Abstract
In this work, the adsorption capacity of Cu2+, Co2+ and Cr3+ by synthetic dibasic calcium silicate hydrate sample as well as its thermal stability was examined. The synthesis of dibasic calcium silicate hydrate was carried out in unstirred suspensions, when CaO/SiO2 molar ratio of primary mixture was equal to 1.5 and the duration of isothermal curing at 175 °C temperature was 16 h. Afterwards, metal ions were incorporated into the synthesis products; the experiments were carried out at 25 °C temperature by stirring 5 g of synthetic dibasic calcium silicate hydrate in 500 mL of Co(NO3)2·6H2O, Cr(NO3)2·9H2O or Cu(NO3)2·3H2O solutions containing 1 g of Co2+, Cr2+ or Cu2+ dm−3 for 30 min. It was obtained that after adsorption all metal ions (100 mg Me2+ g−1) were intercalated into the structure of synthesis products. In situ X-ray diffraction study on the thermal stability of synthesized compounds was performed in a modular temperature chamber from RT to 1000 °C temperature. The obtained results were confirmed by XRD, STA, FT-IR, AAS and SEM methods.
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Yuan H, Chini AR, Lu Y, Shen L. A dynamic model for assessing the effects of management strategies on the reduction of construction and demolition waste. Waste Manag (Oxford). 2012;32:521–31.
Bhatnagar A, Sillanpää M. Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment—a review. Chem Eng J. 2010;157:277–96.
Generation and discharge of wastewater in volume. http://appsso.eurostat.ec.europa.eu/nui/show.do?dataset=env_ww_genv&lang=en. Accessed 30 Oct 2018
The United Nations world water development report. http://www.unwater.org/publications/world-water-development-report-2017/. Accessed 29 Oct 2018
Bhatnagar A, Sillanpää M. A review of emerging adsorbents for nitrate removal from water. Chem Eng J. 2011;168:493–504.
Soon AN, Hameed BH. Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process. Desalination. 2011;269:1–16.
Alver E, Metin AÜ. Anionic dye removal from aqueous solutions using modified zeolite: adsorption kinetics and isotherm studies. Chem Eng J. 2012;200–202:59–67.
Yuan H, Shen L. Trend of the research on construction and demolition waste management. Waste Manag. 2011;31:670–9.
Wang S, Sun H, Ang HM, Tadé MO. Adsorptive remediation of environmental pollutants using novel graphene-based nanomaterials. Chem Eng J. 2013;226:336–47.
Sato T, Qadir M, Yamamoto S, Endo T, Zahoor A. Global, regional, and country level need for data on wastewater generation, treatment, and use. Agric Water Manag. 2013;130:1–13.
Chiang YW, Ghyselbrecht K, Santos RM, Meesschaert B, Martens JA. Synthesis of zeolitic-type adsorbent material from municipal solid waste incinerator bottom ash and its application in heavy metal adsorption. Catal Today. 2012;190:23–30.
Soto ML, Moure A, Domínguez H, Parajó JC. Recovery, concentration and purification of phenolic compounds by adsorption: a review. J Food Eng. 2011;105:1–27.
Caliskan N, Kul AR, Alkan S, Sogut EG, Alacabey İ. Adsorption of Zinc(II) on diatomite and manganese-oxide-modified diatomite: a kinetic and equilibrium study. J Hazard Mater. 2011;193:27–36.
Şahan T, Öztürk D. Investigation of Pb(II) adsorption onto pumice samples: application of optimization method based on fractional factorial design and response surface methodology. Clean Technol Environ Policy. 2014;16:819–31.
Rostamian R, Najafi M, Rafati AA. Synthesis and characterization of thiol-functionalized silica nano hollow sphere as a novel adsorbent for removal of poisonous heavy metal ions from water: kinetics, isotherms and error analysis. Chem Eng J. 2011;171:1004–11.
Rafatullah M, Sulaiman O, Hashim R, Ahmad A. Adsorption of methylene blue on low-cost adsorbents: a review. J Hazard Mater. 2010;177:70–80.
