Abstract
In this work, biodegradable poly(lactic acid) (PLA)/Ti3C2Tx MXene nanocomposites were prepared through melt compounding. The roles of MXene in nonisothermal melt and cold crystallization of PLA were explored. The morphology, structure and crystallization behavior were studied using polarized optical microscopy, wide-angle X-ray diffraction and differential scanning calorimetry. For nonisothermal melt crystallization, the presence of MXene increases the crystallinity and shortens the half-crystallization time but does not change the crystallization peak temperature of PLA. For nonisothermal crystallization from the glassy state, the incorporation of MXene decreases the cold crystallization peak temperature and reduces the crystallinity marginally but does not affect the half-crystallization time of PLA. The crystallization kinetics analysis based on the Avrami equation shows that, for both the melt and cold crystallization, the crystallization mechanism is unchanged irrespective of the addition of MXene. The investigation would be useful for understanding the correlation between processing and properties of PLA/MXene nanocomposites.
Similar content being viewed by others
Data availability
The datasets used or analyzed during the current study are available from the corresponding author on reasonable request.
References
Castro-Aguirre E, Iñiguez-Franco F, Samsudin H, Fang X, Auras R. Poly(lactic acid)—mass production, processing, industrial applications, and end of life. Adv Drug Deliv Rev. 2016;107:333–66.
dos Santos Silva ID, Schäfer H, Jaques NG, Siqueira DD, Ries A, de Souza Morais DD. An investigation of PLA/Babassu cold crystallization kinetics. J Therm Anal Calorim. 2019;141:1389–97.
Díaz-Díaz AM, López-Beceiro J, Li Y, Cheng Y, Artiaga R. Crystallization kinetics of a commercial poly(lactic acid) based on characteristic crystallization time and optimal crystallization temperature. J Therm Anal Calorim. 2020. https://doi.org/10.1007/s10973-020-10081-7.
Zhao Y, Zhu B, Wang Y, Liu C, Shen C. Effect of different sterilization methods on the properties of commercial biodegradable polyesters for single-use, disposable medical devices. Mater Sci Eng C. 2019;105:110041.
Wu B, Zeng Q, Niu D, Yang W, Dong W, Chen M, et al. Design of supertoughened and heat-resistant PLLA/Elastomer blends by controlling the distribution of stereocomplex crystallites and the morphology. Macromolecules. 2019;52:1092–103.
Zhu B, Wang Y, Liu H, Ying J, Liu C, Shen C. Effects of interface interaction and microphase dispersion on the mechanical properties of PCL/PLA/MMT nanocomposites visualized by nanomechanical mapping. Compos Sci Technol. 2020;190:108048.
Saeidlou S, Huneault MA, Li H, Park CB. Poly(lactic acid) crystallization. Prog Polym Sci. 2012;37:1657–77.
Wang Y, Li M, Shen C. Effect of constrained annealing on the microstructures of extrusion cast polylactic acid films. Mater Lett. 2011;65:3525–8.
Wang Y, Li M, Wang K, Shao C, Li Q, Shen C. Unusual structural evolution of poly(lactic acid) upon annealing in the presence of an initially oriented mesophase. Soft Matter. 2014;10:1512–8.
Lim LT, Auras R, Rubino M. Processing technologies for poly(lactic acid). Prog Polym Sci. 2008;33:820–52.
Xu Y, Wang Y, Xu T, Zhang J, Liu C, Shen C. Crystallization kinetics and morphology of partially melted poly(lactic acid). Polym Test. 2014;37:179–85.
Zhang H, Shao C, Kong W, Wang Y, Cao W, Liu C, et al. Memory effect on the crystallization behavior of poly(lactic acid) probed by infrared spectroscopy. Eur Polym J. 2017;91:376–85.
Wei Z, Shao S, Sui M, Song P, He M, Xu Q, et al. Development of zinc salts of amino acids as a new class of biocompatible nucleating agents for poly(l-lactide). Eur Polym J. 2019;118:337–46.
Kong W, Tong B, Ye A, Ma R, Gou J, Wang Y, et al. Crystallization behavior and mechanical properties of poly(lactic acid)/poly(ethylene oxide) blends nucleated by a self-assembly nucleator. J Therm Anal Calorim. 2018;135:3107–14.
Kong W, Zhu B, Su F, Wang Z, Shao C, Wang Y, et al. Melting temperature, concentration and cooling rate-dependent nucleating ability of a self-assembly aryl amide nucleator on poly(lactic acid) crystallization. Polymer. 2019;168:77–85.
Zhang H, Wang S, Zhang S, Ma R, Wang Y, Cao W, et al. Crystallization behavior of poly(lactic acid) with a self-assembly aryl amide nucleating agent probed by real-time infrared spectroscopy and X-ray diffraction. Polym Test. 2017;64:12–9.
