Abstract
In order to make strides the fire retardancy and warm conductivity of silicone rubber (VMQ), a simple synthesis process was used to grow β-FeOOH on the surface of Boron nitride (BN) to form a three-dimensional structure. The structure and morphology of the BN-β-FeOOH hybrid were systematically characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM), which proved the successful preparation of the hybrid BN-β-FeOOH. BN-β-FeOOH were added to VMQ to think about their impact on the warm solidness, combustion and warm conductivity of VMQ. Experimental results showed that the limiting oxygen index (LOI) of VMQ with three parts of BN-β-FeOOH increased to 29.8%, and the peak heat release rate (pHRR) and total heat release (THR) decreased by 34.5 and 30.2%. The flame-retardant performance of VMQ was significantly improved, and the emission of smoke was significantly reduced. At the same time, the thermal conductivity of the VMQ added with BN-β-FeOOH was also significantly improved. The improvement of its flame-retardant performance was due mainly to the physical barrier of boron nitride and the catalytic carbonization of β-FeOOH. In addition, the three-dimensional well-connected thermal conductivity network constructed by BN-β-FeOOH effectively improved the thermal conductivity of VMQ.
Similar content being viewed by others
References
Zhang W, Li X, Shan Z, Wang S, Xiao Y. Surface modification of magnesium hydroxide by wet process and effect on the thermal stability of silicone rubber. Appl Surf Sci. 2019;465:740–6.
Chen XL, Li M, Zhuo JL, Ma CY, Jiao CM. Influence of Fe2O3 on smoke suppression and thermal degradation properties in intumescent flame-retardant silicone rubber. J Therm Anal Calorim. 2016;123(1):439–48.
Zhang C, Wang J, Song S. Preparation of a novel type of flame retardant diatomite and its application in silicone rubber composites. Adv Powder Technol. 2019;30(8):1567–75.
Qi J, Wen Q, Zhu J, He T. Synthesis of a novel intumescent flame retardant based on phosphorus, nitrogen, and silicone, and application in VMQ. J Therm Anal Calorim. 2019;137(5):1549–57.
Kim Y, Hwang S, Choi J, Lee J, Yu K, Baeck S, et al. Valorization of fly ash as a harmless flame retardant via carbonation treatment for enhanced fire-proofing performance and mechanical properties of silicone composites. J Hazard Mater. 2020;404: 124202.
Song P, Song J, Zhang Y. Stretchable conductor based on carbon nanotube/carbon black silicone rubber nanocomposites with highly mechanical, electrical properties and strain sensitivity. Compos Part B-Eng. 2020;191: 107979.
Liu P, Li L, Wang L, Huang T, Yao Y, Xu W. Effects of 2D boron nitride (BN) nanoplates filler on the thermal, electrical, mechanical and dielectric properties of high temperature vulcanized silicone rubber for composite insulators. J Alloy Compd. 2019;774:396–404.
Cai W, Feng X, Wang B, Hu W, Yuan B, Hong N, et al. A novel strategy to simultaneously electrochemically prepare and functionalize graphene with a multifunctional flame retardant. Chem Eng J. 2017;316:514–24.
Wang J, Zhou H, Wang Z, Bai W, Cao Y, Wei Y. Constructing hierarchical structure based on LDH anchored boron-doped g-C3N4 assembled with MnO2 nanosheets towards reducing toxicants generation and fire hazard of epoxy resin. Compos Part B-Eng. 2020;229: 109453.
Gan W, Chen C, Wang Z, Pei Y, Ping W, Xiao S, et al. Fire-resistant structural material enabled by an anisotropic thermally conductive hexagonal boron nitride coating. Adv Funct Mater. 2020;30(10):1909196.
Xu W, Li A, Liu Y, Chen R, Li W. CuMoO4@hexagonal boron nitride hybrid: an ecofriendly flame retardant for polyurethane elastomer. J Mater Sci. 2018;53(16):11265–79.
Yin S, Ren X, Lian P, Zhu Y, Mei Y. Synergistic effects of black phosphorus/boron nitride nanosheets on enhancing the flame-retardant properties of waterborne polyurethane and its flame-retardant mechanism. Polymers. 2020;12(7):E1487.
Qiu S, Hou Y, Xing W, Ma C, Zhou X, Liu L, et al. Self-assembled supermolecular aggregate supported on boron nitride nanoplatelets for flame retardant and friction application. Chem Eng J. 2018;349:223–34.
Wang N, Zhou M, Zhang J, Fang Q. Modified boron nitride as an efficient synergist to flame retardant natural rubber: preparation and properties. Polym Advan Technol. 2020;31(9):1887–95.
Chen T, Wang X, Peng C, Chen G, Yuan C, Xu Y, et al. Efficient flame retardancy, smoke suppression, and mechanical enhancement of β-FeOOH@Metallo-supramolecular polymer core-shell nanorod modified epoxy resin. Macromol Mater Eng. 2020;305(10):1–12.
Chen X, Jiang Y, Jiao C. Smoke suppression properties of ferrite yellow on flame retardant thermoplastic polyurethane based on ammonium polyphosphate. J Hazard Mater. 2014;266:114–21.
