Abstract
We study the anticorrosion properties of newly synthesized derivatives of 2-mercaptobenzimidazole and the efficiency of their action in compositions based on the wastes of production of ɛ-caprolactam at the Chernihiv “Khimvolokno” Open Joint-Stock Company. A conclusion is made that these compounds can be used as corrosion inhibitors for 20 steel placed in acid and neutral media. The efficiency of application of protective compositions based on the wastes of production of ɛ-caprolactam with admixtures of the derivatives of 2-mercaptobenzimidazole is demonstrated for working media with pH 1–6.5.
Similar content being viewed by others
References
V. G. Starchak, O. I. Sizaya, A. N. Krasovskii, and L. D. Kosukhina, “On the inhibiting ability of polymethylenbis-2, 2-benzimidazoles,” Zashch. Met., 30, No. 5, 494–497 (1994).
O. I. Sizaya, “Modification of epoxy compositions by complex compounds of the derivatives of benzimidazole,” Ékotekhnol. Resursosberezh., No. 5, 36–39 (1997).
O. I. Syza, Development of the Scientific Principles of Creation of Inhibiting Synergistic Compositions and Epoxy Coatings Modified by These Compositions for the Purposes of Corrosion Protection [in Ukrainian], Doctoral-Degree Thesis (Engineering) [in Ukrainian], Lviv (2001).
V. G. Starchak, A. N. Krasovskii, L. D. Kosukhina, et al., “Anticorrosion activity of some derivatives of 2-mercaptobenzimidazole,” Zashch. Met., 30, No. 4, 405–409 (1994).
P. A. Al’kozin, Corrosion and Corrosion Protection of the Metal of Thermal Power-Generating Equipment [in Russian], Énergoizdat, Moscow (1982).
Ya. M. Kolotyrkin, Metal and Corrosion [in Russian], Metallurgiya, Moscow (1985).
H. Kaesche, Die Korrosion der Metalle. Physikalisch-Chemische Prinzipien und Aktuelle Probleme, Springer, Berlin (1979).
I. L. Rosenfel’d, Corrosion Inhibitors [in Russian], Khimiya, Moscow (1977).
V. P. Grigor’ev and V. V. Ékilik, Chemical Structure and Protective Action of Corrosion Inhibitors [in Russian], Rostov University, Rostov-on-Don (1978).
L. I. Freiman, V. A. Makarov, and I. E. Bryksin, Potentiometric Methods in Corrosion Investigations and Electrochemical Protection [in Russian], Khimiya, Leningrad (1972).
L. I. Antropov, Theoretical Electrochemistry [in Russian], Vysshaya Shkola, Moscow (1984).
Yu. I. Babei, V. G. Starchak, Yu. A. Klyachko, et al., “On the evaluation of the efficiency of action of corrosion inhibitors,” Zashch. Met., 12, No. 3, 332–333 (1976).
A. J. Gordon and R. A. Ford, The Chemist’s Companion. A Handbook of Practical Data, Techniques, and References, Wiley, New York (1972).
S. M. Reshetnikov, Inhibition of the Acid Corrosion in Metals [in Russian], Udmurtiya, Izhevsk (1980).
V. K. Bahin, Optimization of the Ecological and Corrosion Situation by the Utilization of Wastes of the Chernihiv “Khimvolokno” Open Joint-Stock Company [in Ukrainian], Candidate-Degree Thesis (Engineering) [in Ukrainian], Zaporizhzhya (1995).
O. I. Sizaya, O. L. Gumenyuk, and L. Yu. Chumakova, “Influence of the degree of aggressiveness of a medium on the anticorrosion efficiency of the derivatives of 2-thioquinazolin-4-one,” Zashch. Met., 41, No. 1, 45–46 (2005).
L. I. Antropov, E. M. Makushin, and V. F. Panasenko, Inhibitors of Corrosion in Metals [in Russian], Tekhnika, Kiev (1981).
E. S. Ivanov, Inhibitors of Corrosion in Metals in Acid Media [in Russian], Metallurgiya, Moscow (1986).
Author information
Authors and Affiliations
Additional information
__________
Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol. 43, No. 1, pp. 85–93, January–February, 2007.
Rights and permissions
About this article
Cite this article
Humenyuk, O.L., Syza, O.I. & Krasovs’kyi, O.M. Inhibitor protection of steels in acid and neutral media by the derivatives of 2-mercaptobenzimidazole. Mater Sci 43, 91–101 (2007). https://doi.org/10.1007/s11003-007-0010-7
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11003-007-0010-7