Hua M, Zhang S, Pan B, Zhang W, Lv L, Zhang Q. Heavy metal removal from water/wastewater by nanosized metal oxides: a review. J Hazard Mater. 2012;211–212:317–31.
Bhatnagar A, Jain AK. A comparative adsorption study with different industrial wastes as adsorbents for the removal of cationic dyes from water. J Colloid Interface Sci. 2005;281:49–55.
Bhattacharya AK, Naiya TK, Mandal SN, Das SK. Adsorption, kinetics and equilibrium studies on removal of Cr(VI) from aqueous solutions using different low-cost adsorbents. Chem Eng J. 2008;137:529–41.
Repo E, Warchoł JK, Bhatnagar A, Sillanpää M. Heavy metals adsorption by novel EDTA-modified chitosan–silica hybrid materials. Colloid Interface Sci. 2011;358:261–7.
Samiey B, Cheng C, Wu J. Organic–inorganic hybrid polymers as adsorbents for removal of heavy metal ions from solutions: a review. Materials. 2014;7:673–726.
Ok YS, Yang JE, Zhang Y, Kim S, Chung D. Heavy metal adsorption by a formulated zeolite-Portland cement mixture. J Hazard Mater. 2007;147:91–6.
Eisinas A, Baltakys K, Siauciunas R. Utilisation of gyrolite with impure Cd2 ions in cement stone. Adv Cem Res. 2013;25:69–79.
Mehrali M, Seyed Shirazi SF, Baradaran S, Mehrali M, Metselaar HSC, Kadri NAB, Osman NAA. Facile synthesis of calcium silicate hydrate using sodium dodecyl sulfate as a surfactant assisted by ultrasonic irradiation. Ultrason Sonochem. 2014;21:735–42.
Zhao J, Zhu Y, Wu J, Zheng J, Zhao X, Lu B, Chen F. Chitosan-coated mesoporous microspheres of calcium silicate hydrate: environmentally friendly synthesis and application as a highly efficient adsorbent for heavy metal ions. J Colloid Interface Sci. 2014;418:208–15.
Ahmaruzzaman M. Industrial wastes as low-cost potential adsorbents for the treatment of wastewater laden with heavy metals. Adv Colloid Interface Sci. 2011;166:36–59.
Bankauskaite A, Baltakys K, Eisinas A, Zadaviciute S. Study on adsorption of heavy metal ions in wastewater by synthetic layered inorganic adsorbents. Desalin Water Treat. 2014;26:9144.
Zhao Z, Wei J, Li F, Qu X, Shi L, Zhang H, Yu Q. Synthesis, characterization and hexavalent chromium adsorption characteristics of aluminum-and sucrose-incorporated tobermorite. Materials. 2017;10:597.
Okano K, Uemoto M, Kagami J, Miura K, Aketo T, Toda M, Honda K, Ohtake H. Novel technique for phosphorus recovery from aqueous solutions using amorphous calcium silicate hydrates (A-CSHs). Water Res. 2013;47:2251–9.
Plusquellec G, Nonat A. Interactions between calcium silicate hydrate (C–S–H) and calcium chloride, bromide and nitrate. Cem Concr Res. 2016;90:89–96.
Rajasekaran G. Sulphate attack and ettringite formation in the lime and cement stabilized marine clays. Ocean Eng. 2005;32:1133–59.
Cvetković VS, Purenović JM, Purenović MM, Jovićević JN. Interaction of Mg-enriched kaolinite–bentonite ceramics with arsenic aqueous solutions. Desalination. 2009;249:582–90.
Lu L, Xiang C, He Y, Wang F, Hu S. Early hydration of C3S in the presence of Cd2+, Pb2+ and Cr3+ and the immobilization of heavy metals in pastes. Constr Build Mater. 2017;152:923–32.
Niuniavaite D, Baltakys K, Dambrauskas T. The adsorption kinetic parameters of Co2 ions by α-C2SH. Buildings. 2018;8:10.
Dambrauskas T, Baltakys K, Eisinas A. Formation and thermal stability of calcium silicate hydrate substituted with Al3 ions in the mixtures with CaO/SiO2 = 15. J Therm Anal Calorim. 2018;131:501–12.