Zhang R, Wang Y, Wang K, Zheng G, Li Q, Shen C. Crystallization of poly(lactic acid) accelerated by cyclodextrin complex as nucleating agent. Polym Bull. 2012;70:195–206.
Han Q, Wang Y, Shao C, Zheng G, Li Q, Shen C. Nonisothermal crystallization kinetics of biodegradable poly(lactic acid)/zinc phenylphosphonate composites. J Compos Mater. 2013;48:2737–46.
Wang Y, He D, Wang X, Cao W, Li Q, Shen C. Crystallization of poly(lactic acid) enhanced by phthalhydrazide as nucleating agent. Polym Bull. 2013;70:2911–22.
Barrau S, Vanmansart C, Moreau M, Addad A, Stoclet G, Lefebvre JM, et al. Crystallization behavior of carbon nanotube-polylactide nanocomposites. Macromolecules. 2011;44:6496–502.
Bai T, Zhu B, Liu H, Wang Y, Song G, Liu C, et al. Biodegradable poly(lactic acid) nanocomposites reinforced and toughened by carbon nanotubes/clay hybrids. Int J Biol Macromol. 2020;151:628–34.
Li Y, Wang Y, Liu L, Han L, Xiang F, Zhou Z. Crystallization improvement of poly(L-lactide) induced by functionalized multiwalled carbon nanotubes. J Polym Sci Part B Polym Phys. 2009;47:326–39.
Xu J, Chen T, Yang C, Li Z, Mao Y, Zeng B, et al. Isothermal crystallization of poly(L-lactide) induced by graphene nanosheets and carbon nanotubes: a comparative study. Macromolecules. 2010;43:5000–8.
Wu D, Cheng Y, Feng S, Yao Z, Zhang M. Crystallization behavior of polylactide/graphene composites. Ind Eng Chem Res. 2013;52:6731–9.
Zeng Q, Wang Y, Wang Y, Cao W, Liu C, Shen C. Polyethylene oxide-assisted dispersion of graphene nanoplatelets in poly(lactic acid) with enhanced mechanical properties and crystallization ability. Polym Test. 2019;78:106008.
Naguib M, Mochalin VN, Barsoum MW, Gogotsi Y. 25th anniversary article: MXenes: a new family of two-dimensional materials. Adv Mater. 2014;26:992–1005.
Gao L, Li C, Huang W, Mei S, Lin H, Ou Q, et al. MXene/polymer membranes: synthesis, properties, and emerging applications. Chem Mater. 2020;32(5):1703–47.
Shi Y, Liu C, Liu L, Fu L, Yu B, Lv Y, et al. Strengthening, toughing and thermally stable ultra-thin MXene nanosheets/polypropylene nanocomposites via nanoconfinement. Chem Eng J. 2019;378:122267.
Ling Z, Ren C, Zhao M, Yang J, Giammarco JM, Qiu J, et al. Flexible and conductive MXene films and nanocomposites with high capacitance. Proc Natl Acad Sci. 2014;111:16676–81.
Naguib M, Saito T, Lai S, Rager MS, Aytug T, Parans Paranthaman M, et al. Ti3C2Tx(MXene)–polyacrylamide nanocomposite films. RSC Adv. 2016;76:72069–73.
Luo J, Zhao S, Zhang H, Deng Z, Li L, Yu Z. Flexible, stretchable and electrically conductive MXene/natural rubber nanocomposite films for efficient electromagnetic interference shielding. Compos Sci Technol. 2019;182:107754.
Zhao M, Ren C, Ling Z, Lukatskaya MR, Zhang C, Van Aken KL, et al. Flexible MXene/carbon nanotube composite paper with high volumetric capacitance. Adv Mater. 2015;27:339–45.
Zhang H, Wang L, Chen Q, Li P, Zhou A, Cao X, et al. Preparation, mechanical and anti-friction performance of MXene/polymer composites. Mater Des. 2016;92:682–9.
Chen K, Chen Y, Deng Q, Jeong SH, Jang T, Du S, et al. Strong and biocompatible poly(lactic acid) membrane enhanced by Ti3C2Tz (MXene) nanosheets for guided bone regeneration. Mater Lett. 2018;229:114–7.
Yi Z, Yang J, Liu X, Mao L, Cui L, Liu Y. Enhanced mechanical properties of poly(lactic acid) composites with ultrathin nanosheets of MXene modified by stearic acid. J Appl Polym Sci. 2019;137:48621.
