The application of DSC to oil field includes characterization and phase behavior study of crude oils and their fractions, developing structural and morphological fingerprint of petroleum fluids and wax crystallization study of crudes. Also DSC can be used to study kinetics of pyrolysis, combustion and oxidation of crudes. In this study, microstructural analysis and wax crystallization of crudes are critically reviewed and the leading research works in each field are comprehensively integrated to provide an instructive encyclopedia for future studies. The challenges and opportunities to improve in every section are discussed in detail to address the potential hindrances of using DSC and tackle hesitance for future use of the technique. The integrative approach not only covers the key outcomes of different studies, but also allows one to construct novel experiments with implementing connected researches in the past. In addition, possibility of linking DSC with other methods in order to either improve or broaden the applicability of the technique is overviewed and elaborated. Different operating parameters in using DSC including thermal scanning program, pressure, initial conditions, constant heating/cooling rate, type of thermal program effect and raw data analysis are carefully discussed and the effect of each parameter on the outcome of the studies is systematically expounded. This comprehensive and integrative study shows that although the application of DSC is mature in some fields, its precision is at infancy and developments such as modulated thermal programs can vastly enhance its applicability and accuracy at the same time.
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Létoffé JM, Claudy P, Kok MV, Garcin M, Volle JL. Crude oils: characterization of waxes precipitated on cooling by d.s.c. and thermomicroscopy. Fuel. 1995;74:810–7.
Kok MV. Use of thermal equipment to evaluate crude oils. Thermochim Acta. 1993;214:315–24.
Giavarini C, Pochetti F. Characterization of petroleum products by DSC analysis. J Therm Anal. 1973;5:83–94.
Castro LV, Vazquez F. Fractionation and characterization of mexican crude oils. Energy Fuels. 2009;23:1603–9.
Mothé MG, Perin M, Mothé CG. Comparative thermal study of heavy crude oils by DSC. Pet Sci Technol. 2016;34:314–20.
Masson J-F, Bundalo-Perc S. Calculation of smoothing factors for the comparison of DSC results. J Therm Anal Calorim. 2007;90:639–43.
Thermal Kök M. Analysis applications in fossil fuel science. Literature survey. J Therm Anal Calorim. 2002;68:1061–77.
Kök M. Recent developments in the application of thermal analysis techniques in fossil fuels. J Therm Anal Calorim. 2008;91:763–73.
Wesołowski M. Thermal analysis of petroleum products. Thermochim Acta. 1981;46:21–45.
Rustschev DD. Application of thermal analysis for investigating liquid fuels, petroleum- and coke-chemical products. Thermochim Acta. 1990;168:261–71.
Reading M, Luget A, Wilson R. Modulated differential scanning calorimetry. Thermochim Acta. 1994;238:295–307.
Gill PS, Sauerbrunn SR, Reading M. Modulated differential scanning calorimetry. J Therm Anal. 1993;40:931–9.
Simon SL. Temperature-modulated differential scanning calorimetry: theory and application. Thermochim Acta. 2001;374:55–71.
Masson J-F, Polomark GM. Bitumen microstructure by modulated differential scanning calorimetry. Thermochim Acta. 2001;374:105–14.
Frolov IN, Yusupova TN, Ziganshin MA, Okhotnikova ES, Firsin AA. Features of colloidal disperse structure formation in petroleum bitumen. Colloid J. 2016;78:712–6.
Frolov IN, Yusupova TN, Ziganshin MA, Okhotnikova ES, Firsin AA. Dynamics of formation of asphalt microstructure according to modulated differential scanning calorimetry data. Pet Chem. 2017;57:1002–6.
Masson J-F, Polomark GM, Collins P. Time-dependent microstructure of bitumen and its fractions by modulated differential scanning calorimetry. Energy Fuels. 2002;16:470–6.
Masson J-F, Collins P, Polomark G. Steric hardening and the ordering of asphaltenes in bitumen. Energy Fuels. 2005;19:120–2.
Masson J-F, Polomark GM, Bundalo-Perc S, Collins P. Melting and glass transitions in paraffinic and naphthenic oils. Thermochim Acta. 2006;440:132–40.
