Abstract
Ceramic wall tiles, which are the most popular wall coverings, are especially used for internal applications due to their high porosity and high water absorption. When the tile body absorbs water after laying, water mark problem, which is a common phenomenon in ceramic tiles, occurs. The aim of this study was to increase the current understanding about how the engobe characteristics (opacity, fusibility, permeability) and the type of frit used in engobe compositions influence the water mark formation of a wall tile body. For this purpose, mainly three different types of engobe compositions were developed by using diopside-based, zircon-based, and titanium-based frits. The sintering behaviors of frits and engobes were characterized by using a heating microscope. Water permeability features were measured by water drop test and ink test. The structural and morphological characteristics of the engobes were investigated. This study revealed that increasing engobe fusibility prevents the water mark formation. However, reducing the engobe porosity alone is not enough to solve the problem; the engobe composition should have sufficient opacity. Type and amount of the frit in engobe formulations determine the melting behavior, opacity, and permeability feature of the engobe layer. According to the results, the engobe composition with desired opacity and permeability could not be achieved by using diopside frit due to its melting behavior and dissolution of diopside crystals. On the other hand, engobe compositions using zircon-based and titanium-based frits contributed to minimizing the water mark problem with the formation of zircon and titanite crystals and their impermeable structures.
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References
Gambuli P. World production and consumption of ceramic tile 6th edition. Acimac. 2018. http://www.mec-studies.com/filealbum/740_0.pdf. Accessed 18 Oct 2019.
Boschi A, Melchiades FG, Silva VA, Romachelli JC, Vargas DDT. Avoiding water marks by adjusting engobe layer characteristics Part I. Tile Brick Int. 2002;18:224–7.
Melchiades FG, Silva LL, Silva VA, Romachelli JC, Vargas DDT, Boschi AO. Avoiding water mark formation by adjusting engobe layer characteristics. Qualicer. 2002;18:435–50.
Yıldız B, Kucuk A, Kara A. Effect of pore characteristics on engobe permeability for the water mark problem. Qualicer. 2014;Pos:1–4.
Yıldız B, Development of diopside based wall tile glazes and engobes, Ph.D. thesis. Anadolu University, Eskisehir, Turkey; 2010.
Eppler RA, Eppler DR. Glazes and glass coatings. Ohio: The American Ceramic Society; 2000.
Vari A. Raw material preparation and forming of ceramic tiles. Modena: S.A.L.A; 2000.
Taylor JR, Bull AC. Ceramics glaze technology. London: Pergamon Press; 1980.
Aksan S, Ediz N, Compositions of impervious engobe for floor tiles. In: 6th International advanced technologies symposium (IATS’11) proceeding book. 2011; 256–261.
Moreno A, Bou E, Cabrera MJ, Quereda P. Zirconium silicate opacification mechanism in ceramic engobes. Qualicer. 1998;Pos:29–31.
Parmelee CW. Ceramic glazes. Boston: Cahners Books; 1973.
Castilone RJ, Sriram D, Carty WM, Snyder RL. Crystallization of zircon in stoneware glazes. J Am Ceram Soc. 1999;82:2819–24.
Romero M, Rincon JM, Acosta A. Crystallization of a zirconium-based glaze for ceramic tile coatingsç. J Eur Ceram Soc. 2003;23:1629–35.
Taylor JR, Bull AC. Ceramics glaze technology. London: Pergamon Press; 1980. p. 111.
Santos CR, Fontana TLB, Uggioni E, Riella HG, Bernardin AM. Achieving opacity in ceramic tiles: micro structural and spectrophotometric analysis. Qualicer. 2004;Pos:189–194.
Tarhan M. Whiteness improvement of porcelain tiles incorporated with anorthite and diopside phases. J Therm Anal Calorim. 2019. https://doi.org/10.1007/s10973-019-08268-8.
Perks C, Mudd G. Titanium, zirconium resources and production: a state of the art literature review. Ore Geol Rev. 2019. https://doi.org/10.1016/j.oregeorev.2019.02.025.
Topates G, Tarhan B, Tarhan M. Chemical durability of zircon containing glass-ceramic glazes. Ceram Int. 2017;43:12333–7.
