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Kinetics and Catalysis

, Volume 46, Issue 5, pp 712–718 | Cite as

Cationic Complexes of Monovalent Nickel as Catalysts for Styrene Polymerization

  • V. V. Saraev
  • P. B. Kraikivskii
  • V. V. Annenkov
  • A. I. Vil'ms
  • D. A. Matveev
  • E. N. Danilovtseva
  • T. G. Ermakova
  • N. P. Kuznetsova
  • K. Lammertsma
Article

Abstract

The interaction of the [Ni(PPh3)3]BF4 complex with styrene and the products of styrene conversion in the polymerization reaction were studied by EPR and 13C NMR spectroscopy. The structure of the σ-carbocationic complex of Ni(I) formed by the interaction of styrene with the [Ni(PPh3)3]BF4 cationic phosphine complex of Ni(I) was characterized in detail. It was found that the reaction of styrene polymerization occurred with the participation of the coordination center of the σ-carbocationic complex (coordination catalysis), whereas the reaction of telomerization occurred with the participation of the cationic center of this complex (ionic catalysis). The resulting polymer contained active terminal double bonds; it is a promising macromonomer for the synthesis of grafted copolymers. The discovered capacity of alcohols to undergo nucleophilic addition to a growing polymer chain offers strong possibilities for preparing functional polymers and block copolymers.

Keywords

Styrene Block Copolymer PPh3 Phosphine Cationic Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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REFERENCES