Dreezen G, Groeninckx G, Swier S, Van Mele B. Phase separation in miscible polymer blends as detected by modulated temperature differential scanning calorimetry. Polymer. 2001;42:1449–59.
Frolov IN, Bashkirceva NY, Ziganshin MA, Okhotnikova ES, Firsin AA. The steric hardening and structuring of paraffinic hydrocarbons in bitumen. Pet Sci Technol. 2016;34:1675–80.
Yu X, Granados-Focil S, Tao M, Burnham NA. Time- and composition-dependent evolution of distinctive microstructures in bitumen. Energy Fuels. 2018;32:67–80.
Redelius P, Soenen H. Relation between bitumen chemistry and performance. Fuel. 2015;140:34–43.
Raki L, Masson J-F, Collins P. Rapid bulk fractionation of maltenes into saturates, aromatics, and resins by flash chromatography. Energy Fuels. 2000;14:160–3.
Speight JG. The chemistry and technology of petroleum. 5th ed. Boca Raton: CRC Press; 2014.
Frolov IN, Yusupova TN, Ziganshin MA, Okhotnikova ES, Firsin AA. Formation of phase composition of petroleum bitumen according to data of temperature modulated differential scanning calorimetry. J Therm Anal Calorim. 2018;131:555–60.
ASTM D2007-11. Standard test method for characteristic groups in rubber extender and processing oils and other petroleum-derived oils by the clay-gel absorption chromatographic method. ASTM International, West Conshohocken, 2016.
Lesueur D. The colloidal structure of bitumen: consequences on the rheology and on the mechanisms of bitumen modification. Adv Colloid Interface Sci. 2009;145:42–82.
Frolov IN, Firsin AA. Role of paraffinic hydrocarbons in the formation of the dispersed structure of petroleum asphalt. Chem Technol Fuels Oils. 2016;52:600–5.
Robustillo MD, Coto B, Martos C, Espada JJ. Assessment of different methods to determine the total wax content of crude oils. Energy Fuels. 2012;26:6352–7.
Cheung CY, Cebon D. Deformation mechanisms of pure bitumen. J Mater Civ Eng Am Soc Civil Eng. 1997;9:117–29.
Claudy PM, Létoffé JM, Martin D, Planche JP. Thermal behavior of asphalt cements. Thermochim Acta. 1998;324:203–13.
Chambrion P, Bertau R, Ehrburger P. Characterization of bitumen by differential scanning calorimetry. Fuel. Elsevier. 1996;75:144–8.
Hourston DJ, Schäfer F-U, Gradwell MHS, Song M. TMXDI-based poly(ether urethane)/polystyrene interpenetrating polymer networks: 2. Tg behaviour, mechanical properties and modulus-composition studies. Polymer. 1998;39:5609–17.
Hourston DJ, Schäfer F-U, Bates JS, Gradwell MHS. TMXDI-based poly(ether urethane)/polystyrene interpenetrating polymer networks: 1. Morphology and thermal properties. Polymer. 1998;39:3311–20.
Hourston DJ, Song M, Schafer F-U, Pollock HM, Hammiche A. Modulated differential scanning calorimetry: 13. Analysis of morphology of poly(ethyl methacrylate)/polyurethane interpenetrating polymer networks. Thermochim Acta. 1998;324:109–21.
Cantor AS. Glass transition temperatures of hydrocarbon blends: adhesives measured by differential scanning calorimetry and dynamic mechanical analysis. J Appl Polym Sci. 2000;77:826–32.
Fulem M, Becerra M, Hasan MDA, Zhao B, Shaw JM. Phase behaviour of Maya crude oil based on calorimetry and rheometry. Fluid Phase Equilib. Elsevier. 2008;272:32–41.
Frolov IN, Okhotnikova ES, Ziganshin MA, Firsin AA. Thermodynamic and thermokinetic processes of formation disperse structures of bitumen. Pet Sci Technol. 2017;35:2277–82.
