Skip to main content
SpringerLink
Log in

35S Tracer study of the effect of support nature on the dynamics of the active sites of CoMo and NiMo sulfide catalysts supported on Al 2O3 and activated carbon

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The influence of the support (Al2O3 and activated carbon) on the activity of Mo, NiMo, and CoMo catalysts in thiophene hydrogenolysis is studied using 35S as a tracer. The carbon-supported catalysts have more active sites than their alumina-supported counterparts, while the turnover frequencies of these sites are similar. Thiophene desulfurization and hydrogenation of the resulting C4 olefins take place at the same Mo sites. Tracer tests have demonstrated that the active sites in the catalysts examined are identical and that the support has an effect only on their concentration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. De Beer, V.H.J., Duchet, J.C., and Prins, R., J. Catal., 1981, vol. 72, p. 369.

    Google Scholar 

  2. Duchet, J.C., van Oers, E.M., de Beer, V.H.J., and Prins, R., J. Catal., 1983, vol. 80, p. 386.

    Google Scholar 

  3. Scheffer, B., Arnoldy, P., and Moulijn, J.A., J. Catal., 1988, vol. 112, p. 516.

    Google Scholar 

  4. Farag, H., Mochida, I., and Sakanishi, K., Appl. Catal., A, 2000, vol. 194, p. 147.

    Google Scholar 

  5. Hillerova, E., Vit, Z., and Zdrazil, M., Appl. Catal., 1991, vol. 67, p. 231.

    Google Scholar 

  6. Farag, H., Whitehurst, D.D., Sakanishi, K., and Mochida, I., Catal. Today, 1999, vol. 50, p. 9.

    Google Scholar 

  7. Bouwens, S.M.A.M., van Zon, F.B.M., van Dijk, M.P., van der Kraan, A.M., de Beer, V.H.J., van Veen, J.A.R., and Koningsberger, D.C., J. Catal., 1994, vol. 146, p. 375.

    Google Scholar 

  8. Laine, J., Labady, M., Severino, F., and Yunes, S., J. Catal., 1997, vol. 166, p. 384.

    Google Scholar 

  9. Severino, F., Laine, J., and Lopez-Agudo, A., J. Catal., 2004, vol. 188, p. 244.

    Google Scholar 

  10. Visser, J.P.R., de Beer, V.H.J., and Prins, R., J. Chem. Soc., Faraday Trans., 1987, vol. 1, no. 83, p. 277.

    Google Scholar 

  11. Visser, J.P.R., Scheffer, B., de Beer, V.H.J., Moulijn, J.A., and Prins, R., J. Catal., 1987, vol. 105, p. 277.

    Google Scholar 

  12. Bouwens, S.M.A.M., Koningsberger, D.C., de Beer, V.H.J., and Prins, R., Bull. Soc. Chim. Belg., 1987, vol. 96, p. 951.

    Google Scholar 

  13. Crajé, M.W.J., Ph. Doctoral Thesis, Delft: University of Technology, 1992.

    Google Scholar 

  14. Muralidhar, G., Concha, B.E., Bartholomew, G.L., and Bartholomew, C.H., J. Catal., 1984, vol. 89, p. 274.

    Google Scholar 

  15. Alstrup, I., Chorkendorff, I., Candia, R., Clausen, B.S., and Topsøe, H., J. Catal., 1982, vol. 77, p. 397.

    Google Scholar 

  16. Bouwens, S.M.A.M., Koningsberger, D.C., de Beer, V.H.J., and Prins, R., J. Phys. Chem., 1991, vol. 95, p. 123.

    Google Scholar 

  17. Van der Kraan, A.M., Craje, M.W.J., Gerkema, E., Ramselaar, W.L.T.M., and de Beer, V.H.J., Appl. Catal., 1988, vol. 39, p. 7.

    Google Scholar 

  18. Crajé, M.W.J., Louwers, S.P.A., de Beer, V.H.J., Prins, R., and van der Kraan, A.M., J. Phys. Chem., 1992, vol. 95, p. 5445.