  1. 1.
    Fel'dblyum, V.Sh., Dimerizatsiya i disproportsionirovanie olefinov (Dimerization and Disproportionation of Olefins), Moscow: Khimiya, 1978.Google Scholar
  2. 2.
    Bogdanovic, B., Adv. Organomet. Chem., 1979, p. 105.Google Scholar
  3. 3.
    Keim, W., Angew. Chem., Int. Ed. Engl., 1990, p. 235.Google Scholar
  4. 4.
    Shmidt, F.K., Kataliz kompleksami metallov pervogo perekhodnogo ryada reaktsii gidrirovaniya i dimerizatsii (Hydrogenation and Dimerization Catalyzed by Complexes of First-Row Transition Metals), Irkutsk: Irkutsk. Gos. Univ., 1986.Google Scholar
  5. 5.
    Klabunde, U., Tulip, T.H., Roe, D.C., and Ittel, S.D., J. Organomet. Chem., 1987, p. 141.Google Scholar
  6. 6.
    Tomov, A. and Kurtev, K., J. Mol. Catal. A, 1995, vol. 103, p. 55.Google Scholar
  7. 7.
    Pellecchia, C., Zambelli, A., Oliva, L., and Pappalardo, D., Macromolecules, 1996, vol. 29, p. 6990.Google Scholar
  8. 8.
    Feldman, J., McLain, S.J., Parthasarathy, A., et al., Organometallics, 1997, vol. 16, p. 1514.CrossRefGoogle Scholar
  9. 9.
    Schleis, T., Spaniol, T.P., Okuda, J., et al., J. Organomet. Chem., 1998, vol. 569, p. 159.CrossRefGoogle Scholar
  10. 10.
    Peruch, F., Cramail, H., and Deffieux, A., Macromolecules, 1999, vol. 32, p. 7977.CrossRefGoogle Scholar
  11. 11.
    Koppl, A. and Alt, H.G., J. Mol. Catal. A, 2000, vol. 154, p. 45.Google Scholar
  12. 12.
    Milano, G., Guerra, G., Pellecchia, C., and Cavallo, L., Organometallics, 2000, vol. 19, p. 1343.CrossRefGoogle Scholar
  13. 13.
    Heinicke, J., Koesling, M., Bruell, R., et al., Eur. J. Inorg. Chem., 2000, vol. 2, p. 299.Google Scholar
  14. 14.
    Lee, B.Y., Bazan, G.C., Vela, J., Komon, Z.J., et al., J. Am. Chem. Soc., 2001, vol. 123, p. 5352.Google Scholar
  15. 15.
    Soula, R., Broyer, J.P., Llauro, M.F., et al., Macromolecules, 2001, vol. 34, p. 2438.Google Scholar
  16. 16.
    Hicks, F.A. and Brookhart, M., Organometallics, 2001, vol. 20, p. 3217.CrossRefGoogle Scholar
  17. 17.
    Preishuber-Pflugl, P. and Brookhart, M., Macromolecules, 2002, vol. 35, p. 6074.CrossRefGoogle Scholar
  18. 18.
    Schroder, D.L., Keim, W., Zuideveld, M.A., and Mecking, S., Macromolecules, 2002, vol. 35, p. 6071.CrossRefGoogle Scholar
  19. 19.
    Daugulis, O. and Brookhart, M., Organometallics, 2002, vol. 21, p. 5926.Google Scholar
  20. 20.
    Jenkins, J.C. and Brookhart, M., Organometallics, 2003, vol. 22, p. 250.CrossRefGoogle Scholar
  21. 21.
    Carlini, C., Raspolli Galletti A.M., Sbrana G., and Caretti D, Polymer, 2001, vol. 42, p. 5069.CrossRefGoogle Scholar
  22. 22.
    Saraev, V.V., Kraikivskmi, P.B., Zelinskii, S.N., et al., Koord. Khim., 2001, vol. 27, no.2, p. 136.Google Scholar
  23. 23.
    Saraev, V.V., Tkach, V.S., Kraikivskii, P.B., et al., Koord. Khim., 1998, vol. 24, no.8, p. 602.Google Scholar
  24. 24.
    Kraikivskii, P.B., Saraev, V.V., Matveev, D.A., et al., Koord. Khim., 2003, vol. 29, no.6, p. 461.Google Scholar
  25. 25.
    Saraev, V.V., Kraikivskii, P.B., Lazarev, P.G., et al., Koord. Khim., 1996, vol. 22, no.9, p. 648.Google Scholar
  26. 26.
    Koptyug, V.A., Arenonievye iony. Stroenie i reaktsionnaya sposobnost' (Arenonium Ions: Structure and Reactivity), Novosibirsk: Nauka, 1983.Google Scholar
  27. 27.
    Gordon, A.J. and Ford, R.A., A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.Google Scholar
  28. 28.
    Tkach, V.S., Gruznykh, V.A., Murasheva, N.A., and Shmidt, F.K., Koord. Khim., 1990, vol. 16, no.4, p. 574.Google Scholar
  29. 29.
    Rabek, J.F., Experimental Methods in Polymer Chemistry, New York: Wiley, 1980, vol. 1.Google Scholar
  30. 30.
    Praktikum po vysokomolekulyarnym soedineniyam (Practical Course of Polymers), Kabanov, V.A., Ed., Moscow: Khimiya, 1985, p. 224.Google Scholar
  31. 31.
    Saraev, V.V., Kraikivskii, P.B., Lazarev, P.G., et al., Koord. Khim., 1996, vol. 22, no.9, p. 655.Google Scholar

Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • V. V. Saraev
    • 1
  • P. B. Kraikivskii
    • 1
  • V. V. Annenkov
    • 2
  • A. I. Vil'ms
    • 1
  • D. A. Matveev
    • 1
  • E. N. Danilovtseva
    • 2
  • T. G. Ermakova
    • 3
  • N. P. Kuznetsova
    • 3
  • K. Lammertsma
    • 4
  1. 1.Irkutsk State UniversityIrkutskRussia
  2. 2.Institute of Limnology, Siberian DivisionRussian Academy of SciencesIrkutskRussia
  3. 3.Favorskii Institute of Chemistry, Siberian DivisionRussian Academy of SciencesIrkutskRussia
  4. 4.Vrije UniversiteitAmsterdamthe Netherlands

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