Peramanu S, Pruden BB, Rahimi P. Molecular weight and specific gravity distributions for athabasca and cold lake bitumens and their saturate, aromatic, resin, and asphaltene fractions. Ind Eng Chem Res. 1999;38:3121–30.
Wunderlich B, Okazaki I, Ishikiriyama K, Boller A. Melting by temperature-modulated calorimetry. Thermochim Acta. 1998;324:77–85.
Wunderlich B. A classification of molecules, phases, and transitions as recognized by thermal analysis. Thermochim Acta. 1999;340–341:37–52.
Claudy P, Letoffe JM, King GN, Planche JP, Brule B. Characterization of paving asphalts by differential scanning calorimetry. Fuel Sci Technol Int. 1991;9:71–92.
Coto B, Martos C, Espada JJ, Robustillo MD, Peña JL. Analysis of paraffin precipitation from petroleum mixtures by means of DSC: iterative procedure considering solid–liquid equilibrium equations. Fuel. 2010;89:1087–94.
Singh P, Venkatesan R, Fogler HS, Nagarajan N. Formation and aging of incipient thin film wax-oil gels. AIChE J. 2000;46:1059–74.
Coutinho JAP, Daridon J-L. Low-pressure modeling of wax formation in crude oils. Energy Fuels. 2001;15:1454–60.
Coutinho JAP, Daridon J-L. The limitations of the cloud point measurement techniques and the influence of the oil composition on its detection. Pet Sci Technol. 2005;23:1113–28.
Duan J, Deng S, Xu S, Liu H, Chen M, Gong J. The effect of gas flow rate on the wax deposition in oil-gas stratified pipe flow. J Pet Sci Eng. 2018;162:539–47.
Currell BR, Robinson B. Characterization and analysis of waxes by differential thermal analysis. Talanta. 1967;14:421–4.
Lange J, Jochinke H. Kennzeichnung von Wachsen durch differential-thermo-analyse. Fette, Seifen, Anstrichm. 1965;67:89–94.
Kok MV, Létoffé J-M, Claudy P, Martin D, Garcin M, Volle J-L. Comparison of wax appearance temperatures of crude oils by differential scanning calorimetry, thermomicroscopy and viscometry. Fuel. 1996;75:787–90.
Vieira LC, Buchuid MB, Lucas EF. Effect of pressure on the crystallization of crude oil waxes. I. Selection of test conditions by microcalorimetry. Energy Fuels. 2010;24:2208–12.
Paiva FL, Calado VMA, Marchesini FH. On the use of modulated temperature differential scanning calorimetry to assess wax crystallization in crude oils. Fuel. 2017;202:216–26.
Matricarde Falleiro RM, Akisawa Silva LY, Meirelles AJA, Krähenbühl MA. Vapor pressure data for fatty acids obtained using an adaptation of the DSC technique. Thermochim Acta. 2012;547:6–12.
Khoshooei MA, Sharp D, Maham Y, Afacan A, Dechaine GP. A new analysis method for improving collection of vapor-liquid equilibrium (VLE) data of binary mixtures using differential scanning calorimetry (DSC). Thermochim Acta. 2018;659:232–41.
Gimzewski E, Audley G. Monitoring wax crystallisation in diesel using differential scanning calorimetry (DSC) and microcalorimetry. Thermochim Acta. 1993;214:149–55.
Inaba H. Nano-watt stabilized DSC and its applications. J Therm Anal Calorim. 2005;79:605–13.
Wang S, Tozaki K-I, Hayashi H, Inaba H, Yamamoto H. Observation of multiple phase transitions in some even n-alkanes using a high resolution and super-sensitive DSC. Thermochim Acta. 2006;448:73–81.
Wang S, Tozaki K, Hayashi H, Hosaka S, Inaba H. Observation of multiple phase transitions in n-C22H46 using a high resolution and super-sensitive DSC. Thermochim Acta. 2003;408:31–8.
Tozaki K, Inaba H, Hayashi H, Quan C, Nemoto N, Kimura T. Phase transitions of n-C32H66 measured by means of high resolution and super-sensitive DSC. Thermochim Acta. 2003;397:155–61.
