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Crystal growth of La2SrB10O19 from undercooled melt

Journal of Thermal Analysis and Calorimetry volume 146, pages 1569–1576 (2021)Cite this article

Abstract

The crystal growth rate of La2SrB10O19 in an undercooled melt of stoichiometric composition was studied. The crystallization of the bulk samples was performed in a single-stage regime under isothermal conditions at the selected temperatures for the different time periods. The surface crystallization was observed and in all crystallized samples, the La2SrB10O19 crystalline phase was identified. Based on the dependence of the crystalline layer thickness on treatment time at selected temperature, crystal growth rate was obtained. The crystal growth rates were from 1.65 × 10−8 to 2.77 × 10−7 m s−1 in the temperature interval (700–780 °C). The experimental values were compared to the calculated values using theoretical model of the crystal growth. The experimental growth rate followed the same trend as the calculated growth rate, but the experimental values were higher than the calculated.

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Acknowledgements

This work was supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (Contract No. 451-03-68/2020-14/200135 and 451-03-68/2020-14/200023).

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Authors and Affiliations

  1. Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000, Belgrade, Serbia

    Sonja V. Smiljanić & Snežana R. Grujić

  2. Institute for the Technology of Nuclear and Other Mineral Raw Materials, 86 Franchet d’Esperey St, 11000, Belgrade, Serbia

    Srđan Matijašević, Jovica Stojanović, Jelena Nikolić & Veljko Savić

  3. Innovation Center of the Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000, Belgrade, Serbia

    Daniela Ž. Popović

Authors
  1. Sonja V. Smiljanić
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  2. Snežana R. Grujić
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  3. Srđan Matijašević
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  4. Jovica Stojanović
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  5. Jelena Nikolić
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All authors listed have made a significant contribution to the research reported and have read and approved the submitted manuscript, and furthermore, all those who made substantive contributions to this work have been included in the author list.

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Correspondence to Sonja V. Smiljanić.

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Smiljanić, S.V., Grujić, S.R., Matijašević, S. et al. Crystal growth of La2SrB10O19 from undercooled melt. J Therm Anal Calorim 146, 1569–1576 (2021). https://doi.org/10.1007/s10973-020-10122-1

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