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Unknown phase equilibria in the ternary oxide V2O5–CuO–In2O3 system in subsolidus area

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Abstract

The syntheses of two compounds Cu2In3VO9 and CuInVO5, forming in the ternary system V2O5–CuO–In2O3, are described. The compound CuInVO5 has been for the first time obtained as the pure phase. The temperatures and modes of melting of the compounds are determined, and their IR spectra are analysed. The phase diagram of V2O5–CuO–In2O3 system in subsolidus area is constructed by DTA and XRD methods. This system is shown to consist of 11 subsidiary subsystems in which three solid phases coexist at equilibrium. The melting temperatures of these subsystems are also determined.

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Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, West Pomeranian University of Technology, Szczecin, Al. Piastow 42, 71-065, Szczecin, Poland

    Monika Bosacka, Elzbieta Filipek & Agnieszka Paczesna

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  1. Monika Bosacka
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  2. Elzbieta Filipek
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  3. Agnieszka Paczesna
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Correspondence to Monika Bosacka.

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Bosacka, M., Filipek, E. & Paczesna, A. Unknown phase equilibria in the ternary oxide V2O5–CuO–In2O3 system in subsolidus area. J Therm Anal Calorim 125, 1161–1170 (2016). https://doi.org/10.1007/s10973-016-5446-2

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