Ludwig FJ. Analysis of microcrystalline and paraffin waxes by means of infrared spectra in the molten state. Anal Chem. 1965;37:1737–41.
Hennessy AJ, Neville A, Roberts KJ. An examination of additive-mediated wax nucleation in oil pipeline environments. J Cryst Growth. 1999;198–199:830–7.
Hammami A, Mehrotra AK. Thermal behaviour of polymorphic n-alkanes: effect of cooling rate on the major transition temperatures. Fuel. 1995;74:96–101.
Mazee WM. On the properties of paraffin wax in the solid state. J Inst Pet. 1949;35:97–102.
Craig RG, Powers JM, Peyton FA. Analytical calorimetry: differential thermal analysis and calorimetry of waxes. In: Johnson JF, editor. Porter RS. Boston: Springer, US; 1968. p. 157–66.
Bucaram SM. An improved paraffin inhibitor. J Pet Technol. 1967;19:150–6.
Zaky MT, Mohamed NH. Influence of low-density polyethylene on the thermal characteristics and crystallinity of high melting point macro- and micro-crystalline waxes. Thermochim Acta. 2010;499:79–84.
Stank J, Mullay J. Analysis of wax/oil mixtures using DSC. Thermochim Acta. 1986;105:9–17.
Flaherty B. Characterisation of waxes by differential scanning calorimetry. J Chem Technol Biotechnol. 1971;21:144–8.
ASTM D4419-90. Standard test method for measurement of transition temperatures of petroleum waxes by differential scanning calorimetry (DSC). ASTM International, 2015.
Srivastava SP, Handoo J, Agrawal KM, Joshi GC. Phase-transition studies in n-alkanes and petroleum-related waxes-A review. J Phys Chem Solids. 1993;54:639–70.
Handoo J, Srivastava SP, Agrawal KM, Joshi GC. Thermal properties of some petroleum waxes in relation to their composition. Fuel. 1989;68:1346–8.
ASTM D721-17. Standard test method for oil content of petroleum waxes. ASTM International. 2017.
Chen J, Zhang J, Li H. Determining the wax content of crude oils by using differential scanning calorimetry. Thermochim Acta. 2004;410:23–6.
Kumar S, Agrawal KM, Khan HU, Sikora A. Study of phase transition in hard microcrystalline waxes and wax blends by differential scanning calorimetry. Pet Sci Technol. 2004;22:337–45.
Drotloff H, Möller M. On the phase transitions of cycloalkanes. Thermochim Acta. 1987;112:57–62.
Drotloff H, Emeis D, Waldron RF, Möller M. Chain folding and mesomorphic states of cycloalkanes. Polymer. 1987;28:1200–6.
Srivastava SP, Tandon RS, Pandey DC, Madhwal DC, Goyal SK. Phase transitions in petroleum waxes: correlation with properties. Fuel. 1993;72:1345–9.
Létoffé JM, Claudy P, Garcin M, Volle JL. Evaluation of crystallized fractions of crude oils by differential scanning calorimetry: correlation with gas chromatography. Fuel. 1995;74:92–5.
Kök MV, Letoffe JM, Claudy P. Comparative methods in the determination of wax content and pour points of crude oils. J Therm Anal Calorim. 2007;90:827–31.
Young PH, Dollimore D, Schall CA. Thermal analysis of solid-solid interactions in binary mixtures of alkylcyclohexanes using DSC. J Therm Anal Calorim. 2000;62:163–71.
Hipeaux JC, Born M, Durand JP, Claudy P, Létoffé JM. Physico-chemical characterization of base stocks and thermal analysis by differential scanning calorimetry and thermomicroscopy at low temperature. Thermochim Acta. 2000;348:147–59.
Petitjean D, Schmitt JF, Laine V, Bouroukba M, Cunat C, Dirand M. Presence of isoalkanes in waxes and their influence on their physical properties. Energy Fuels. 2008;22:697–701.
Petitjean D, Schmitt JF, Laine V, Cunat C, Dirand M. Influence of the alkane molar distribution on the physical properties of synthetic waxes. Energy Fuels. 2010;24:3028–33.
