Abstract
It was found that VO2+, Fe3+, Co2+, and Cu2+ ions catalyze the reaction of O3 with Cl- in an acidic medium. The dependence of the rate of Cl2 liberation in the reaction of O3 with Cl- on the concentrations of H+, VO2+, Fe3+, Co2+, and Cu2+ ions in the reaction solution was studied. A reaction scheme was proposed to explain the experimentally found catalytic effects of these ions. The constants that characterize the steps of the proposed scheme were determined.
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Translated from Kinetika i Kataliz, Vol. 46, No. 1, 2005, pp. 147–152. Original Russian Text Copyright © 2005 by Levanov, Kuskov, Koiaidarova, Zosimov, Antipenko, Lunin.
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Levanov, A.V., Kuskov, I.V., Koiaidarova, K.B. et al. Catalysis of the reaction of ozone with chloride ions by metal ions in an acidic medium. Kinet Catal 46, 138–143 (2005). https://doi.org/10.1007/s10975-005-0021-z
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DOI: https://doi.org/10.1007/s10975-005-0021-z