Skip to main content
SpringerLink
Log in

Changes in Polarization Resistance in the Process of Formation of Protective Phase Layers with Participation of Organic Ligands

  • Published:
Materials Science Aims and scope

We study the principal kinetic regularities of the formation of protective metalloorganic films in acid media in the presence of complex-forming corrosion inhibitors and propose an equivalent scheme of the metal/electrolyte interface taking into account the polarization resistance of diffusion of the phase layer and intended for the analysis of the dynamics of its growth in the course of formation of protective layers with participation of inhibitors of the indicated kind. It is shown that the thickness of the film increases and protective properties improve with time according to the parabolic law obeying the regularities of diffusion kinetics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. S. M. Reshetnikov, Inhibitors of the Acid Corrosion of Metals [in Russian], Khimiya, Leningrad (1986).

    Google Scholar 

  2. L. I. Antropov and I. S. Pogrebova, “Relationship between the adsorption of organic compounds and their influence on the corrosion of metals in acid media,” in: Itogi VINITI. Ser.: Corrosion and Corrosion Protection [in Russian], Vol. 2, VINITI, Moscow (1973), pp. 27–112.

  3. D. A. Tkalenko, M. D. Tkalenko, and S. O. Mazanko, “Macrokinetic approach to the analysis of the action of corrosion inhibitors in metals,” Fiz.-Khim. Mekh. Mater., Special Issue, 222–225 (1996).

  4. D. A. Tkalenko, Yu. P. Vishnevskaya, A. V. Noskov, and M. V. Byk, “Kinetics of formation of the protective layers on metals in the presence of organic corrosion inhibitors,” in: Abstr. of the Second Internat. Sci.-Eng Conf. “Contemporary Methods in Theoretical and Experimental Electrochemistry” (June 21–25, 2010, Ples) [in Russian], Ples (2010), p. 51.

  5. D. A. Tkalenko, G. Venkatesvaran, Yu. P. Vishnevskaya, et al., “Inhibitory effect of cysteine in acid media,” Protect. Met. Physical Chem. Surfaces, 46, No. 5, 609–614 (2010).

    Article  Google Scholar 

  6. Yu . S. Gerasimenko and N. A. Belousova, Method for the Determination of Corrosion Rate under the Conditions of Diffusion Control and Passivation [in Russian], Application No. 94076425 Dated 28.07.94, MKI, G01 No. 27/26, Industrial Property, Official Bulletin, No. 1, 292 (1996).

  7. Yu. P. Vyshnevs’ka, D. A. Tkalenko, Yu. V. Savchenko, and M. V. Byk, “Application of the processes of complex formation in the protection of metals against corrosion fracture,” Fiz.-Khim. Mekh. Mater., Special Issue, No. 7, 606–611 (2008).

  8. N. P. Zhuk, A Course of Corrosion and Protection of Metals [in Russian], Metallurgiya, Moscow (1968).

    Google Scholar 

  9. V. I. Rybkov, Solid-Phase Chemical Kinetics and Reaction Diffusion [in Ukrainian], Institute for Problems in Materials Science, Ukrainian National Academy of Sciences, Kyiv (2002).

    Google Scholar 

  10. D. А. Tkalenko, Yu. P. Vishnevskaya, M. D. Byk, and M. D. Tkalenko, “Phase protective layers on metals in the presence of the derivatives of guanidine,” Visn. NTU “KhPI,” No. 30, 86–90 (2010).

  11. D. А. Tkalenko, Yu. P. Vyshnevs’ka, L. S. Tsybul’ska, et al, “Complex-forming inhibitors of the corrosion of metals in acid media,” Fiz.-Khim. Mekh. Mater., Special Issue, No. 8, 475–480 (2010).

  12. V. S. Kublanovskii, А. V. Gorodyskii, V. N. Belinskii, and Т. S. Glushchak, Changes of Concentration in Near-Electrode Layers in the Process of Electrolysis [in Russian], Naukova Dumka, Kiev (1978).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. “Kyiv Polytechnic Institute”, National Technical University of Ukraine, Kyiv, Ukraine

    D. A. Tkalenko, Yu. P. Vyshnevs’ka, Yu. S. Herasymenko & I. F. Khirkh-Yalan

Authors
  1. D. A. Tkalenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. P. Vyshnevs’ka
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. S. Herasymenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. F. Khirkh-Yalan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. P. Vyshnevs’ka.

Additional information

Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 49, No. 3, pp. 28–33, May–June, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tkalenko, D.A., Vyshnevs’ka, Y.P., Herasymenko, Y.S. et al. Changes in Polarization Resistance in the Process of Formation of Protective Phase Layers with Participation of Organic Ligands. Mater Sci 49, 304–310 (2013). https://doi.org/10.1007/s11003-013-9615-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11003-013-9615-1

Keywords

Search

Navigation