Abstract
Vanadium-based body-centered cubic alloy has been considered as a potential candidate for hydrogen storage and permeation applications at ambient temperature. However, the cost of vanadium is too high to be used for the commercial application. The high cost is mainly because of the multisteps in the synthesis process. Aluminothermy is a well-established cost-effective technique to synthesize the vanadium. In this process, aluminum will be an unavoidable impurity, which may affect the hydrogen storage and permeation properties of vanadium. Therefore, it is desirable to understand the effect of residual aluminum on the hydrogen storage properties of vanadium. In the present study, vanadium was prepared by aluminothermy process and refined by electron beam melting. The thermodynamics and kinetics of hydrogen absorption–desorption of as such synthesized vanadium were studied. The hydrogen storage properties of vanadium were found to be marginally influenced by the presence of aluminum as an interstitial impurity.
Similar content being viewed by others
References
Kumar S, Singh A, Jain U, Dey GK. Development of tantalum–zirconium alloy for hydrogen purification. Fusion Eng Des. 2016;109–111:1487–90.
Kumar S, Mukherjee A, Sonak S, Krishnamurthy N. Studies on the interaction of hydrogen with Li2TiO3 pebbles and pellets. J Nucl Mater. 2013;443:207–11.
Kumar S, Tirpude A, Krishnamurthy N. Studies on the solubility of hydrogen in the molten Pb83Li17 eutectic alloy. Int J Hydrog Energy. 2013;38(14):6002–7.
Akiba E. Hydrogen absorbing alloys. Curr Opin Solid Mater Sci. 1999;4:267–72.
Zhevago NK. Other methods of the physical storage of hydrogen. Compend Hydrog Energy. 2016;82:189–218.
Taxak M, Kumar S, Krishnamurthy N. Thermodynamic parameters for the Ta–Cr–H solid solution from equilibrium P–C–T Data. J Chem Thermodyn. 2013;67:48–54.
Schlapbach L, Züttel A. Hydrogen-storage materials for mobile applications. Nature. 2001;414:353–8.
Sakintuna B, Lamari-Darkrim F, Hirscher M. Metal hydride materials for solid hydrogen storage: a review. Int J Hydrog Energy. 2007;32:1121–312.
Kumar S, Miyaoka H, Ichikawa T, Dey GK, Kojima Y. Micro-alloyed Mg2Ni for better performance as negative electrode of Ni–MH battery and hydrogen storage. Int J Hydrog Energy. 2017;42(7):5220–6.
Samir FM. Intermetallic hydrides: a review with ab initio aspects. Prog Solid State Chem. 2010;38:1–37.
Kumar S, Taxak M, Krishnamurthy N. Hydrogen absorption kinetics of V4Cr4Ti alloy prepared by aluminothermy process. Int J Hydrog Energy. 2012;37(4):3283–91.
Krishnamurthy N, Kumar S, Awasthi A. Preparation of binary alloys of refractory metals by co-reduction of group V metals alloys. In: 17th Plansee seminar (2009), vol 1, RM 30/1-30/10.
Kumar S, Krishnamurthy N. Synthesis of V–Ti–Cr alloys by aluminothermy co-reduction of its oxides. Int J Process Appl Ceram. 2011;5(4):181–6.
Kumar S. Studies on hydrogen interaction with vanadium and vanadium–aluminum alloys. Ph.D. thesis: Homi Bhabha National Institute, Mumbai, India http://shodhganga.inflibnet.ac.in/handle/10603/11610?mode=full.
Kumar S, Krishnamurthy N. Hydrogen absorption kinetics in ball milled V 80 wt% LaNi5 composite. J Alloys Compd. 2013;580:S179–82.
Wang H, Lin H-J, Cai WT, Ouyang L-Z, Zhu M. Tuning Kinetics and thermodynamics of hydrogen storage in light metal element systems—a review of recent progress. J Alloys Compd. 2016;658:280–300.
Kumar S, Krishnamurthy N. Variation of activation energy of hydrogen absorption of vanadium as a function of Al. Int J Hydrog Energy. 2012;37(18):13429–36.