Zhang L, He Y, Ma L, Chen J, Fan Y, Zhang S, et al. Hierarchically stabilized PAN/β-FeOOH nanofibrous membrane for efficient water purification with excellent antifouling performance and robust solvent resistance. ACS Appl Mater Inter. 2019;11(37):34487–96.
Wang W, Pan H, Shi Y, Yu B, Pan Y, Kim M, et al. Sandwich-like coating consisting of alternating montmorillonite and β-FeOOH for reducing the fire hazard of flexible polyurethane foam. ACS Sustain Chem Eng. 2015;3(12):3214–23.
Ruan K, Shi X, Guo Y, Gu J. Interfacial thermal resistance in thermally conductive polymer composites: a review. Compos Commun. 2020;22: 100518.
Ji C, Yan C, Wang Y, Xiong S, Zhou F, Li Y, et al. Thermal conductivity enhancement of CNT/MoS2/graphene−epoxy nanocomposites based on structural synergistic effects and interpenetrating network. Compos Part B-Eng. 2019;163:363–70.
Yu B, Xing W, Guo W, Qiu S, Wang X, Lo S, et al. Thermal exfoliation of hexagonal boron nitride for effective enhancements on thermal stability, flame retardancy and smoke suppression of epoxy resin nanocomposites via sol–gel process. J Mater Chem A. 2016;4(19):7330–40.
Fang H, Lin J, Zhang L, Chen A, Wu F, Geng L, et al. Fibrous form-stable phase change materials with high thermal conductivity fabricated by interfacial polyelectrolyte complex spinning. Carbohyd Polym. 2020;249: 116836.
Song X, Boily J. Carbon dioxide binding at dry FeOOH mineral surfaces: evidence for structure-controlled speciation. Environ Sci Technol. 2013;47(16):9241–8.
Imtiaz M, Chen Z, Zhu C, Pan H, Zada I, Li Y, et al. In situ growth of β-FeOOH on hierarchically porous carbon as anodes for high-performance lithium-ion batteries. Electrochim Acta. 2018;283:401–9.
Tu L, Xiao Q, Wei R, Liu X, et al. Fabrication and enhanced thermal conductivity of boron nitride and polyarylene ether nitrile hybrids. Polymers (Basel). 2019;11(8):1340.
Zhao M, Feng Y, Li Y, Li G, Wang Y, Han Y, et al. Preparation and performance of Phenyl-Vinyl-POSS/Addition-type curable silicone rubber hybrid material. J Macromol Sci A. 2014;51(8):639–45.
Wu T, Qiu J, Lai X, Li H, Zeng X. Effect and mechanism of hepta-phenyl vinyl polyhedral oligomeric silsesquioxane on the flame retardancy of silicone rubber. Polym Degrad Stabil. 2019;159:163–73.
Xu Q, Jin C, Majlingova A, Restas A. Discuss the heat release capacity of polymer derived from microscale combustion calorimeter. J Therm Anal Calorim. 2017;133(1):649–57.
Li A, Xu W, Chen R, Liu Y, Li W. Fabrication of zeolitic imidazolate frameworks on layered double hydroxide nanosheets to improve the fire safety of epoxy resin. Compos Part A-Appl S. 2018;112:558–71.
Xu W, Wang X, Wu Y, Li W, Chen C. Functionalized graphene with Co-ZIF adsorbed borate ions as an effective flame retardant and smoke suppression agent for epoxy resin. J Hazard Mater. 2019;363:138–51.
Cao L, Zheng A, Cao X, Yuan D, Xu C, Chen Y. Morphology and non-isothermal crystallization of dynamically vulcanized PP/EPDM blends in situ compatibilized via magnesium dimethacrylate. Polym Test. 2017;62:68–78.
Zhang X, Yi J, Yin Y, Song Y, Xiong C. Thermal conductivity and electrical insulation properties of h-BN@PDA/silicone rubber composites. Diam Relat Mater. 2021;117: 108485.
Taiyo, Shimizu Ryoichi, Kishi Kazufumi, Kobashi Takahiro, Morimoto Toshiya, Okazaki Takeo, Yamada Kenji, Hata Improved thermal stability of silicone rubber nanocomposites with low filler content achieved by well-dispersed carbon nanotubes. Composites Communications (2020); 221:100482. https://doi.org/10.1016/j.coco.2020.100482
Acknowledgements
The authors express their gratitude to the Natural Science Research Project of Colleges and Universities in Anhui Province (KJ2021A0627,KJ2020JD12) and the Anhui Provincial Natural Science Foundation (2208085ME114) for their support.
Author information
Authors and Affiliations
Contributions
WX was involved in conceptualization. WX and LF were responsible for writing, reviewing and editing, and methodology. JW contributed to resources. WX and MQ performed supervision. YZ, YZ and MQ carried out investigation.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Xu, W., Fan, L., Wang, J. et al. Preparation of three-dimensional modified boron nitride and its effect on the flame-retardant performance and thermal conductivity of silicone rubber. J Therm Anal Calorim 148, 1133–1147 (2023). https://doi.org/10.1007/s10973-022-11830-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-022-11830-6