Abstract
The Eu3+-activated strontium aluminate-based Sr3Al2O6:Eu3+,Ho3+, Sr2.99Ba0.01Al2O6:Eu3+,Ho3+ and Sr2.99Mg0.01Al2O6:Eu3+,Ho3+ phosphor systems were prepared by the solid-state reaction method under open atmosphere. DTA/TG analysis was conducted to obtain the thermal behaviours of the phosphors. Depending on the thermal analysis results, the heat treatments were carried out and the obtained single phase formations were characterised by X-ray diffraction. The effects of Ba2+ and Mg2+, which were individually added as trace amounts, and also of the same activator (Eu3+) and co-dopant (Ho3+) that were used for all host lattices, on the photoluminescence and phase formation properties of the hosts were investigated.
Similar content being viewed by others
References
Öztürk E, Karacaoglu E. Investigation of phase formation dependency of photoluminescence properties of Eu3+ in Mg4Al2O7:Eu3+, Dy3+ and Ca4Al2O7:Eu3+, Dy3+ red-emitting phosphors. J Therm Anal Calorim. 2015;120:1139–43.
Chen XY, Bao SP, Wu YC. Controlled synthesis and luminescent properties of Eu2+ (Eu3+), Dy3+-doped Sr3Al2O6 phosphors by hydrothermal treatment and postannealing approach. J Solid State Chem. 2010;183:2004–11.
Huang P, Cui C, Wang S. Influence of calcination temperature on luminescent properties of Sr3Al2O6:Eu2+, Dy3+ phosphors prepared by sol–gel-combustion processing. Opt Mater. 2009;32:184–9.
Zhang P, Lingxia L, Yuming T. The low temperature synthesis of Eu2+ and Dy3+ activated Sr3Al2O6 nanophosphors by microwave method. Phys B. 2009;404:4286–9.
Nag A, Kutty TRN. Photoluminescence of Sr2−xLnxCeO4+x/2 (Ln = Eu, Sm or Yb) prepared by a wet chemical method. J Mater Chem. 2003;13(2):370–6.
Scholten MJ, Schoonman J, van Miltenburg JC, Oonk HAJ. Synthesis of SrCeO3, BaCeO3, SrZrO3 and BaZrO3 and their reaction with CO2. Solid Oxide Fuel Cells. 1993;93(4):146–55.
Tian Y, Zhang P, Zheng Z, Chai Y. A novel approach for preparation of Sr3Al2O6:Eu2+, Dy3+ nanoparticles by sol–gel–microwave processing. Mater Lett. 2012;73:157–60.
Prodjosantoso AK, Kennedy BJ. Heavy metals in cement phases: on the solubility of Mg, Cd, Pb and Ba in Ca3Al2O6. Cem Concr Res. 2003;633:1077–84.
Sullivan E, Avdeev M, Vogt T. Structural distortions in Sr3−xAxMO4F (A = Ca, Ba; M = Al, Ga, In) anti-Perovskites and corresponding changes in photoluminescence. J Solid State Chem. 2012;194:297–306.
Kaur J, Parganiha Y, Dubey V. Luminescence studies of Eu3+ doped calcium bromofluoride phosphor. Phys Res Int. 2013. doi:10.1155/2013/494807.
Georgescu S, Popescu M, Sava F, Velea A, Pavelescu G. Eu3+ luminescence in As2S3 dot network. Chalcogenide Lett. 2009;8(12):737–8.
Yanmin Q, Xinbo Z, Xiao Y, Yan C, Hai G. Photoluminescent properties of Sr2SiO4:Eu3+ and Sr2SiO4:Eu2+ phosphors prepared by solid-state reaction method. J Rare Earths. 2009;27(2):323–6.
Das S, Reddy AA, Ahmad S, Nagarajan R, Prakash GV. Synthesis and optical characterization of strong red light emitting KLaF4:Eu3+ nanophosphors. Chem Phys Lett. 2011;508:117–20.
Li Y, Chang Y, Lin Y, Chang Y, Lin Y. Synthesis and luminescent properties of Ln3+ (Eu3+, Sm3+, Dy3+)-doped lanthanum aluminum germanate LaAlGe2O7 phosphors. J Alloys Compd. 2007;439:367–75.
Acknowledgements
The authors would like to thank Karamanoglu Mehmetbey University, Scientific Research Projects Commission (BAP, Project Number: 05-YL-14) in the Republic of Turkey for its financial support.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Öztürk, E. The effect of Ba/Mg impurities on the phase formation and photoluminescence properties of (Sr3−xMx)Al2O6:Eu3+,Ho3+ (M = Ba, Mg) phosphors. J Therm Anal Calorim 126, 365–369 (2016). https://doi.org/10.1007/s10973-016-5546-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-016-5546-z