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The study and modeling of cyclocarbonylation reactions for chlorinated epoxy resins with applying Calvet calorimetry

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Abstract

The methodology and results of cyclocarbonylation kinetic study for chlorinated epichlorohydrine oligomers with sodium bicarbonate are presented. Calvet calorimetry is applied as the main kinetic research technique. Correlation between heat production and epichlorohydrine groups conversion has been established. A mathematical model of the cyclocarbonylation reaction in a two-phase “solid–liquid” system has been developed. The proposed model takes into account mass transfer phenomena between the two phases as well as chemical reactions in the liquid reaction phase. The mathematical model kinetic parameters were determined in the result of solving an inverse kinetic task with applying heat production experimental data together with product concentrations data. The model developed in course of the work was used to determine the optimal conditions for running cyclocarbonylation process.

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Acknowledgements

Calorimetric measurements and data processing were performed in St. Petersburg Mining University with the equipment and software obtained due to the Development Program “National Research University” (2011–2013) in course of the ministry program “Support of Fundamental Research Works” (2014–2016). The authors are grateful to their colleagues A. Velts and V. Lunev, who provided the chemical background and reagents and performed the necessary chemical analyses to fulfill this work.

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  1. National Mineral Resources University “Mining University”, Vasilievskii Ostrov, 21 Line, 2, St. Petersburg, Russia, 199106

    F. Y. Sharikov & Yu V. Sharikov

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  1. F. Y. Sharikov
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  2. Yu V. Sharikov
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Correspondence to F. Y. Sharikov.

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Sharikov, F.Y., Sharikov, Y.V. The study and modeling of cyclocarbonylation reactions for chlorinated epoxy resins with applying Calvet calorimetry. J Therm Anal Calorim 126, 743–754 (2016). https://doi.org/10.1007/s10973-016-5580-x

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  • DOI: https://doi.org/10.1007/s10973-016-5580-x

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