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Density and excess properties of N-methyldiethanolamine (MDEA) with 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate [hmim][FAP]

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Abstract

In the present work, new data on the densities and refractive indices for 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate [hmim][FAP] with N-methyldiethanolamine are reported for various concentrations and at temperatures (303.15–328.15) K. Excess molar volumes \({V^{\text{E}}}\) and excess refractive indices \( n_{\text{D}}^{\text{E}}\) were calculated from the experimental data. Refractive index values for the binary mixtures were predicted by using Lorentz–Lorenz, Gladstone–Dale and Eykman equations. Excess molar volumes showed positive trend, whereas excess refractive indices showed negative trend over the entire range of temperatures and concentrations studied in the present research.

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Acknowledgements

The financial support by MyRA-Malaysia incentive grant through CO2 Rich Natural Gas Value Chain Program is highly appreciated.

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Authors and Affiliations

  1. Institute of Chemical Engineering and Technology, University of the Punjab, Lahore, Pakistan

    Majid Majeed Akbar

  2. Department of Chemical Engineering, National Institute of Technology, Trichy, 620015, India

    Appusamy Arunagiri

  3. Chemical Engineering Department, Universiti Teknologi PETRONAS, 31750, Tronoh, Perak, Malaysia

    Fareeda Chemat & Thanabalan Murugesan

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  1. Majid Majeed Akbar
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  2. Fareeda Chemat
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  3. Appusamy Arunagiri
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  4. Thanabalan Murugesan
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Correspondence to Thanabalan Murugesan.

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Akbar, M.M., Chemat, F., Arunagiri, A. et al. Density and excess properties of N-methyldiethanolamine (MDEA) with 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate [hmim][FAP]. J Therm Anal Calorim 123, 785–791 (2016). https://doi.org/10.1007/s10973-015-4957-6

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  • DOI: https://doi.org/10.1007/s10973-015-4957-6

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