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Exploring the impact of vanadium on physical, structural and thermal properties of bioactive glass 46S6: a comparative study with other metallic elements

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Abstract

Vanadium-doped quaternary bioactive glass systems 46 SiO2, (24–x/2) Na2O, (24–x/2) CaO, 6P2O5, xV, where x = 0, 0.5, 2.5, 2.8, and 5 mass% of vanadium through the use of V2O5 oxide, were successfully synthesized by the melt-quenching technique. Several physicochemical methods were employed to study the effects of vanadium on the physical, structural, and thermal properties of all doped bioactive glasses 46S6-xV. Density (ρg), molar volume (Vm), oxygen molar volume (VO), and oxygen packing density (OPD) variations were correlated with the decrease in compactness of the vitreous network upon the introduction of 2.8 mass% vanadium. Investigations revealed that the bioactive glass network is less polymerized with an increase in vanadium content up to 2.8 mass%. The thermal characteristics and excess entropy ΔSex of doped bioactive glasses were determined. Calculated thermal stability factors show the high forming ability of elaborated bioactive glass. The obtained results show that the introduction of 2.8 mass% of vanadium on the glass matrix induces a significant decrease in ∆Tg (49 K) and ∆Tf (250 K). Increases in excess entropy confirm that the presence of vanadium leads to a more disordered 46S6 glass matrix. The studied 46S6 glass exhibits better thermal properties when vanadium is incorporated, making it more useful for various industrial and technological applications.

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Acknowledgements

Authors would like to knowledge Christophe Calers from CMEBA and Nathalie Herbert from ISCR UMR CNRS 2662 for their precious help.

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Authors and Affiliations

  1. CNRS, ISCR-UMR 6226, Univ Rennes, 35000, Rennes, France

    Nada Hamrouni, Hassane Oudadesse, Bertrand Lefeuvre & Odile Merdrignac-Conanec

  2. Faculty of Sciences of Tunis, University of Tunis El Manar, Manar II, 2092, Tunis, Tunisia

    Nada Hamrouni

  3. LR01ES14 Laboratory of Environment Biomonitoring, Sciences Faculty of Bizerta, University of Carthage, 7021, Zarzouna, Tunisia

    Mossadok Ben-Attia

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  1. Nada Hamrouni
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  2. Hassane Oudadesse
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Hamrouni, N., Oudadesse, H., Lefeuvre, B. et al. Exploring the impact of vanadium on physical, structural and thermal properties of bioactive glass 46S6: a comparative study with other metallic elements. J Therm Anal Calorim 148, 13245–13261 (2023). https://doi.org/10.1007/s10973-023-12632-0

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