Turner WR. Normal alkanes. Ind Eng Chem Prod Res Dev. 1971;10:238–60.
Dirand M, Chevallier V, Provost E, Bouroukba M, Petitjean D. Multicomponent paraffin waxes and petroleum solid deposits: structural and thermodynamic state. Fuel. 1998;77:1253–60.
Srivastava SP, Butz T, Oschmann H-J, Rahimian I. Study of the temperature and enthalpy of thermally induced phase-transitions in n-alkanes, their mixtures and fischer-tropsch waxes. Pet Sci Technol. 2000;18:493–518.
Khan AR, Mahto V, Fazal SA, Laik S. Studies of wax deposition onset in the case of Indian crude oil. Pet Sci Technol. 2008;26:1706–15.
Edwards Y, Isacsson U. Wax in bitumen. Road Mater Pavement Des. 2005;6:281–309.
Piroozian A, Hemmati M, Ismail I, Manan MA, Bayat AE, Mohsin R. Effect of emulsified water on the wax appearance temperature of water-in-waxy-crude-oil emulsions. Thermochim Acta. 2016;637:132–42.
Sun G, Li C, Yang F, Yao B, Xiao Z. Experimental investigation on the gelation process and gel structure of water-in-waxy crude oil emulsion. Energy Fuels. 2017;31:271–8.
Li H, Gong J. The effect of pressure on wax disappearance temperature and wax appearance temperature of water cut crude oil. Beijing: International Society of Offshore and Polar Engineers; 2010. p. 92–6.
Ji H-Y, Tohidi B, Danesh A, Todd AC. Wax phase equilibria: developing a thermodynamic model using a systematic approach. Fluid Phase Equilib. 2004;216:201–17.
Pauly J, Daridon J-L, Sansot J-M, Coutinho JAP. The pressure effect on the wax formation in diesel fuel. Fuel. 2003;82:595–601.
Li Z, Firoozabadi A. Modeling asphaltene precipitation by n-alkanes from heavy oils and bitumens using cubic-plus-association equation of state. Energy Fuels. 2010;24:1106–13.
Kutcherov V, Chernoutsan A. Crystallization and glass transition in crude oils and their fractions at high pressure. Int J Thermophys. 2006;27:474–85.
Kutcherov V, Lundin A, Ross RG, Anisimov M, Chernoutsan A. Glass transition in viscous crude oils under pressure. Int J Thermophys. 1994;15:165–76.
Kutcherov V. Glass transition in crude oils under pressure. Int J Thermophys. 2006;27:467–73.
Juyal P, Cao T, Yen A, Venkatesan R. Study of live oil wax precipitation with high-pressure micro-differential scanning calorimetry. Energy Fuels. 2011;25:568–72.
Kutcherov V, Chernoutsan A, Brazhkin V. Crystallization and glass transition in crude oils and their fractions at atmospheric and high pressures. J Mol Liq. 2017;241:428–34.
Stalkup FI. Carbon dioxide miscible flooding: past, present, and outlook for the future. J Pet Technol. 1978;30:1102–12.
Hosseinipour A, Japper-Jaafar AB, Yusup S. The effect of CO2 on wax appearance temperature of crude oils. Proced Eng. 2016;148:1022–9.
Jiang B, Qiu L, Li X, Yang S, Li K, Chen H. Measurement of the wax appearance temperature of waxy oil under the reservoir condition with ultrasonic method. Pet Explor Dev. 2014;41:509–12.
Daridon J-L, Pauly J, Coutinho JAP, Montel F. Solid−liquid−vapor phase boundary of a north sea waxy crude: measurement and modeling. Energy Fuels. 2001;15:730–5.
Hamouda AA, Viken BK. Wax deposition mechanism under high-pressure and in presence of light hydrocarbons. In: SPE International Symposium on Oilfield Chemistry, New Orleans, Louisiana: Society of Petroleum Engineers; March 1993; 385–96.
Vieira LC, Buchuid MB, Lucas EF. Effect of pressure on the crystallization of crude oil waxes. II. Evaluation of crude oils and condensate. Energy Fuels. 2010;24:2213–20.