Smith DL, Chung H-M, Loomis BA, Matsui H, Votinov S, Witzenburg WV. Development of vanadium-base alloys for fusion first wall blanket applications. Fusion Eng Des. 1995;29:399–410.
Kumar S, Jain A, Ichikawa T, Kojima Y, Dey GK. Development of vanadium based hydrogen storage material: a review. Renew Sustain Energy Rev. 2017;72:791–800.
Seo C-Y, Kim J-H, Lee PS, Lee J-Y. Hydrogen storage properties of vanadium based bcc solid solution metal hydride. J. Alloys Compds. 2003;348:252–7.
Kumar S, Tiwari GP, Sonak S, Jain U, Krishnamurthy N. High-performance FeTi-3.1 mass% V for on-board hydrogen storage solution. Energy. 2014;75:520–4.
Kumar S, Taxak M, Krishnamurthy N. Synthesis and hydrogen absorption in V4Ti4Cr alloy. J Therm Anal Calorim. 2013;112(1):51–7.
Kumar S, Taxak M, Krishnamurthy N. Hydrogen absorption kinetics of V-Al alloy. J Therm Anal Calorim. 2013;112(1):5–10.
Tanaka T, Keita M, Azofeifa DE. Theory of hydrogen absorption in metal hydrides. Phys Rev B. 1981;24(4):1771–6.
Kumar S, Sonak S, Krishnamurthy N. Hydrogen solid solution thermodynamics of V1−x Al x (x: 0, 0.18, 0.37, 0.52) alloys. Int J Hydrog Energy. 2013;38(23):9928–34.
Taxak M, Kumar S, Krishnamurthy N, Tiwari GP, Suri AK. Change in lattices parameter of tantalum due to dissolved hydrogen. Int J Process Appl Ceram. 2012;6(2):73–6.
Kumar S, Taxak M, Krishnamurthy N, Suri AK, Tiwari GP. Terminal solid solubility of hydrogen in V–Al solid solution. Int. J Refract Met Hard Mater. 2012;31:76–81.
Yukawa H, Yamashita D, Ito S, Morinaga M, Yamaguchi S. Compositional dependence of hydrating properties of vanadium alloys at low hydrogen pressure. J. Alloys Compds. 2003;356–357:45–9.
Lototsky MV, Yartys VA, Zavaliy IY. Vanadium-based BCC alloys phase-structural characteristics and hydrogen sorption properties. J Alloys Compds. 2005;404–406:421–6.
Kumar S, Krishnamurthy N. Effects of aluminum on solubility and β phase stability of the vanadium–hydrogen system. Int J Refract Met Hard Mater. 2012;35:191–5.
Pauling L. Location of hydrogen atoms in tetragonal and monoclinic modifications of β 1–V2H. J Solid State Chem. 1989;79:63–4.
Wiswall R. Hydrogen storage in metals in topics. In: Apefeld G, Volkl J, editors. Applied physics hydrogen in metals II, vol. 29. Berlin: Springer; 1978.
Kumar S, Tiwari GP, Krishnamurthy N. Tailoring the hydrogen desorption thermodynamics of V2H by alloying additives. J Alloys Compd. 2015;645:S252–6.
Matsumura T, Yukawa H, Morinaga M. Alloying effect on the electronic structure of VH2 and V2H. J Alloys Compds. 1999;284:82–8.
Acknowledgements
This research work was supported by JSPS—Japan under the “Postdoctoral Fellowship Program for Overseas Researchers” granted to Sanjay Kumar (JSPS ID: P15078). The authors appreciate the keen interest and motivation shown by Professor GK Dey, Director Materials Group during the investigations.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
Authors declare no conflict of interest for this research.
Rights and permissions
About this article
Cite this article
Kumar, S., Jain, A. & Kojima, Y. Thermodynamics and kinetics of hydrogen absorption–desorption of vanadium synthesized by aluminothermy. J Therm Anal Calorim 130, 721–726 (2017). https://doi.org/10.1007/s10973-017-6430-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-017-6430-1