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Thermal behavior of typical weak basic ion exchange resin

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Abstract

Thermal behaviors of typical weak basic ion exchange resins (301 and 315) were studied with thermogravimetry, elemental analysis, and Fourier transform infrared spectrometer in this study. Results indicated that there were three stages for 301 resin mass loss, the first stage and the second stage were mainly related to the decomposition of functional group, and the third stage was the decomposition of main chain. Whereas there were two stages for 315 resin mass loss, the first stage was elimination of moisture, and the second stage was the decompositions of functional group and main chain. Moreover, the decomposition of tertiary amine had three stages, the polyamine was a continuous mass loss process, and the thermostability of tertiary amine was weaker than that of polyamine.

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References

  1. Qian TB. Ion exchanger application technology. Tianjin: Science and Technology Press; 1984.

    Google Scholar 

  2. He BL. Ion exchange and adsorption resin. Shanghai: Shanghai Science Education Press; 1995.

    Google Scholar 

  3. Wang JS, Chen YS, Deng W, Kan CY. Preparation of sulphonate-containing polymer particles via semi-continuous emulsion copolymerizaion of styrene and sodium styrene sulphonate. Chinese J Polym Sci. 2011;29:111–6.

    CAS  Google Scholar 

  4. Ali M, Ahmad R, Sadat A, Mohammad S. Characterization and kinetics study of the photochlorination of polyethylene. Polym J. 2012;44:973–7.

    Article  Google Scholar 

  5. Dakka SM. TG/DTA/MS of poly (Methyl methacrylate), the effect of particle size. J Therm Anal Calorim. 2003;74:729–34.

    Article  CAS  Google Scholar 

  6. Silva RMF, Medeiros FPM, Nascimento TG, Macêdo RO, Neto PJR. Thermal chracterization of indinavir sulfate suing TG, DSC and DSC-photovisual. J Therm Anal Calorim. 2009;95:965–8.

    Article  Google Scholar 

  7. Manich AM, Carilla J, Miguel RAL, Lucas JM, Franco FGF, Montero LA, Cayuela D. Thermal transitions of polylactide false-twist textured multifilaments determined by DSC and TMA. J Therm Anal Calorim. 2010;99:723–31.

    Article  CAS  Google Scholar 

  8. Wang MC, Wei LH, Zhao T. A novel condensation-addition-type phenolic resin (MPN): synthesis, characterization and evaluation as matrix of composites. Polymer. 2005;46:9202–10.

    Article  CAS  Google Scholar 

  9. Fu Y, Liu Y, Fu XP, Zou L, Li H, Li M, Chen XG, Qin JG. Synthesis of click-chelator via Cu(I)-catalyzed alkyne-azide cyloaddition. Chinese J Chem. 2010;28:2226–32.

    Article  CAS  Google Scholar 

  10. Zhu YQ, Chen HH, He CL. Novel polyelectrolytes containing perfluorocyclobutane and triazole units: synthesis, characterization and proerties. Polym J. 2011;43:258–64.

    Article  CAS  Google Scholar 

  11. Chen LJ, Shi HG, Wu HK. Preparation and characterization of a novel fluorinated acrylate resin. J Fluorine Chem. 2010;131:731–7.

    Article  CAS  Google Scholar 

  12. Dai Z, Li YF, Yang SG, Zhao N, Zhang XL, Xu J. Kinetics and thermal properties of epoxy resins basicd on bisphenol fluorene structure. Eur Polym J. 2009;45:1941–8.

    Article  CAS  Google Scholar 

  13. Li L, Zhang L, Wen Z, Chen DZ. Synthesis, characterization, and photophysical properties of materials obtained by co-inercalation of chromophores into layered double hydroxides. Chinese J Chem. 2010;28:171–8.

    Article  CAS  Google Scholar 

  14. Scott TF, Cook WD, Forsythe JS. Kinetics and network structure of thermally cured vinyl ester resins. Eur Polym J. 2002;38:705–16.

    Article  CAS  Google Scholar 

  15. Lopes PE, Hattum F, Pereira CMC, Nóvoa PJRO, Forero S, Hepp F. Pambaguian L. High CNT content composites with CNT buckypaer and epoxy resin matrix: Impregnation behavior compostie production and characterization Compos Struct. 2010;92:1291–8.

    Google Scholar 

  16. Feng XM, Wei Q, Chen SP, Gao SL. Synthesis, structural characterization and luminescence of lanthanide coordination polymers with pyridine-2,5-dicarobylci acid. Chinese J Chem. 2010;28:11–5.

    Article  CAS  Google Scholar 

  17. Dubois MA, Dozol JF, Nicotra C. Pyrolysis and incineration of cationic and anionic ion-exchange resins-Identification of volatile degradation compounds. J Anal App Pyrolysis. 1995;31:129–40.

    Article  CAS  Google Scholar 

  18. Chambree D, Idiţoiu C, Segal E, Cesàro A. The study of non-isothermal degradation of acrylic ion-exchange resins. J Therm Anal Calorim. 2005;82:803–11.

    Article  CAS  Google Scholar 

  19. Singare PU, Lokhande RS, Madyal RS. Thermal degradation studies of some strongly acidic cation exchange resins. Open J Phys Chem. 2011;1:45–54.

    Article  CAS  Google Scholar 

  20. Jiang BH, Xu JG, Zhang JJ, Wu XY, Liu ZZ. Study on application of weak-basic ion-exchange in citric acid recovery. Ion Exch Adsorpt. 1996;12:254–8.

    CAS  Google Scholar 

  21. Fan WC, Lu FZ. Study on application of speical anion exchange resin for citric acid. Shanghai Chem Ind. 1993;18:23–37.

    CAS  Google Scholar 

  22. Macan J, Brnardić I, Ivanković M, Mencer H. DSC study of cure kinetics of dgeba-basicd epoxy resin with poly (oxypropylene) diamine. J Therm Anal Calorim. 2005;81:369–73.

    Article  CAS  Google Scholar 

  23. Saraydin D, Karadag E, Şahiner N, Güven O. The influence of preparation methods on the swelling and network properites of acrylamide dydrogels with crosslinkers. J Macromol Sci Pure Appl Chem. 2004;41:419–31.

    Article  Google Scholar 

  24. Anderson HL, Schneider HA, Kemmler A, Strey R. The basic processes of depolymierization and its real kinetic and analysis. J Therm Anal Calorim. 2005;47:1063–8.

    Article  Google Scholar 

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Acknowledgements

This work was supported by the Fundamental Research Funds for the Central Universities (JUSRP11205).

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Authors and Affiliations

  1. The Key Laboratory of Food Colloids and Biotechnology Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, China

    Junwei Zhang & Hao Qian

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  1. Junwei Zhang
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  2. Hao Qian
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Correspondence to Junwei Zhang.

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Zhang, J., Qian, H. Thermal behavior of typical weak basic ion exchange resin. J Therm Anal Calorim 115, 875–880 (2014). https://doi.org/10.1007/s10973-013-3347-1

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  • DOI: https://doi.org/10.1007/s10973-013-3347-1

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