Abstract
Linear and weakly nonlinear stability analyses of double-diffusive convection in two-component liquids with either potassium chloride (KCl) or sodium chloride (NaCl) aqueous solution, and heat being present is investigated in the paper for free, and rigid, isothermal, iso-solutal boundaries. Using the thermophysical values of the aqueous solutions, we have shown that the stationary convection is the preferred mode at onset and that sub-critical motion is possible. We found that the critical thermal Rayleigh number for water + NaCl + heat is higher compared to that of water + KCl+ heat. The study shows that for water + KCl + heat, the transition from convective motion to chaotic motion occurs at \(r_{\mathrm{H}}=27.2\) for free boundaries and at 48.5 for rigid boundaries. Here, \(r_{\mathrm{H}}\) denotes the Hopf thermal Rayleigh number. Further, the existence of windows of mildly chaotic points and fully periodic intervals are reported using Lyapunov exponents and bifurcation diagrams. Chaotic motions in both the aqueous solutions are nearly identical. The percentage increase in heat transport in the double-diffusive system involving NaCl is nearly 1% more than that of KCl in the case of free boundaries, whereas in the case of realistic boundaries it is nearly 1.6%. The comparison of the Nusselt and the Sherwood numbers between water + KCl and water + NaCl leads us to the conclusion that the aqueous solution with lower Lewis number transports maximum heat in the case of free boundaries and opposite is seen in the case of rigid boundaries due to the boundary effect. The many qualitative similarities between the results of artificial and realistic boundaries are highlighted.
Similar content being viewed by others
Change history
25 March 2022
The fourth author’s affiliation was incorrectly published as 1, 4. The corrected affiliation of fourth author is 4 which was corrected.
References
Turner JS. Double-diffusive phenomena. Annu Rev Fluid Mech. 1974;6:37–56.
Turner JS. Double-diffusive intrusions into a density gradient. J Geophys Res. 1978;83:2887–901.
Turner JS, Gustafson LB. Fluid motions and compositional gradients produced by crystallization or melting at vertical boundaries. J Volcanol Geotherm Res. 1981;11:9S125.
Huppert HE. On the stability of a series of double-diffusive layers. Deep Sea Res. 1971;18:1005–21.
Huppert HE. Multicomponent convection: turbulence in Earth. Sun Sea Nat. 1983;303:478–9.
Stern ME. Collective instability of salt fingers. J Fluid Mech. 1969;35:209–28.
Holyer JY. On the collective stability of salt fingers. J Fluid Mech. 1981;110:195–207.
Veronis G. On finite amplitude instability in thermohaline convection. J Mater Res. 1965;23:1–17.
Veronis G. Effect of a stabilizing gradient of solute on thermal convection. J Fluid Mech. 1968;34:315–36.
Huppert HE, Moore DR. Nonlinear double-diffusive convection. J Fluid Mech. 1976;78:821–54.
Proctor RE. Steady subcritical thermohaline convection. J Fluid Mech. 1981;105:507–21.
Knobloch E, Proctor MRE. Nonlinnear double-diffusive convection. J Fluid Mech. 1981;108:291–316.
Trevor JM. Double-diffusive convection caused by coupled molecular diffusion. J Fluid Mech. 1983;126:379–97.
Platten JK. Soret effects. University of Mons, B7000 Mons, Belgium.
Rudraiah N, Siddheshwar PG. A weak nonlinear stability analysis of double diffusive convection with cross diffusion in a fluid saturated porous medium. Heat Mass Transf. 1998;33:287–93.
Malashetty MS, Gaikwad SN, Swamy M. An analytical study of linear and non-linear double diffusive convection with Soret effect in couple stress liquids. Int J Therm Sci. 2006;45:897–907.
Andereck CD, Colovas PW, Degen MM, Renardy YY. Instabilities in two layer Rayleigh–Bénard convection: overview and outlook. Int J Eng Sci. 1998;36:1451–70.
Siddheshwar PG, Pranesh S. An analytical study of linear and non-linear convection in Boussinesq–Stokes suspensions. Int J Nonlinear Mech. 2004;39:165–72.
Narayana M, Gaikwad SN, Sibanda P, Malge RB. Double diffusive magneto-convection in viscoelastic fluids. Int J Heat Mass Transf. 2013;67:194–201.
Siddheshwar PG, Kanchana C, Kakimoto Y, Nakayama A. Steady finite amplitude Rayleigh–Bénard convection in nanoliquids using a two-phase model-theoretical answer to the phenomenon of enhanced heat transfer. ASME J Heat Transf. 2016;139:012402.
Siddheshwar PG, Kanchana C. Unicellular unsteady Rayleigh–Bénard convection in Newtonian liquids and Newtonian nanoliquids occupying enclosures: new findings. Int J Mech Sci. 2017;131–132:1061–72.
Kanchana C, Zhao Y. Effect of internal heat generation/absorption on Rayleigh–Bénard convection in water well-dispersed with nanoparticles or carbon nanotubes. Int J Heat Mass Transf. 2018;127:1031–47.
Siddheshwar PG, Kanchana C. Effect of trigonometric sine, square and triangular wave-type time-periodic gravity-aligned oscillations on Rayleigh–Bénard convection in Newtonian liquids and Newtonian nanoliquids. Meccanica. 2019;54:451–69.
