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Aliphatic saturated sulfones C6-C14: possible candidates for a new aprotic inert solvent: part 1: melting of individual substances

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Abstract

1H NMR, DSC and TG were used for investigating nine aliphatic sulfones. The most suitable solvent – diethyl ether – was used for its purification by recrystallisation. The thermal stability of these substances was studied; it is comparable to ethylene carbonate and can be increased by using a RSO2R' with (a) longer carbon chain in any R and R' and (b) linear R and/or R' instead of branched one(s). Melting parameters of 8 sulfones were obtained for the first time and the enthalpy and temperature of (n-C4H9)2SO2 were revised. Four of 9 sulfones have melting point below the room temperature. A C4 radical possibly is optimal to get a lower m.p. Melting point decreases in a row both linear R > both branched R ≥ one branched R. Additionally, the attempts to reevaluate SO2 increment value were made.

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Acknowledgements

This study was supported by the Russian Science Foundation (grant No. 19-73-10078). The work was performed at the User Facilities Center of M. V. Lomonosov Moscow State University with partial support from M. V. Lomonosov Moscow State University Program of Development. Thermoanalytical research was performed in the frame of theme «Chemical Thermodynamics and Theoretical Material Science» 121031300039-1. Authors are grateful to Badma Mankaev for registration of NMR spectra.

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Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, GSP-1, Leninskie Gory 1/3, Moscow, Russian Federation, 119991

    Ekaterina V. Belova, Julia D. Shakirova, Leonid A. Kulikov, Zoya V. Bobyleva & Irina A. Uspenskaya

  2. Department of Material Science, Lomonosov Moscow State University,, GSP-1, Leninskie Gory 1/73, Moscow, Russian Federation, 119991

    Zoya V. Bobyleva

Authors
  1. Ekaterina V. Belova
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  2. Julia D. Shakirova
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  3. Leonid A. Kulikov
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  4. Zoya V. Bobyleva
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  5. Irina A. Uspenskaya
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Contributions

EVB, JDS and ZVB contributed to the study conception and design. Material preparation, data collection and analysis were performed by JDS, EVB and LAK. The first draft of the manuscript was written by JDS and EVB and all authors commented on previous versions of the manuscript. Writing—review and editing, as well as supervision, was performed by IAU. ZVB contributed to funding acquisition. All authors read and approved the final manuscript.

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Correspondence to Ekaterina V. Belova.

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Belova, E.V., Shakirova, J.D., Kulikov, L.A. et al. Aliphatic saturated sulfones C6-C14: possible candidates for a new aprotic inert solvent: part 1: melting of individual substances. J Therm Anal Calorim 148, 5637–5646 (2023). https://doi.org/10.1007/s10973-023-12128-x

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  • DOI: https://doi.org/10.1007/s10973-023-12128-x

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