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Journal of Thermal Analysis and Calorimetry

, Volume 128, Issue 1, pp 29–37 | Cite as

Growth, optical, thermal, dielectric and mechanical studies of sodium hydrogen succinate single crystal

A third-order NLO material
  • P. S. Latha Mageshwari
  • R. Priya
  • S. Krishnan
  • V. Joseph
  • S. Jerome Das
Article

Abstract

Sodium hydrogen succinate, an alkali metallo-organic third-order nonlinear optical crystal, had been grown successfully using aqueous solution by slow evaporation technique at room temperature. Transparent single crystals were selected and subjected to single-crystal X-ray diffraction analysis to identify lattice parameters, space group and morphology. The grown crystal was further subjected to powder X-ray diffraction to analyze the crystalline quality, UV–Vis–NIR spectral analysis to reveal optical transparency, FTIR spectroscopy for confirmation of the functional group analysis and TG–DTG/DSC analysis to determine the thermal stability. The dielectric constant and dielectric loss were studied as a function of frequency at different temperatures, and the results were discussed. The mechanical properties were calculated by Vickers microhardness test, and the third-order nonlinear optical parameters such as nonlinear refractive index, nonlinear absorption coefficient and real and imaginary parts of the third-order nonlinear optical susceptibility were determined by Z-scan technique.

Keywords

Crystal growth Thermal studies Third harmonic generation Z-scan technique 

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2016

Authors and Affiliations

  • P. S. Latha Mageshwari
    • 1
  • R. Priya
    • 2
  • S. Krishnan
    • 3
  • V. Joseph
    • 4
  • S. Jerome Das
    • 4
  1. 1.Department of PhysicsR. M. K. Engineering CollegeKavaraipettaiIndia
  2. 2.Department of PhysicsR. M. D. Engineering CollegeKavaraipettaiIndia
  3. 3.Department of PhysicsB. S.Abdur Rahman UniversityChennaiIndia
  4. 4.Department of PhysicsLoyola CollegeChennaiIndia

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