    Google Scholar 

  19. Breysse, M., Bennett, B.A., Chadwick, D., and Vrinat, M., Bull. Soc. Chim. Belg., 1981, vol. 90, p. 1271.

    Google Scholar 

  20. Crajé, M.W.J., de Beer, V.H.J., and van der Kraan, A.M., Bull. Soc. Chim. Belg., 1991, vol. 108, p. 953.

    Google Scholar 

  21. Topsøe, H. and Clausen, B.S., Catal. Rev.—Sci. Eng., 1984, vol. 26, p. 395.

    Google Scholar 

  22. Topsøe, H. and Clausen, B.S., Appl. Catal., 1986, vol. 25, p. 273.

    Google Scholar 

  23. Candia, R., Villadsen, J., Topsøe, N.-Y., Clausen, B.S., and Topsøe, H., Bull. Soc. Chim. Belg., 1984, vol. 93, p. 763.

    Google Scholar 

  24. Pawelec, B., Mariscal, R., Fierro, J.L.G., Greenwood, A., and Vasudevan, P.T., Appl. Catal., A, 2001, vol. 206, p. 295.

    Google Scholar 

  25. Hensen, E.J.M., Brans, H.J.A., Lardinois, G.M.H.J., de Beer, V.H.J., van Veen, J.A.R., and van Santen, R.A., J. Catal., 2000, vol. 192, p. 98.

    Google Scholar 

  26. Sakanishi, K., Nagamatsu, T., Mochida, I., and Duayne Whitehurst, D., J. Mol. Catal. A: Chem., 2000, vol. 155, p. 101.

    Google Scholar 

  27. Ferrari, M., Maggi, R., Delmon, B., and Grange, P., J. Catal., 2001, vol. 198, p. 47.

    Google Scholar 

  28. Farag, H., Mochida, I., and Sakanishi, K., Appl. Catal., A, 2000, vols. 194–195, p. 147.

    Google Scholar 

  29. Lee, J.J., Han, S., Kim, H., Koh, J.H., Hyeon, T., and Moon, S.H., Catal. Today, 2003, vol. 86, p. 141.

    Google Scholar 

  30. Kogan, V.M., Rozhdestvenskaya, N.N., and Korshevets, I.K., Appl. Catal., A, 2002, vol. 234, p. 207.

    Google Scholar 

  31. Kogan, V.M., Parfenova, N.M., Gaziev, R.G., Rozhdestvenskaya, N.N., and Korshevets, I.K., Kinet. Katal., 2003, vol. 44, no. 4, p. 638.

    Google Scholar 

  32. Kogan, V.M., Gaziev, R.G., Lee, S.W., and Rozhdestvenskaya, N.N., Appl. Catal., A, 2003, vol. 251, p. 187.

    Google Scholar 

  33. Miciukiewicz, J. and Massoth, F.E., J. Catal., 1989, vol. 119, p. 531.

    Google Scholar 

  34. Kogan, V.M., Thi Dung Nguen, and Yakerson, V.I., Bull. Soc. Chim. Belg., 1995, vol. 104, p. 303.

    Google Scholar 

  35. Daage, M. and Chianelli, R.R., J. Catal., 1994, vol. 149, p. 414.

    Google Scholar 

  36. Kochubey, D.I. and Babenko, V.P., React. Kinet. Catal. Lett., 2002, vol. 77, no. 2, p. 237.

    Google Scholar 

  37. Lauritsen, J.V., Nyberg, M., Vang, R.T., Bollinger, M.V., Clausen, B.S., Topsøe, H., Jacobsen, K.W., Lægsgaard, E., Norskov, J.K., and Besenbacher, F., Nanotechnology, 2003, vol. 14, p. 385.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. M. Kogan

Authors
  1. V. M. Kogan
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Kinetika i Kataliz, Vol. 46, No. 1, 2005, pp. 85–96.

Original Russian Text Copyright © 2005 by Kogan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kogan, V.M. 35S Tracer study of the effect of support nature on the dynamics of the active sites of CoMo and NiMo sulfide catalysts supported on Al 2O3 and activated carbon. Kinet Catal 46, 77–87 (2005). https://doi.org/10.1007/s10975-005-0049-0

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10975-005-0049-0

Keywords

Search

Navigation