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Influence of temperature conditions of forming nanosized SnO2-based materials on hydrogen sensor properties

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Abstract

Semiconductor sensors are widely used to detect toxic and flammable gases, and nanosized SnO2 is usually applied as material for gas-sensitive layers of the sensors. Sensor nanomaterial has to provide appropriate value of the electrical resistance of the sensor in air and high sensor response to analyzed gas. Sol–gel synthesis is the most promising to obtain SnO2 nanomaterial because it enables to rich high chemical homogeneity of the obtaining material, to control its particle size and structure at different stages of the material synthesis. These characteristics of the nanomaterials have to determine the sensor properties. To obtain SnO2 sensor nanomaterial, synthesis of xerogel by a sol–gel method via SnCl4·5H2O dissolved in the ethylene glycol was carried out. To provide optimal values of the sensor electrical resistance in air, decomposition of the xerogel was studied by DTA–DTG analysis. This study was carried out by heating the xerogel to 1000 °C in air with heating rates of 2.5, 5 and 10 °C min−1. It was found that decomposition of the xerogel was performed in several stages: water desorption, removing ethanediol-1,2, HCl and CO2. Using the selected heating mode with isothermal holding at 280, 350, 390 and 600 °C, optimized SnO2 nanomaterial was obtained. It was found that sensors based on this material had suitable values of their electrical resistances (150–400 kΩ) and possessed high responses to very small concentration of hydrogen.

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References

  1. Tricoli A, Righettoni M, Teleki A. Semiconductor gas sensors: dry synthesis and application. Angew Chem Int Ed. 2010;49:7632–59.

    Article  CAS  Google Scholar 

  2. Kim H, Jin C, Park S, Kim S, Lee C. H2S gas sensing properties of bare and Pd-functionalized CuO nanorods. Sens Actuators B Chem. 2012;161:594–9.

    Article  CAS  Google Scholar 

  3. Wetchakuna K, Samerjai T, Tamaekonga N, Liewhirana C, Siriwonga C, Kruefua V, Wisitsoraat A, Tuantranont A, Phanichphant S. Semiconducting metal oxides as sensors for environmentally hazardous gases. Sens Actuators B Chem. 2011;160:580–91.

    Article  Google Scholar 

  4. Hübert T, Boon-Brett L, Black G, Banach U. Hydrogen sensors: a review. Sens Actuators B Chem. 2011;157:2329–52.

    Article  Google Scholar 

  5. Suematsu K, Yuasa M, Kida T, Yamazoe N, Shimanoe K. Determination of oxygen adsorption species on SnO2: exact analysis of gas sensing properties using a sample gas pretreatment system. J Electrochem Soc. 2014;161:123–8.

    Article  Google Scholar 

  6. Gurlo A. Interplay between O2 and SnO2: oxygen ionosorption and spectroscopic evidence for adsorbed oxygen. ChemPhysChem. 2006;7:2041–52.

    Article  CAS  Google Scholar 

  7. Rumyantseva MN, Makeeva EA, Gas’kov AM. Influence of the microstructure of semiconductor sensor materials on oxygen chemisorption on their surface. Russ J Gen Chem. 2008;78:2556–65.

    Article  CAS  Google Scholar 

  8. Bacelar WK, Oliveira MM, Souza VC, Longo E, Leite ER. Influence of oxygen adsorbed on tin varistors doped with Co, Mn and Cr oxides. J Mater Sci Mater Electron. 2002;13:409–14.

    Article  CAS  Google Scholar 

  9. Pan SS, Ye C, Teng XM, Fan HT, Li GL. Preparation and characterization of nitrogen-incorporated SnO2 films. Appl Phys A Mater. 2006;85:21–4.

    Article  CAS  Google Scholar 

  10. Pang G, Chen S, Koltypin Y, Zaban A, Feng S, Gedanken A. Controlling the particle size of calcined SnO2 nanocrystals. Nano Lett. 2001;1:723–6.

    Article  CAS  Google Scholar 

  11. Matushko I, Maksymovych N, Yatsimirsky A, Sylenko P, Nikitina N, Kaskevych O, Derkachenko N. Study of stability of long-term operation of H2 adsorption semiconductor sensors. Messenger Natl Taras Shevchenko Univ Kyiv. 2007;45:8–10.

    Google Scholar 

  12. Lingmin Y, Xinhui F, Lijun Q, Lihe M, Wen Y. Dependence of morphologies for SnO2 nanostructures on their sensing property. Appl Surf Sci. 2011;257:3140–4.

    Article  Google Scholar 

  13. Xu C, Tamaki J, Miura N, Yamazoe N. Grain size effects on gas sensitivity of porous SnO2–based elements. Sens Actuators B Chem. 1991;3:147–55.

