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New continuous solid solution in the Zn2InV3O11–Mg2InV3O11 system

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Abstract

A new substitutional solid solution of the composition Zn2−xMgxInV3O11 was found to form in the Zn2InV3O11–Mg2InV3O11 system. The new phase was obtained by solid-state reactions. The phase was synthesized by heating in air adequate mixtures of ZnO, V2O5, In2O3 with a precursor of MgO and was characterized using XRD, DTA–TG, IR and SEM/EDX methods. The effects of the degree of Mg2+ ion incorporation in the crystal lattice of Zn2InV3O11 replacing Zn2+ on the unit cell volume, thermal stability, morphology and IR spectra of Zn2−xMgxInV3O11 in the range 0.0 < x < 2.0 were determined. A phase diagram up to solidus line of the pseudobinary Zn2InV3O11–Mg2InV3O11 system was constructed.

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Authors and Affiliations

  1. Faculty of Chemical Technology and Engineering, Department of Inorganic and Analytical Chemistry, West Pomeranian University of Technology, Szczecin, Al. Piastow 42, 71-065, Szczecin, Poland

    Monika Bosacka & Elżbieta Filipek

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  1. Monika Bosacka
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  2. Elżbieta Filipek
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Correspondence to Monika Bosacka.

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Bosacka, M., Filipek, E. New continuous solid solution in the Zn2InV3O11–Mg2InV3O11 system. J Therm Anal Calorim 130, 63–68 (2017). https://doi.org/10.1007/s10973-017-6235-2

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  • DOI: https://doi.org/10.1007/s10973-017-6235-2

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