Vieira LC, Buchuid MB, Lucas EF. Evaluation of pressure on the crystallization of waxes using microcalorimetry. J Therm Anal Calorim. 2013;111:583–8.
Das SK, Butler RM. Extraction of heavy oil and bitumen using solvents at reservoir pressure. In: Technical Meeting/Petroleum Conference of the South Saskatchewan Section. Regina: Petroleum Society of Canada; October 1995; 1–15.
Krishna R, Bhattarcharjee S, Joshi GC, Singh H, Purohit RC, Dilawar SVK, et al. Correlation of low temperature properties of diesel fuel with composition. Erdol und Kohle, Erdgas, Petrochemie. 1989;42:72–5.
Noel F. Thermal analysis of lubricating oils. Thermochim Acta. 1972;4:377–92.
García MDC, Carbognani L. Asphaltene−paraffin structural interactions. effect on crude oil stability. Energy Fuels. 2001;15:1021–7.
Orea M, Ranaudo MA, Lugo P, López L. Retention of alkane compounds on asphaltenes. insights about the nature of asphaltene-alkane interactions. Energy Fuels. 2016;30:8098–113.
Mahmoud R, Gierycz P, Solimando R, Rogalski M. Calorimetric probing of n-alkane−petroleum asphaltene interactions. Energy Fuels. 2005;19:2474–9.
Alcazar-Vara LA, Garcia-Martinez JA, Buenrostro-Gonzalez E. Effect of asphaltenes on equilibrium and rheological properties of waxy model systems. Fuel. 2012;93:200–12.
Gray MR. Consistency of asphaltene chemical structures with pyrolysis and coking behavior. Energy Fuels. 2003;17:1566–9.
Carbognani L, Rogel E. Solid petroleum asphaltenes seem surrounded by alkyl layers. Pet Sci Technol. 2003;21:537–56.
Wiehe IA. The pendant-core building block model of petroleum residua. Energy Fuels. 1994;8:536–44.
Ganeeva YM, Yusupova TN, Romanov GV, Gubaidullin AT, Samigullina AI. The composition and thermal properties of waxes in oil asphaltenes. J Therm Anal Calorim. 2015;122:1365–73.
Ariza-Leon E, Molina-Velasco D-R, Chaves-Guerrero A. Review of studies on asphaltene - wax interaction and the effect thereof on crystallization. CT&F Ciencia, Tecnol y Futur. 2014;5:39–53.
Yang X, Kilpatrick P. Asphaltenes and waxes do not interact synergistically and coprecipitate in solid organic deposits. Energy Fuels. 2005;19:1360–75.
Oliveira GE, Mansur CRE, Lucas EF, González G, de Souza WF. The effect of asphaltenes, naphthenic acids, and polymeric inhibitors on the pour point of paraffins solutions. J Dispers Sci Technol. 2007;28:349–56.
García MDC. Crude oil wax crystallization. The effect of heavy n-paraffins and flocculated asphaltenes. Energy Fuels. 2000;14:1043–8.
Senra M, Panacharoensawad E, Kraiwattanawong K, Singh P, Fogler HS. Role of n-alkane polydispersity on the crystallization of n-alkanes from solution. Energy Fuels. 2008;22:545–55.
Kravchenko V. The eutectics and solid solutions of paraffins. Acta Physicochim URSS. 1946;21:335–44.
Kousksou T, Jamil A, El Rhafiki T, Zeraouli Y. Paraffin wax mixtures as phase change materials. Sol Energy Mater Sol Cells. 2010;94:2158–65.
He B, Martin V, Setterwall F. Liquid–solid phase equilibrium study of tetradecane and hexadecane binary mixtures as phase change materials (PCMs) for comfort cooling storage. Fluid Phase Equilib. 2003;212:97–109.
Wang W, Huang Q, Wang C, Li S, Qu W, Zhao J, et al. Effect of operating conditions on wax deposition in a laboratory flow loop characterized with DSC technique. J Therm Anal Calorim. 2015;119:471–85.