Guo Y, Zhong M, Fang Z, Wan P, Yu G. A wearable transient pressure sensor made with MXene nanosheets for sensitive broad-range human-machine interfacing. Nano Lett. 2019;19:1143–50.
Liu G, Zhang X, Wang D. Tailoring crystallization: towards high-performance poly(lactic acid). Adv Mater. 2014;26:6905–11.
Xu J, Zhong G, Hsiao BS, Fu Q, Li Z. Low-dimensional carbonaceous nanofiller induced polymer crystallization. Prog Polym Sci. 2014;39:555–93.
Huang Z, Wang S, Kota S, Pan Q, Barsoum MW, Li C. Structure and crystallization behavior of poly(ethylene oxide)/Ti3C2Tx MXene nanocomposites. Polymer. 2016;102:119–26.
Liang L, Han G, Li Y, Zhao B, Zhou B, Feng Y, et al. Promising Ti3C2Tx MXene/Ni chain hybrid with excellent electromagnetic wave absorption and shielding capacity. ACS Appl Mater Interfaces. 2019;11:25399–409.
Liang L, Yang R, Han G, Feng Y, Zhao B, Zhang R, et al. Enhanced electromagnetic wave-absorbing performance of magnetic nanoparticles-anchored 2D Ti3C2Tx MXene. ACS Appl Mater Interfaces. 2020;12:2644–54.
Tarrío-Saavedra J, López-Beceiro J, Naya S, Artiaga R. Effect of silica content on thermal stability of fumed silica/epoxy composites. Polym Degrad Stab. 2008;93:2133–7.
Cavallo D, Gardella L, Alfonso GC, Mileva D, Androsch R. Effect of comonomer partitioning on the kinetics of mesophase formation in random copolymers of propene and higher α-olefins. Polymer. 2012;53:4429–37.
Refaa Z, Boutaous M, Xin S, Siginer DA. Thermophysical analysis and modeling of the crystallization and melting behavior of PLA with talc: kinetics and crystalline structures. J Therm Anal Calorim. 2017;128:687–98.
Kalish JP, Aou K, Yang X, Hsu SL. Spectroscopic and thermal analyses of α′ and α crystalline forms of poly(L-lactic acid). Polymer. 2011;52:814–21.
Shen C, Wang Y, Li M, Hu D. Crystal modifications and multiple melting behavior of poly(L-lactic acid-co-D-lactic acid). J Polym Sci Part B Polym Phys. 2011;49:409–13.
He D, Wang Y, Shao C, Zheng G, Li Q, Shen C. Effect of phthalimide as an efficient nucleating agent on the crystallization kinetics of poly(lactic acid). Polym Test. 2013;32:1088–93.
Avrami M. Kinetics of phase change. II transformation-time relations for random distribution of nuclei. J Chem Phys. 1940;8:212–24.
Avrami M. Granulation, phase change, and microstructure kinetics of phase change. J Chem Phys. 1941;9:177–84.
Lorenzo AT, Arnal ML, Albuerne J, Muller AJ. DSC isothermal polymer crystallization kinetics measurements and the use of the Avrami equation to fit the data: guidelines to avoid common problems. Polym Test. 2007;26:222–31.
Jeziorny A. Parameters characterizing the kinetics of the non-isothermal crystallization of poly(ethylene terephthalate) determined by DSC. Polymer. 1978;19:1142–4.
Xu T, Wang Y, Han Q, He D, Li Q, Shen C. Nonisothermal crystallization kinetics of poly(lactic acid) nucleated with a multiamide nucleating agent. J Macromol Sci Part B Phys. 2014;53:1680–94.
Yu J, Qiu Z. Isothermal and nonisothermal cold crystallization behaviors of biodegradable poly(L-lactide)/octavinyl-polyhedral oligomeric silsesquioxanes nanocomposites. Ind Eng Chem Res. 2011;50:12579–86.
Haji Abdolrsaouli M, Babaei A, Kaschta J, Nazockdat H. Polylactide/organoclay nanocomposites: the effect of organoclay types on the structure development and the kinetic of cold crystallization. J Vinyl Addit Technol. 2018;25:48–58.
Wang Y, Funari SS, Mano JF. Influence of semicrystalline morphology on the glass transition of poly(L-lactic acid). Macromol Chem Phys. 2006;207:1262–71.
Acknowledgements
This work is financially supported by the National Natural Science Foundation of China (52073261, U1704162), and the 111 Project (D18023).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Zhao, Q., Wang, B., Qin, C. et al. Nonisothermal melt and cold crystallization behaviors of biodegradable poly(lactic acid)/Ti3C2Tx MXene nanocomposites. J Therm Anal Calorim 147, 2239–2251 (2022). https://doi.org/10.1007/s10973-020-10502-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-020-10502-7