Ravi R, Kanchana C, Siddheshwar PG. Effect of second diffusing component and cross diffusion on primary and secondary thermoconvective instabilities in couple stress liquids. Appl Math Mech. 2017;38:1579–600.
Lakshmi KM, Siddheshwar PG. Unsteady finite amplitude convection of water-copper nanoliquid in high-porosity enclosures. ASME J Heat Transf. 2019;141:062405.
Siddheshwar PG, Shivakumara BN, Zhao Y, Kanchana C. Rayleigh–Bénard convection in a Newtonian liquid bounded by rigid isothermal boundaries. Appl Math Comput. 2019;371:124942.
Kanchana C, Siddheshwar PG, Zhao Y. A study of Rayleigh–Bénard convection in hybrid nanoliquids with physically realistic boundaries. Eur Phy J Spec Top. 2019;228:2511–30.
Kanchana C, Siddheshwar PG, Zhao Y. Regulation of heat transfer in Rayleigh-Bénard convection in Newtonian liquids and Newtonian nanoliquids using gravity, boundary temperature and rotational modulations. J Therm Anal Calorim. 2020. https://doi.org/10.1007/s10973-020-09325-3.
Mutabazi I, Wesfreid JE, Guyon E. Dynamics of spatio-temporal cellular structures—Henri Bénard centenary review. New York: Springer; 2006.
Aurnou JM, Olson PL. Experiments on Rayleigh–Bénard convection, magnetoconvection and rotating magnetoconvection in liquid gallium. J Fluid Mech. 2001;430:283–307.
Ginde RM, Gill WN, Verhoeven JD. An experimental study of Rayleigh–Bénard convection in liquid Tin. Chem Eng Commun. 1989;82:223–8.
Bergé P, Dubois M. Rayleigh–Bénard convection. Contemp Phys. 1984;25:535–82.
Li Z, Sarafraz MM, Mazinami A, Hayat T, Alsulami H, Goodarzi M. Pool boiling heat transfer to \(CuO{-}H_{2}O\) nanofluid on finned surfaces. Int J Heat Mass Transf. 2020;156:119780.
Gerla PE, Rubiolo AC. A model for determination of multicomponent diffusion coefficients in foods. J Food Eng. 2003;56:401–10.
Radko T. Double-diffusive convection. Cambridge: Cambridge University Press; 2013.
Vélez-Ruiz JF. Mass transfer in cheese. In: El-Amin M., editor. Advanced topics in mass transfer. Saudi Arabia. 2011. p. 355–70.
Zaytsev ID, Aseyev GG. Properties of aqueous solutions of electrolytes. London: CRC Press; 1992.
Carvalho GR, Chenlo F, Moreira R, Telis-Romero J. Physicothermal properties of aqueous sodium chloride solutions. J Food Process Eng. 2015;38:234–42.
Lorenz EN. Deterministic nonperiodic flow. J Atmos Sci. 1963;20:130–41.
Loncin M, Merson RL. Food engineering principles and selected applications. New York: Academic Press; 1979.
Chandrasekhar S. Hydrodynamic and hydromagnetic stability. New York: Oxford University Press; 1961.
Kanchana C, Siddheshwar PG, Zhao Y. The effect of boundary conditions on the onset of chaos in Rayleigh–Bénard convection using energy-conserving Lorenz models. Appl Math Model. 2020;88:349–66.
Saltzman EN. Finite amplitude free convection as an initial value problem—I. J Atmos Sci. 1962;19:329–41.
Rayleigh L. On convection currents in a horizontal layer of fluid when the higher temperature is on the under side. Philos Mag Ser. 1916;32:529–46.
Malkus WVR, Veronis G. Finite amplitude cellular convection. J Fluid Mech. 1958;38:227–60.
Pranesh S, Siddheshwar PG, Tarannum S, Yekasi V. Convection in a horizontal layer of water with three diffusing components. SN Appl Sci. 2020;2:806.
Kanchana C, Su Y, Zhao Y. Regular and chaotic Rayleigh–Bénard convective motions in methanol and water. Commun Nonlinear Sci Numer Simul. 2020;83:105129.
Kunnen RJP, Monico RO, Van der Poel EP, Lohse D. Transition to geostrophic convection: the role of the boundary conditions. J Fluid Mech. 2016;799:413–32.
Siddheshwar PG, Titus PS. Nonlinear Rayleigh–Bénard convection with variable heat source. ASME J Heat Transf. 2013;135:122502.
Acknowledgements
The author(KC) is grateful to the Universidad de Tarapacá, Chile for supporting her research work with the University of Tarapaca, Arica (UTA) Fellowship. The author BS expresses his gratitude to Jawaharlal Nehru Technological University College of Engineering, Hyderabad (JNTUCEH) for financial support under Technical Education Quality Improvement Program (TEQIP)-3 for a year. The authors are grateful to the Reviewers and the Editor for their most valuable comments.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Kanchana, C., Siddheshwar, P.G., Shanker, B. et al. Convective heat and mass transports and chaos in two-component systems: comparison of results of physically realistic boundary conditions with those of artificial ones. J Therm Anal Calorim 147, 3247–3266 (2022). https://doi.org/10.1007/s10973-021-10662-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-021-10662-0