Valinejad R, Solaimany Nazar AR. An experimental design approach for investigating the effects of operating factors on the wax deposition in pipelines. Fuel. 2013;106:843–50.
Huang Q, Wang J, Zhang J. Physical properties of wax deposits on the walls of crude pipelines. Pet Sci. 2009;6:64–8.
Huang QY. Modeling of wax deposition on waxy crude pipelines. Ph. D. Thesis, China University of Petroleum, Beijing; 2000.
Martins JA, Cruz-Pinto JJC. The temperature calibration on cooling of differential scanning calorimeters. Thermochim Acta. 1999;332:179–88.
Menczel JD, Leslie TM. Temperature calibration of an electrical compensation DSC on cooling using thermally stable high purity liquid crystals. J Therm Anal. 1993;40:957–70.
Kök MV, Varfolomeev MA, Nurgaliev DK. Wax appearance temperature (WAT) determinations of different origin crude oils by differential scanning calorimetry. J Pet Sci Eng. 2018;168:542–5.
Roenningsen HP, Bjoerndal B, Baltzer Hansen A, Batsberg Pedersen W. Wax precipitation from North Sea crude oils: 1. Crystallization and dissolution temperatures, and Newtonian and non-Newtonian flow properties. Energy Fuels. 1991;5:895–908.
Martos C, Coto B, Espada JJ, Robustillo MD, Gómez S, Peña JL. Experimental determination and characterization of wax fractions precipitated as a function of temperature. Energy Fuels. 2008;22:708–14.
Espada JJ, Coutinho JAP, Peña JL. Evaluation of methods for the extraction and characterization of waxes from crude oils. Energy Fuels. 2010;24:1837–43.
Fan K, Huang Q, Li S. Determination of the optimizing operating procedure for DSC test of wax-solvent samples with narrow and sharp wax peak and error analysis of data reliability. J Therm Anal Calorim. 2016;126:1713–25.
Khoshooei MA. Vapour-liquid equilibrium of by-products n-alcohols and 1, 3-propanediol from polyol production. M.Sc. Thesis, University of Alberta, Edmonton; 2013.
Monger-McClure TG, Tackett JE, Merrill LS. Comparisons of cloud point measurement and paraffin prediction methods. SPE Prod Facil. 1999;14:4–16.
Queimada AJ, Dauphin C, Marrucho IM, Coutinho JA. Low temperature behaviour of refined products from DSC measurements and their thermodynamical modelling. Thermochim Acta. 2001;372:93–101.
Guo X, Pethica BA, Huang JS, Adamson DH, Prud’homme RK. Effect of cooling rate on crystallization of model waxy oils with microcrystalline poly(ethylene butene). Energy Fuels. 2006;20:250–6.
Mansourpoor M, Azin R, Osfouri S, Izadpanah AA. Study of wax disappearance temperature using multi-solid thermodynamic model. J Pet Explor Prod Technol. 2018 (in-press).
Bosselet F, Létoffé JM, Claudy P, Valentin P. Etude du comportement thermique des n-alcanes dans des milieux hydrocarbones complexes par analyse calorimetrique differentielle. II. Determination du taux de n-alcanes contenu dans un gazole. Determination du point de trouble. Thermochim Acta. 1983;70:19–34.
Baltzer HA, Larsen E, Batsberg PW, Nielsen AB, Roenningsen HP. Wax precipitation from North Sea crude oils. 3. Precipitation and dissolution of wax studied by differential scanning calorimetry. Energy Fuels. 1991;5:914–23.
Heino E-L. Determination of cloud point for petroleum middle distillates by differential scanning calorimetry. Thermochim Acta. 1987;114:125–30.
Taggart AM, Voogt F, Clydesdale G, Roberts KJ. An examination of the nucleation kinetics of n-alkanes in the homologous series C13H28 to C32H66, and their relationship to structural type, associated with crystallization from stagnant melts. Langmuir. 1996;12:5722–8.
DE Andrade V, Marcelino Neto MA, Negrão COR. The importance of supersaturation on determining the solid-liquid equilibrium temperature of waxy oils. Fuel. 2017;206:516–23.
