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Complexes of some transition metal ions with selected dichlorophenoxyacetic acid

Thermal, spectral and magnetic properties

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Abstract

This paper presents the interpretations of data obtained from the investigations of 2,4-dichlorophenoxyacetates of selected lanthanide(III) ions. The compounds of 2,4-dichlorophenoxyacetic acid ion with La(III), Pr(III)–Lu(III) with the formula Ln(C8H5O3Cl2)3·nH2O, where Ln(III) = lanthanides, n = 2, 4 or 5 depending on Ln(III) ions, were synthesized and characterized by elemental analysis, FTIR spectroscopy, magnetic and thermogravimetric studies and also by X-ray powder diffraction (XRD) measurements. The compounds crystallize in monoclinic or triclinic systems. The carboxylate groups act as bidentate chelating agents. On heating in air up to 1173 K, the analysed compounds are decomposed in three steps: they are dehydrated to anhydrous salts which next are decomposed to the oxides of respective metals with intermediate formation of the oxychlorides. The enthalpy values of the dehydration process changed from 44.00 to 91.34 kJ mol−1. The magnetic moments of compounds were determined in the ranges of 76–303 K and for some of them at 4.2–303 K.

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Authors and Affiliations

  1. Faculty of Chemistry, Maria Curie-Skłodowska University, 20-031, Lublin, Poland

    Wiesława Ferenc, Beata Cristóvão & Dariusz Osypiuk

  2. Institute of Physics, Maria Curie-Skłodowska University, 20-031, Lublin, Poland

    Jan Sarzyński

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  1. Wiesława Ferenc
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  2. Beata Cristóvão
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  3. Jan Sarzyński
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  4. Dariusz Osypiuk
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Correspondence to Wiesława Ferenc.

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Ferenc, W., Cristóvão, B., Sarzyński, J. et al. Complexes of some transition metal ions with selected dichlorophenoxyacetic acid. J Therm Anal Calorim 126, 129–139 (2016). https://doi.org/10.1007/s10973-016-5321-1

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