Gajek M, Rapacz-Kmita A, Leśniak M, Stodolak-Zych E, Dudek M, Sitarz M. Influence of SrO content on microstructure and crystallization of glazes in the SiO2–Al2O3–CaO–MgO–K2O system. J Therm Anal Calorim. 2019. https://doi.org/10.1007/s10973-019-08188-7.
Hocaoğlu E. Developing of the engobe glazes with diopside based crystallization. Master of science thesis, Anadolu University, Eskisehir, Turkey; 2004.
Aparisi J, Sanchez LF, Amoros JL, Escardino A, Orts MJ, Mestre S. Obtaining smooth, white floor tile glazes from zirconium-free frits. Qualicer. 1998;Pos:66–68.
Senanon W, Yongsiri P, Eitsayyeam S, Tunkasiri T, Pengpat K. Comparison between incorporation and conventional fabrication techniques of diopside-based glass-ceramics. Mater Lett. 2019. https://doi.org/10.1016/j.matlet.2019.04.077.
Bou E, Moreno A, Escardino A, Gozalbo A. Micro structural study of opaque glazes obtained from frits of the system: SiO2–Al2O3–B2O3–(P2O5)–CaO–K2O–TiO2. J Eur Ceram Soc. 2007;27:1791–6.
Teixeira S, Bernardin AM. Development of TiO2 white glazes for ceramic tiles. Dyes Pigm. 2009;80:292–6.
Biffi G, Ortelli G, Vincenzini P. Ceramic glazes opacified with CaTiSiO5. Ceramurgia Int. 1975;1:34–5.
Amorós JL, Orts MJ, Mestre S, Garcia-Ten J, Feliu C. Porous single-fired wall tile bodies: influence of quartz particle size on tile properties. J Eur Ceram Soc. 2010;30:17–28.
Tarhan B. Usage of fired wall tile wastes into fireclay sanitaryware products. J Aust Ceram Soc. 2019. https://doi.org/10.1007/s41779-018-0285-1.
Salman SM, Salama SN. Crystallization and thermal expansion characteristics of In2O3-containing lithium iron silicate-diopside glasses. Ceram Silik. 2011;55:114–22.
Finger LW, Qhashi Y. The thermal expansion of diopside to 800°C and a refinement of the crystal structure at 700°C. Am Miner. 1976;61:303–10.
Alptekin K. Development of glass-ceramic glazes. Master of science thesis, Anadolu University, Eskisehir, Turkey; 2003.
Ilic BR, Mitrovic AA, Milicic LR. Thermal treatment of kaolin clay to obtain metakaolin. Institute for Testing of Materials. 2010. https://doi.org/10.2298/hemind100322014i.
Traore K, Kabré TS, Blanchart P. Gehlenite and anorthite crystallisation from kaolinite andcalcite mix. Ceram Int. 2003;29:377–83.
Pekkan K, Karasu B. Zircon-free frits suitable for single fast-firing opaque wall tile glazes and their industrial productions. J Eur Ceram Soc. 2009;29:1571–8.
Quinteiro E, Boschi AO, Lconcllt C, Manfredini T, Siligardi C. Glass-ceramic systems compatible with the firing conditions used in the ceramic tile industry. Qualicer. 2002;2002:301–11.
Aydin T, Tarhan M, Tarhan B. Addition of cement kiln dust in ceramic wall tile bodies. J Therm Anal Calorim. 2018. https://doi.org/10.1007/s10973-018-7615-y.
Hu AM, Li M, Mao DL. Crystallization of spodumene-diopside in the las glass ceramics with CaO and MgO addition. J Therm Anal Calorim. 2007;90:185–9.
Kuchinski FA. Materials and corrosion. In: Wachtman JB, Haber RK, editors. Ceramic films and coatings. New York: Noyes Publications; 1993. p. 97–100.
Acknowledgements
The authors would like to thank Research Fund of Uşak University for the support to the project numbered 2018/GS002. Special thanks also go to the people of Usak Seramik A. S. and Usak Seramik A. S. of Turkiye, facilitating the study to be conducted satisfactorily.
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Tarhan, M., Tarhan, B. Development of waterproof engobe layer for ceramic wall tiles. J Therm Anal Calorim 140, 555–565 (2020). https://doi.org/10.1007/s10973-019-08893-3
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DOI: https://doi.org/10.1007/s10973-019-08893-3