Abstract
In situ X-ray diffraction and spectroscopic methods for direct contactless measurement of the temperature of nanoparticles of the active component in operating supported catalysts are considered. These methods have provided convincing evidence that the temperature of nanoparticles of the active component may differ significantly from the support temperature during a very exothermic reaction.
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REFERENCES
Slin’ko, M.G., Kirillov, V.A., Kulikov, A.V., Kuzin, N.A., and Shigarov, A.B., Dokl. Akad. Nauk, 2000, vol. 373, no.3, p. 359.
Slin’ko, M.G., Kirillov, V.A., Mikhailova, I.A., and Fadeev, S.I., Dokl. Akad. Nauk, 2001, vol. 376, no.2, p. 219.
Kellow, J. and Wolf, E.E., Catal. Today, 1999, vol. 9, p. 47.
Parmon, V.N., Kinet. Katal., 1996, vol. 37, p. 476.
Gudkov, B.S., Subbotin, A.N., Dykh, Z h.L., and Yakerson, V.I., Dokl. Akad. Nauk, 1997, vol. 353, p. 347.
Subbotin, A.N., Gudkov, B.S., Dykh, Zh.L., and Yakerson, V.I., React. Kinet. Catal. Lett., 1999, vol. 66, p. 97.
Khasin, A.A., Yur’eva, T.M., and Parmon, V.N., Dokl. Akad. Nauk, 1999, vol. 367, p. 213.
Simonova, L.G., Barelko, V.V., Toktarev, A.V., Paushtis, E.A., Kaichev, V.V., Zaikovskii, V.I., Bukhtiyarov, V.I., and Bal’zhinimaev, B.S., Kinet. Katal., 2001, vol. 42, no.6, p. 917.
Krieger, T.A., Plyasova, L.M., and Yurieva, T.M., Mater. Sci. Forum, 2000, vol. 321, p. 386.
Tsybulya, S.V., Cherepanova, S.V., and Solov’eva, L.P., Zh. Strukt. Khim., 1996, vol. 37, p. 332.
Finkel’, V.A., Vysokotemperaturnaya rentgenografiya metallov (High-Temperaure X-ray Crystallography for Metals), Moscow: Metallurgiya, 1968.
Guinier, A., Theorie et technigue de la radiocristallographie, Paris: Dunod, 1956, p. 601.
Novikova, S.I., Teplovoe rasshirenie tverdykh tel (Thermal Expansion of Solids), Moscow: Nauka, 1974.
Plyasova, L.M., Kriger, T.A., Khasin, A.A., and Parmon, V.N., Dokl. Akad. Nauk, 2002, vol. 382, no.4, p. 505.
Iveronova, V.I. and Revkevich, G.P., Teoriya rasseyaniya rentgenovskikh luchei (Theory of X-ray Scattering), Moscow: Mosk. Gos. Univ., 1972.
Rentgenografiya v fizicheskom metallovedenii (X-ray Diffraction in Metal Physics), Bagaryatskii, Yu.A., Ed., Moscow: Gosmetallurgizdat, 1961.
Spravochnik khimika (Chemist’s Handbook), Nikol’skii, B.P., Ed., Moscow: Khimiya, 1971, vol. 1.
Rentgenografiya: Spetspraktikum (X-ray Diffraction: Specialized Practical Course), Katsnel’son, A.A., Ed., Moscow: Mosk. Gos. Univ., 1986, p. 198.
Petrov, Yu.I., Fizika malykh chastits (Physics of Small Particles), Moscow: Nauka, 1982.
Valiev, R.Z. and Aleksandrov, I.V., Nanostrukturnye materialy, poluchennye intensivnoi plasticheskoi deformatsiei (Nanomaterials: Preparation by Intensive Plastic Deformation), Moscow: Logos, 2000.
Plyasova, L.M., Krieger, T.A., Molina, I.Yu., Ermakova, M.A., and Parmon, V.N., 19th European Crystallographic Meeting, Nancy, 2000, p. 358.
Skryshevskii, A.F., Strukturnyi analiz zhidkostei i amorfnykh tel (Structural Analysis of Liquids and Amorphous Solids), Moscow: Vysshaya Shkola, 1980.
Blokh, A.G., Osnovy teploobmena izlucheniem (Basic Principles of Radiative Heat Transfer), Moscow: Gosenergoizdat, 1962, p. 48.
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Translated from Kinetika i Kataliz, Vol. 46, No. 2, 2005, pp. 302–315.
Original Russian Text Copyright © 2005 by Plyasova, Aver’yanov, Paukshtis, Kriger, Khasin, Parmon.
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Plyasova, L.M., Aver’yanov, V.V., Paukshtis, E.A. et al. Development of contactless methods for directly measuring the temperature of nanoparticles of the active component in operating supported catalysts. Kinet Catal 46, 282–294 (2005). https://doi.org/10.1007/s10975-005-0074-z
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DOI: https://doi.org/10.1007/s10975-005-0074-z