlal Nehru Memorial Fund, New Delhi, India for providing a scholarship for Mr. Narendra Kumar Agrawal to carry out his PhD work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. K. Agrawal.

Additional information

Published in Fizyko-Khimichna Mekhanika Materialiv, Vol. 51, No. 1, pp. 64–70, January–February, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Agrawal, N.K., Agarwal, R., Gautam, A.K. et al. Surface Modification of Polymer Nanocomposites by Glow-Discharge Plasma Treatment. Mater Sci 51, 68–75 (2015). https://doi.org/10.1007/s11003-015-9811-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11003-015-9811-2

Keywords

Navigation