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Characteristic Features of the Sorption–Desorption of Hydrogen by Mg–M–Ni (M = Al, Mn, Ti) Ternary Alloys

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By the method of high-energy milling in a ball mill, we obtain new alloys of Mg–M−Ni (M = Al, Mn, Ti) ternary systems. The properties of hydrogen sorption of the Mg3AlNi2 compound (Ti2Ni-type structure) are investigated and compared with the properties of Mg3MNi2 (M = Mn, Ti) isostructural compounds. The sorption–desorption of hydrogen by Mg88M4Ni8 (M = Al, Mn, Ti) alloys is studied. The catalytic influence of Mg3MNi2 ternary phases on the hydrogenation of magnesium is established.

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Authors and Affiliations

  1. Karpenko Physicomechanical Institute, Ukrainian National Academy of Sciences, Lviv, Ukraine

    V. V. Berezovets’, R. V. Denys & I. Yu. Zavalii

  2. Institut de Chimie et des Matériaux de Paris Est, Centre National de la Recherche Scientifique, Thiais, France

    V. Paul-Boncour

  3. Iowa State University, Ames Laboratory, Iowa, USA

    V. Pecharsky

Authors
  1. V. V. Berezovets’
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  2. R. V. Denys
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  3. I. Yu. Zavalii
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  4. V. Paul-Boncour
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  5. V. Pecharsky
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Corresponding author

Correspondence to I. Yu. Zavalii.

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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 49, No. 2, pp. 26–34, March–April, 2013.

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Berezovets’, V.V., Denys, R.V., Zavalii, I.Y. et al. Characteristic Features of the Sorption–Desorption of Hydrogen by Mg–M–Ni (M = Al, Mn, Ti) Ternary Alloys. Mater Sci 49, 159–169 (2013). https://doi.org/10.1007/s11003-013-9595-1

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  • DOI: https://doi.org/10.1007/s11003-013-9595-1

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