Tiwary D, Mehrotra AK. Phase transformation and rheological behaviour of highly paraffinic “Waxy” mixtures. Can J Chem Eng. 2004;82:162–74.
Kasumu AS, Arumugam S, Mehrotra AK. Effect of cooling rate on the wax precipitation temperature of “waxy” mixtures. Fuel. 2013;103:1144–7.
Japper-Jaafar A, Bhaskoro PT, Mior ZS. A new perspective on the measurements of wax appearance temperature: comparison between DSC, thermomicroscopy and rheometry and the cooling rate effects. J Pet Sci Eng. 2016;147:672–81.
Faust HR. The thermal analysis of waxes and petrolatums. Thermochim Acta. 1978;26:383–98.
Claudy P, Létoffé J-M, Chagué B, Orrit J. Crude oils and their distillates: characterization by differential scanning calorimetry. Fuel. 1988;67:58–61.
Claudy P, Létoffé J-M, Neff B, Damin B. Diesel fuels: determination of onset crystallization temperature, pour point and filter plugging point by differential scanning calorimetry. Correlation with standard test methods. Fuel. 1986;65:861–4.
Miller R, Dawson G. Characterization of hydrocarbon waxes and polyethylenes by DSC. Thermochim Acta. 1980;41:93–105.
Liu Y, Li X, Hu P, Hu G. Study on the supercooling degree and nucleation behavior of water-based graphene oxide nanofluids PCM. Int J Refrig. 2015;50:80–6.
Jiang Z, Hutchinson J, Imrie C. Measurement of the wax appearance temperatures of crude oils by temperature modulated differential scanning calorimetry. Fuel. 2001;80:367–71.
Ruwoldt J, Kurniawan M, Oschmann H-J. Non-linear dependency of wax appearance temperature on cooling rate. J Pet Sci Eng. 2018;165:114–26.
Struchkov IA, Rogachev MK. Wax precipitation in multicomponent hydrocarbon system. J Pet Explor Prod Technol. 2017;7:543–53.
Paiva FL, Marchesini FH, Calado VMA, Galliez AP. Wax precipitation temperature measurements revisited: the role of the degree of sample confinement. Energy Fuels. 2017;31:6862–75.
Alcazar-Vara LA, Buenrostro-Gonzalez E. Characterization of the wax precipitation in Mexican crude oils. Fuel Process Technol. 2011;92:2366–74.
Hammami A, Ratulowski J, Coutinho JAP. Cloud points: can we measure or model them? Pet Sci Technol. 2003;21:345–58.
Kök MV, Letoffe JM, Claudy P. DSC and rheometry investigations of crude oils. J Therm Anal Calorim. 1999;56:959–65.
Alcazar-Vara, LA, Buenrostro-Gonzalez E. Liquid-solid phase equilibria of paraffinic systems by DSC measurements. In: Elkordy AA, editor. Appl Calorim a Wide Context. Rijeka: InTech; 2013. pp. 254–76.
Huang Z, Zheng S, Fogler HS. Wax deposition: experimental characterizations, theoretical modeling, and field practices. Boca Raton: CRC Press; 2016.
Kruka VR, Cadena ER, Long TE. Cloud-point determination for crude oils. J Pet Tech. 1995;47:681–7.
Erickson DD, Niesen VG, Brown TS. Thermodynamic measurement and prediction of paraffin precipitation in crude oil. In: SPE Annual Technical Conference and Exhibition. Houston, Texas: Society of Petroleum Engineers; Octpber 1993;933–48.
Cazaux G, Barre L, Brucy F. Waxy crude cold start: assessment through gel structural properties. In: SPE Annual Technical Conference and Exhibition. New Orleans, Louisiana: Society of Petroleum Engineers; September 1998;729–739.
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Ahmadi Khoshooei, M., Fazlollahi, F., Maham, Y. et al. A review on the application of differential scanning calorimetry (DSC) to petroleum products. J Therm Anal Calorim 138, 3485–3510 (2019). https://doi.org/10.1007/s10973-019-08022-0
- Structural study
- Wax precipitation
- Temperature scanning rate
- Modulated temperature program