    Article  CAS  Google Scholar 

  14. Korotcenkov G, Cho BK, Brinzari V. The role of grain size in response of SnO2- and In2O3-based conductometric gas sensors. Adv Mater Res. 2012;486:153–9.

    Article  CAS  Google Scholar 

  15. Supothina S. Gas sensing properties of nanocrystalline SnO2 thin films prepared by liquid flow deposition. Sens Actuators B Chem. 2003;93:526–30.

    Article  CAS  Google Scholar 

  16. Zhu J, Lu Z, Aruna ST, Aurbach D, Gedanken A. Sonochemical synthesis of SnO2 nanoparticles and their preliminary study as Li insertion electrodes. Chem Mater. 2000;12:2557–66.

    Article  CAS  Google Scholar 

  17. Müller R, Hernandez-Ramirez F, Shen H, Du H, Mader W, Mathur S. Influence of precursor chemistry on morphology and composition of CVD-grown SnO2 nanowires. Chem Mater. 2012;24:4028–35.

    Article  Google Scholar 

  18. Madzlan A, Saad Saber A, Wan R, Wan B. Size-controlled synthesis of SnO2 nanoparticles by sol–gel method. Mater Lett. 2013;91:31–4.

    Article  Google Scholar 

  19. Zhang G, Liu M. Preparation of nanostructured tin oxide using a sol–gel process based on tin tetrachloride and ethylene glycol. J Mater Sci. 1999;34:3213–9.

    Article  CAS  Google Scholar 

  20. Oleksenko L, Maksimovich N, Matushko I, Buvailo A, Derkachenko N. Hydrogen sensitivity of sensors based on CoxOy/SnO2/Sb2O5 nanomaterials obtained by the sol–gel method. Russ J Phys Chem. 2013;87:265–9.

    Article  CAS  Google Scholar 

  21. Maksymovych N, Kaskevych O, Nikitina N, Karbun P, Martinenko F, Bakay E. Semiconductor material for adsorption sensors of low molecular organic compounds and method of its preparation. Russian Federation patent No 2119695. 1998.

  22. Dueramae I, Jubsilp C, Takeichi T, Rimdusit S. Thermal degradation mechanism of highly filled nano-SiO2 and polybenzoxazine. J Therm Anal Calorim. 2014;116:435–46.

    Article  CAS  Google Scholar 

  23. Han Z, Han Y, Xu S. Preparation of nano-cerium dioxide and its effect on the thermal decomposition of ammonium perchlorate. J Therm Anal Calorim. 2014;116:273–8.

    Article  CAS  Google Scholar 

  24. Wang L, Ma Z, Liu S, Huang Z. In situ growth mechanism and the thermodynamic functions of zinc oxide nano-arrays and hierarchical structure. J Therm Anal Calorim. 2014;115:201–8.

    Article  CAS  Google Scholar 

  25. ASTM Diffraction date cards of X-ray diffraction data. American Society for testing and materials. Philadelphia. 1946–1996.

  26. Monshi A, Reza Foroughi M, Reza Monshi M. Modified Scherrer equation to estimate more accurately nano-crystallite size using XRD. World J Nano Sci Eng. 2012;2:154–60.

    Article  Google Scholar 

  27. Andrievskii RA. Thermal stability of nanomaterials. Russ Chem Rev. 2002;71:853–66.

    Article  CAS  Google Scholar 

  28. Glezer AM. Amorphous and nanocrystalline structures: similarities, differences, mutual transitions. Khim Zh. 2002;46:57–64.

    CAS  Google Scholar 

  29. De G, Ёhn RK, Xomeritakis G, Brinker C. Nanocrystalline mesoporous palladium activated tin oxide thin films as room-temperature hydrogen gas sensors. J Chem Commun. 2007;18:1840–2.

  30. Gong J, Sun J, Chen Q. Micromachined sol–gel carbon nanotube/SnO2 nanocomposite hydrogen sensor. Sens Actuatores B Chem. 2008;130:829–35.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. National Taras Shevchenko University of Kyiv, 62a Volodymyrska Str., Kiev, 01601, Ukraine

    E. V. Sokovykh, L. P. Oleksenko, N. P. Maksymovych & I. P. Matushko

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  1. E. V. Sokovykh
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  2. L. P. Oleksenko
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  3. N. P. Maksymovych
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  4. I. P. Matushko
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Correspondence to E. V. Sokovykh.

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Sokovykh, E.V., Oleksenko, L.P., Maksymovych, N.P. et al. Influence of temperature conditions of forming nanosized SnO2-based materials on hydrogen sensor properties. J Therm Anal Calorim 121, 1159–1165 (2015). https://doi.org/10.1007/s10973-015-4560-x

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  • DOI: https://doi.org/10.1007/s10973-015-4560-x

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