Skip to main content
SpringerLink
Log in

Mechanism of carboxylic acid formation on vanadium-containing oxide catalysts

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The surface intermediates in acrolein oxidation into acrylic acid on a V-Mo oxide catalyst, formaldehyde oxidation into formic acid on a V-Ti catalyst, and 3-pyridinecarboxaldehyde and β-picoline oxidation into nicotinic acid on a V-Ti catalyst are identified by in situ IR spectroscopy. The acids are found to form by similar mechanisms. The intermediates in acid formation are saltlike surface compounds (formates, acrylates, and nicotinates) stabilized on vanadium ions. The role of vanadium in acid formation is discussed in terms of the mechanisms suggested.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Popova, G.Ya., Andrushkevich, T.V., and Zenkovets, G.A., Kinet. Katal., 1997, vol. 38, no.2, p. 285.

    Google Scholar 

  2. Slinkard, W.E. and DeGroot, P.B., J. Catal., 1981, vol. 68, no.2, p. 423.

    CAS  Google Scholar 

  3. Al’kaeva, E.M., Andrushkevich, T.V., Zenkovets, G.A., Kryukova, G.N., and Tsybulya, S.V., Catal. Today, 2000, vol. 61, p. 1.

    Google Scholar 

  4. Hengstum, A.J., Ommen, J.G., and Bosch, H., Gellings, P.J., Appl. Catal., 1983, vol. 8, p. 369.

    Google Scholar 

  5. Sachtler, W.M.H., Dorgelo, G.J.H., Fahrenfort, J., and Voorhoeve, R.J.H., Proc. 4th Int. Cong. on Catalysis, Budapest, 1971, vol. 1, p. 454.

    Google Scholar 

  6. Vrbaski, Th. and Mathewes, W.K., J. Catal., 1966, vol. 5, no.1, p. 125.

    CAS  Google Scholar 

  7. Mitsubishi Chemicals, JP 10-36311, 1998.

  8. Thorsteinson, E.M., Wilson, T.P., Young, F.G., and Kasai, P.H., J. Catal., 1978, vol. 52, no.1, p. 116.

    CAS  Google Scholar 

  9. Andrushkevich, T.V., Catal. Rev., 1993, vol. 35, no.2, p. 213.

    CAS  Google Scholar 

  10. Krylov, O.V. and Matyshak, V.A., Promezhutochnye soedineniya v geterogennom katalize (Intermediates in Heterogeneous Catalysis), Moscow: Nauka, 1996.

    Google Scholar 

  11. Tatewaki, H. and Huzinaga, S., J. Chem. Phys., 1979, vol. 71, p. 4339.

    CAS  Google Scholar 

  12. Frisch, M.J., Trucks, G.W., Schlegel, H.B., Gill, P.M.W., Johnson, B.G., Wong, M.W., Foresman, J.B., Robb, M.A., Head-Gordon, M., Replogle, ES., Gomperts, R., Andres, J.L., Raghavachari, K., Binkley, J.S., Gonzalez, C., Martin, L., Fox, D.J., Defrees, D.J., Baker, J., Stewart, J.J.P., and Pople, J.A., Gaussian 92/DFT: Revision G.2, Pittsburgh: Gaussian Inc., 1993.

    Google Scholar 

  13. Andrushkevich, T.V., Popova, G.Ya., Al’kaeva, E.M., Makarenko, M.G., and Zenkovets, G.A., Khim. Promst., 1996, no. 3, p. 21.

  14. Popova, G.Ya., Chesalov, Yu.A., Andrushkevich, T.V., and Stoyanov, E.S., Kinet. Katal., 2000, vol. 41, no.4, p. 601.

    Google Scholar 

  15. Bondareva, V.M., Andrushkevich, T.V., Lapina, O.B., Malakhov, V.V., Dovlitova, L.S., and Vlasov, A.A., Kinet. Katal., 2000, vol. 41, no.5, p. 736.

    Google Scholar 

  16. Popova, G.Ya., Chesalov, Yu.A., Andrushkevich, T.V., and Stoyanov, E.S., React. Kinet. Catal. Lett., 2002, vol. 76, no.1, p. 123.

    CAS  Google Scholar 

  17. Sokolovskii, V.D., Boreskov, G.K., Davydov, A.A., Gundrizer, T.A., Anufrienko, V.F., Ismailov, E.G., Budneva, A.A., and Maksimov, N.G., Dokl. Akad. Nauk SSSR, 1974, vol. 216, p. 599.

    CAS  Google Scholar 

  18. Popova, G.Ya., Andrushkevich, T.V., Chesalov, Yu.A., and Stoyanov, E.S., Kinet. Katal., 2000, vol. 41, no.6, p. 885.

    Google Scholar 

  19. Popova, G.Ya., Chesalov, Yu.A., Andrushkevich, T.V., Zakharov, I.I., and Stoyanov, E.S., J. Mol. Catal., 2002, vol. 158, p. 345.

    Google Scholar 

  20. Al’kaeva, E.M., Andrushkevich, T.V., and Zenkovets, G.A., 1st World Conf. on Environmental Catalysis, Piza, Italy, 1995, p. 447.

  21. Vanadievye katalizatory okisleniya geterotsiklicheskikh soedinenii (Vanadium Catalysts for Oxidation of Heterocyclic Compounds), Shimanskaya, M.V., Ed., Riga: Zinatne, 1990.

    Google Scholar 

  22. Green, I.H.S. and Harrison, D.J., Spectrochim. Acta, 1977, vol. 33, p. 75.

    Google Scholar 

  23. Sadtler Research Laboratories, 1971, 21676 K.

  24. Andrushkevich, T.V. and Popova, G.Ya., Usp. Khim., 1991, vol. 60, no.9, p. 1999.

    CAS  Google Scholar 

  25. Popova, G.Ya., Andrushkevich, T.V., Meshcheryakov, V.D., and Davydov, A.A., Kinet. Katal., 1990, vol. 31, no.2, p. 408.

    CAS  Google Scholar 

  26. Popova, G.Ya., Andrushkevich, T.V., and Metalkova, G.A., React. Kinet. Catal. Lett., 1979, vol. 12, p. 469.

    CAS  Google Scholar 

  27. Golodets, G.I., Dokl. Akad. Nauk SSSR, 1969, vol. 184, no.6, p. 1334.

    CAS  Google Scholar 

  28. Golodets, G.I., Teor. Eksp. Khim., 1982, vol. 18, no.18, p. 37.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    G. Ya. Popova, T. V. Andrushkevich, I. I. Zakharov & Yu. A. Chesalov

Authors
  1. G. Ya. Popova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. V. Andrushkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. I. Zakharov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. A. Chesalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Kinetika i Kataliz, Vol. 46, No. 2, 2005, pp. 233–242.

Original Russian Text Copyright © 2005 by Popova, Andrushkevich, Zakharov, Chesalov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Popova, G.Y., Andrushkevich, T.V., Zakharov, I.I. et al. Mechanism of carboxylic acid formation on vanadium-containing oxide catalysts. Kinet Catal 46, 217–226 (2005). https://doi.org/10.1007/s10975-005-0069-9

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10975-005-0069-9

Keywords

Search

Navigation