Abstract
Energy storage plays an important role in improving the applicability of a wide range of energy systems. Buildings could be considered as a desirable place for this purpose. Incorporating phase change materials (PCMs) as form-stable composites into the building materials has been widely taken into consideration in recent years. However, there are still some shortcomings in applying this technique. In this study, we focused on a surface modification method to prevent leakage of PCM from porous aggregates during heating/cooling cycles. Paraffin (PA) as phase change material was impregnated into the expanded perlite (EP) particles by vacuum impregnation method, and prepared EP/PA composite was coated by a layer of polystyrene. Thermal characterization of obtained composite samples was conducted by DSC and TG analysis. Also, a simple apparatus was prepared to evaluate thermal behavior of a concrete block made by these modified form-stable PCMs during the heating process. Oozing circle method and visual observation for leakage were conducted for surface-modified EP/PA particles and final concrete blocks, respectively. Finally, compressive strength test was applied to evaluate the feasibility of using concretes made by EP/PA composites as structural concrete. The results showed that using polystyrene as a coating material for EP/PA particles was a promising method for PCM leakage prevention. Latent heat value decreased about 18% for surface-modified EP/PA but no leakage trace was observed; also in spite of decreasing in compressive strength up to 40%, it is still in acceptable range for structural purposes.
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References
Hawes DW, Feldman D, Banu D. Latent heat storage in building materials. Energy Build. 1993;20(1):77–86.
Abuelnuor AA, Omara AAM, Saqr KM, Elhag IHI. Improving indoor thermal comfort by using phase change materials: a review. Int J Energy Res. 2018;42(6):2084–103.
Hawes DW, Banu D, Feldman D. Latent heat storage in concrete. Sol Energy Mater. 1989;19(3–5):335–48.
Memon SA. Phase change materials integrated in building walls: a state of the art review. Renew Sustain Energy Rev. 2014;31:870–906.
Schossig P, Henning HM, Gschwander S, Haussmann T. Micro-encapsulated phase-change materials integrated into construction materials. Sol Energy Mater Sol Cell. 2005;89(2):297–306.
Sarı A, Karaipekli A, Kaygusuz K. Capric acid and stearic acid mixture impregnated with gypsum wallboard for low-temperature latent heat thermal energy storage. Int J Energy Res. 2008;32(2):154–60.
Zhang D, Zhou J, Wu K, Li Z. Granular phase changing composites for thermal energy storage. Sol Energy. 2005;78(3):471–80.
Sharifi NP, Sakulich A. Application of phase change materials to improve the thermal performance of cementitious material. Energy Build. 2015;103:83–95.
Lu Z, Zhang J, Sun G, Xu B, Li Z, Gong C. Effects of the form-stable expanded perlite/paraffin composite on cement manufactured by extrusion technique. Energy. 2015;82:43–53.
Ramakrishnan S, Sanjayan J, Wang X, Alam M, Wilson J. A novel paraffin/expanded perlite composite phase change material for prevention of PCM leakage in cementitious composites. Appl Energy. 2015;157:85–94.
Li X, Sanjayan JG, Wilson JL. Fabrication and stability of form-stable diatomite/paraffin phase change material composites. Energy Build. 2014;76:284–94.
Zhang J, Guan X, Song X, Hou H, Yang Z, Zhu J. Preparation and properties of gypsum based energy storage materials with capric acid–palmitic acid/expanded perlite composite PCM. Energy Build. 2015;92:155–60.
Zhang N, Yuan Y, Yuan Y, Li T, Cao X. Lauric–palmitic–stearic acid/expanded perlite composite as form-stable phase change material: preparation and thermal properties. Energy Build. 2014;82:505–11.
Liu P, Gu X, Bian L, Peng L, He H. Capric acid/intercalated diatomite as form-stable composite phase change material for thermal energy storage. J Therm Anal Calorim. 2019;138(1):359–68.
Sarı A, Biçer A. Preparation and thermal energy storage properties of building material-based composites as novel form-stable PCMs. Energy Build. 2012;51:73–83.
Biçer A, Sarı A. New kinds of energy-storing building composite PCMs for thermal energy storage. Energy Convers Manag. 2013;69:148–56.
Kenisarin MM, Kenisarina KM. Form-stable phase change materials for thermal energy storage. Renew Sustain Energy Rev. 2012;16(4):1999–2040.
Ramakrishnan S, Wang X, Sanjayan J, Wilson J. Assessing the feasibility of integrating form-stable phase change material composites with cementitious composites and prevention of PCM leakage. Mater Lett. 2017;192:88–91.
Cheng F, Wen R, Zhang X, Huang Z, Huang Y, Fang M, et al. Synthesis and characterization of beeswax-tetradecanol-carbon fiber/expanded perlite form-stable composite phase change material for solar energy storage. Compos Part A. 2018;107:180–8.
Kong X, Zhong Y, Rong X, Min C, Qi C. Building energy storage panel based on paraffin/expanded perlite: preparation and thermal performance study. Materials. 2016;9(2):70.
Li X, Chen H, Liu L, Lu Z, Sanjayan JG, Duan WH. Development of granular expanded perlite/paraffin phase change material composites and prevention of leakage. Sol Energy. 2016;137:179–88.
Kheradmand M, Castro-Gomes J, Azenha M, Silva PD, de Aguiar JLB, Zoorob SE. Assessing the feasibility of impregnating phase change materials in lightweight aggregate for development of thermal energy storage systems. Constr Build Mater. 2015;89:48–59.
Kolthoff IM, O’connor PR, Hansen JL. Mechanism of emulsion polymerization of styrene with persulfate as activator in the absence and presence of mercaptan and a retarder. J Polym Sci. 1955;15(80):459–73.
Ma B, Adhikari S, Chang Y, Ren J, Liu J, You Z. Preparation of composite shape-stabilized phase change materials for highway pavements. Constr Build Mater. 2013;42:114–21.
Kong X, Yao C, Jie P, Liu Y, Qi C, Rong X. Development and thermal performance of an expanded perlite-based phase change material wallboard for passive cooling in building. Energy Build. 2017;152:547–57.
Mehta S, Biederman S, Shivkumar S. Thermal degradation of foamed polystyrene. J Mater Sci. 1995;30(11):2944–9.
Lorwanishpaisarn N, Kasemsiri P, Posi P, Chindaprasirt P. Characterization of paraffin/ultrasonic-treated diatomite for use as phase change material in thermal energy storage of buildings. J Therm Anal Calorim. 2016;128(3):1293–303.
Hasanabadi S, Sadrameli SM, Soheili H, Moharrami H, Heyhat MM. A cost-effective form-stable PCM composite with modified paraffin and expanded perlite for thermal energy storage in concrete. J Therm Anal Calorim. 2018;136:1201–16.
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Financial support from the Research Department of Tarbiat Modares University and Iranian Science Foundation (INSF) is gratefully acknowledged by the first and second authors.
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Hasanabadi, S., Sadrameli, S.M. & Sami, S. Preparation, characterization and thermal properties of surface-modified expanded perlite/paraffin as a form-stable phase change composite in concrete. J Therm Anal Calorim 144, 61–69 (2021). https://doi.org/10.1007/s10973-020-09440-1
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DOI: https://doi.org/10.1007/s10973-020-09440-1