Abstract
In some heterogeneous chemical processes occurring on the solid/gas interface, reactant atoms and molecules chemisorbed during the reaction are not directly involved in chemical transformations but act as catalytic sites accelerating this reaction.
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REFERENCES
Krylov, O.V. and Matyshak, V.A., Promezhutochnye soedineniya v geterogennom katalize (Intermediates in Heterogeneous Catalysis), Moscow: Nauka, 1995.
Lavrenko, V.A., Rekombinatsiya atomov vodoroda na poverkhnosti tverdykh tel (Recombination of Hydrogen Atoms on Solid Surfaces), Kiev: Naukova Dumka, 1973.
Styrov, V.V., Kinet. Katal., 1968, vol. 9, no.1, p. 124.
Grankin, V.P., Styrov, V.V., and Tyurin, Yu.I., Kinet. Katal., 1983, vol. 24, no.1, p. 141.
Grankin, V.P. and Tyurin, Yu.I., Kinet. Katal., 1996, vol. 37, no.4, p. 608.
Kharlamov, V.F., Khim. Fiz., 1994, vol. 13, no.6, p. 83.
Kharlamov, V.F., Rekombinatsiya atomov na poverkhnosti tverdykh tel i soputstvuyushchie effekty (Recombination of Atoms on Solid Surface and Accompanying Effects), Tomsk: Tomsk. Gos. Univ., 1994.
Kharlamov, V.F., Anufriev, K.M., Krutovskii, E.P., et al., Pis’ma Zh. Tekh. Fiz., 1998, vol. 24, no.5, p. 23.
Kharlamov, V.F. and Anufriev, K.M., Pis’ma Zh. Tekh. Fiz., 1999, vol. 25, no.15, p. 27.
Styrov, V.V., Yagnova, L.I., and Izmailov, Sh.L., Kinet. Katal., 1975, vol. 16, no.3, p. 705.
Kharlamov, V.F., Khim. Fiz., 1991, vol. 10, no.8, p. 1084.
Kharlamov, V.F., Zh. Fiz. Khim., 1997, vol. 71, no.4, p. 678.
Kharlamov, V.F. and Rogozhina, T.S., Zh. Fiz. Khim., 2003, vol. 77, no.4, p. 632.
Kharlamov, V.F., Rogozhina, T.S., Barmin, A.V., et al., Pis’ma Zh. Tekh. Fiz., 2002, vol. 28, no.13, p. 67.
Makushev, I.A., Barmin, A.V., Kharlamov, V.F., et al., Prib. Tekh. Eksp., 2003, no. 1, p. 134.
Kharlamov, V.F., Makushev, I.A., Barmin, A.V., et al., Pis’ma Zh. Tekh. Fiz., 2003, vol. 29, no.7, p. 87.
Kharlamov, V.F., Poverkhnost, 1993, no. 11, p. 122.
Anufriev, K.M., Kharlamov, V.F., and Razumov, A.V., Prib. Tekh. Eksp., 2000, no. 1, p. 152.
Callear, A.B. and Lambert, J.D., in Comprehensive Chemical Kinetics, vol. 4: The Formation and Decay of Excited Species, Bamford, C. and Tipper, C., Eds., Amsterdam: Elsevier, 1969.
Zaitsev, V.V., Opt. Spektrosk., 1992, vol. 72, no.4, p. 859.
Boreskov, G.K., Kataliz: voprosy teorii i praktiki (Theory and Practice of Catalysis), Novosibirsk: Nauka, 1987.
Izmailov, Sh.L. and Kharlamov, V.F., Kinet. Katal., 1982, vol. 23, no.5, p. 1179.
Kisliuk, P.J., J. Phys. Chem. Soc., 1957, vol. 3, p. 95; 1958, vol. 5, p. 78.
Ptushinskii, Yu.G. and Chuikov, B.A., Poverkhnost, 1992, no. 9, p. 5.
Matsushima, T., Almy, D.B., and White, J.M., Surf. Sci., 1977, vol. 67, no.1, pp. 89, 122.
Weinberg, W.H., Comrie, C.M., and Lambert, R.M., J. Catal., 1976, vol. 41, no.3, p. 489.
Kiperman, S.L., Gaidai, N.A., Nekrasov, N.V., et al., Chem. Eng. Sci., 1999, no. 54, p. 4305.
Kiperman, S.L. and Gaidai, N.A., Kinet. Katal., 1999, vol. 40, no.5, p. 705.
Kozhushner, M.A., Kolebatel’naya relaksatsiya adsorbirovannykh molekul (Vibrational Relaxation of Adsorbed Molecules), Moscow: Nauka, 1982.
Kharlamov, V.F. and Rogozhina, T.S., Kondens. Sredy Mezhfazn. Granitsy, 2002, vol. 4, no.2, p. 162.
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Translated from Kinetika i Kataliz, Vol. 46, No. 4, 2005, pp. 497–505.
Original Russian Text Copyright © 2005 by Kharlamov.
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Kharlamov, V.F. Chemisorbed Atoms and Molecules of Reactants As Active Sites in Heterogeneous Catalysis. Kinet Catal 46, 464–471 (2005). https://doi.org/10.1007/s10975-005-0099-3
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DOI: https://doi.org/10.1007/s10975-005-0099-3