Baltakys K, Siauciunas R, Gendvilas R, Eisinas A, Dambrauskas T, Kitrys S. Physically and chemically bound H2O in the α-C2S hydrate structure. J Therm Anal Calorim. 2014;118:807–16.
Vargas AMM, Cazetta AL, Kunita MH, Silva TL, Almeida VC. Adsorption of methylene blue on activated carbon produced from flamboyant pods (Delonix regia): study of adsorption isotherms and kinetic models. Chem Eng J. 2011;168:722–30.
Wu B, Ye G. Carbonation mechanism of different kind of CSH: rate and products. Concr Suppl Cement Mater. 2016;113:163–272.
He Y, Zhao X, Lu L, Struble LJ, Hu S. Effect of C/S ratio on morphology and structure of hydrothermally synthesized calcium silicate hydrate. J Wuhan Univ Technol. 2011;26:770–3.
Yu P, Kirkpatrick RJ, Poe B, McMillan PF, Cong X. Structure of calcium silicate hydrate (C–S–H): near-, mid-, and far-infrared spectroscopy. J Am Ceram Soc. 1999;82:742–8.
Garbev K, Gasharova B, Beuchle G, Kreisz S, Stemmermann P. First observation of α-Ca2[SiO3(OH)](OH)–Ca6[Si2O7][SiO4](OH)2 phase transformation upon Thermal Treatment in Air. J Am Ceram Soc. 2008;91:263–71.
Crini G, Peindy HN, Gimbert F, Robert C. Removal of CI Basic Green 4 (Malachite Green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: kinetic and equilibrium studies. Sep Purif Technol. 2007;53:97–110.
Zhuang X, Wan Y, Feng C, Shen Y, Zhao D. Highly efficient adsorption of bulky dye molecules in wastewater on ordered mesoporous carbons. Chem Mater. 2009;21:706–16.
Southam DC, Lewis TW, McFarlane AJ, Johnston JH. Amorphous calcium silicate as a chemisorbent for phosphate. Curr Appl Phys. 2004;4:355–8.
Southam DC, Lewis TW, McFarlane AJ, Borrmann T, Johnston JH. Calcium–phosphorus interactions at a nano-structured silicate surface. J Colloid Interface Sci. 2008;319:489–97.
Diamond S. The microstructure of cement paste in concrete. Cem Concr Res. 1986;1:122–47.
Franus W, Panek R, Wdowin M. SEM investigation of microstructures in hydration products of Portland cement. In: 2nd international multidisciplinary microscopy and microanalysis congress; 2015, p. 105–12.
Becker O, Varley RJ, Simon GP. Thermal stability and water uptake of high performance epoxy layered silicate nanocomposites. Eur Polym J. 2004;40:187–95.
Gallucci E, Zhang X, Scrivener KL. Effect of temperature on the microstructure of calcium silicate hydrate (C–S–H). Cem Concr Res. 2013;53:185–95.
Liu X, Ding C. Plasma-sprayed wollastonite 2 M/ZrO2 composite coating. Surf Coat Technol. 2003;172:270–8.
Xue H, Wang G, Hu M, Chen B. Modification of wollastonite by acid treatment and alkali-induced redeposition for use as papermaking filler. Powder Technol. 2015;276:193–9.
Nour WMN, Mostafa AA, Ibrahim DM. Recycled wastes as precursor for synthesizing wollastonite. Ceram Int. 2008;34:101–5.
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This work was funded by a Grant (No. S-MIP–17-92) from the Research Council of Lithuania.
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Niuniavaite, D., Baltakys, K., Dambrauskas, T. et al. Cu2+, Co2+ and Cr3+ adsorption by synthetic dibasic calcium silicate hydrates and their thermal stability in a 25–1000 °C temperature range. J Therm Anal Calorim 138, 2241–2249 (2019). https://doi.org/10.1007/s10973-019-08795-4
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DOI: https://doi.org/10.1007/s10973-019-08795-4