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Thermal degradation of honeys and evaluation of physicochemical properties

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Abstract

The physicochemical characterization and thermal profile of honeys produced by stingless bees are poorly known, mainly due to the high diversity of flora mellifera and to the low production that is inherent of these species. The objective of this study was to determine the physicochemical characteristics of five samples of honey from bees from the species Melipona seminigra merrillae of Amazonas State, Brazil. The thermal degradation profile of these honey samples was evaluated by thermogravimetry in order to contribute with the establishment of a quality standard of honeys produced from Brazilian stingless bees. Thus, the following analyses were performed: reducing sugars, moisture, hydroxymethylfurfural, protein, ash, pH, and acidity. The results showed that the current legislation concerning the honey of Apis mellifera is not an appropriate standard for all the properties analyzed, reinforcing the need for a honey standard including the honeys of all Brazilian bees. The honey samples displayed similar thermal degradation profiles, with the thermal process starting at room temperature and ending at a temperature next to 600 °C.

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References

  1. Specifications from Normative Instruction number 11 of October 20, 2000. Brazil. Ministry of Agriculture, Livestock and Food Supply; Normative Instruction number 11 of October 20, 2000, Diário Oficial da União, October 23, 2000.

  2. AL-Mamary M, Al-Meeri A, Al-Habori M. Antioxidant activities and total phenolics of different types of honey. Nutr Res. 2002;22:1041–47.

    Google Scholar 

  3. Küçük M, Kolaili S, Karaoğlu S, Ulusoy E, Baltaci C, Candan F. Biological activities and chemical composition of three honeys of different types from Anatolia. Food Chem. 2007;100:526–34.

    Article  Google Scholar 

  4. Arráez-Román D, Gómez-Caravaca AM, Gómez-Romero M, Segura-Carratero A, Fernández-Gutiérrez A. Identification of phenolic compounds in rosemary honey using solid-phase extraction by capillary electrophoresis–electrospray ionization-mass spectrometry. J Pharm Biom Anal. 2006;41:1648–56.

    Article  Google Scholar 

  5. Baltrušaityté V, Venskutonis PR, Čeksteryté V. Radical scavenging activity of different floral origin honey and bee bread phenolic extracts. Food Chem. 2007;10:502–14.

    Article  Google Scholar 

  6. Acquarone C, Buera P, Elizalde B. Pattern of pH and electrical conductivity upon honey dilution as a complementary tool for discriminating geographical origin of honeys. Food Chem. 2007;101:03–695.

    Article  Google Scholar 

  7. Azeredo LC, Azeredo MAA, Souza ASR, Dutra VML. Protein contents and physicochemical properties in honey samples of Apis mellifera of different floral origins. Food Chem. 2003;80:249–54.

    Article  CAS  Google Scholar 

  8. Vit P, Medina M, Enriquez ME. Quality standards for medicinal uses of Meliponinae honey in Guatemala, Mexico and Venezuela. Bee World. 2004;85:2–5.

    Google Scholar 

  9. Marques-Souza AC, Absy ML, Kerr WE, Peralta FJA. Pollen collected by two Meliponini species (Hymenoptera, Apidae) from Amazonas State, Brazil. Rev Bras Biol. 1995;55:855–64.

    Google Scholar 

  10. Association of Official Analytical Chemists (AOAC). Official methods of analysis, supl. 2. 15th ed. Washington, DC: AOAC; 1990.

  11. Anaceleto DA, Souza BA, Marchini LC, Moreti ACCC. Composition of the honey of samples originated from Jataí bees (Tetragonisca angustula latreille, 1811). Cienc Tecnol Aliment. 2009;29:535–41.

    Article  Google Scholar 

  12. Souza RCS, Yuyama LKO, Aguiar JPL. Nutritional value of honey and pollen of stingerless bees of the Amazonian region. Acta Amaz. 2004;34:333–6.

    Article  Google Scholar 

  13. Souza BA, Marchini LC, Oda-Souza M, Carvalho CAL, Alves RGO. Characterization of honey produced by species of Melipona Illiger, 1806 (Apidae: Meliponini) from the northeast area of Brazil: 1. Physico-chemical characteristics. Quim Nova. 2009;32:303–8.

    Article  CAS  Google Scholar 

  14. Alves RMO, Carvalho CAL, Souza BA, Sodré GS, Marchini LC. Physico-chemical characteristics of honey samples of stingless bee Melipona mandacaia Smith (Hymenoptera: Apidae). Cienc Tecnol Aliment. 2005;25:644–50.

    Article  CAS  Google Scholar 

  15. Codex Alimentarius Commission. Codex standards for sugars (honey). FAO: Rome; 1989.

    Google Scholar 

  16. White JW, Subers MH, Schepartz I. The identification of inhibine the antibacterial factor in honey, as hydrogen peroxide and its origin in a honey glucose–oxidase system. Am Bee J. 1963;73:430–1.

    Google Scholar 

  17. Terrab A, Recamales AF, Hernanz D, Heredia FJ. Characterisation of Spanish thyme honeys by their physicochemical characteristics and mineral contents. Food Chem. 2004;88:537–42.

    Article  CAS  Google Scholar 

  18. Finola MS, Lasangno MC, Marioli JM. Microbiological and chemical characterization of honeys from central Argentina. Food Chem. 2007;100:1649–53.

    Article  CAS  Google Scholar 

  19. De Rodríguez GO, Ferrer BS, Ferrer A, Rodríguez B. Characterization of honey produced in Venezuela. Food Chem. 2004;84:499–502.

    Article  Google Scholar 

  20. Cortopassi-Laurino M, Gelli DS. Analyse pollinique, propriétés physico-chimiques et action antibactérienne des miels d’abeilles africanisées Apis mellifera et de Méliponinés du Brésil. Apidologie. 1991;22:61–73.

    Article  Google Scholar 

  21. Anklam E. A review of the analytical methods to determine the geographical and botanical origin of honey. Food Chem. 1998;63:549–62.

    Article  CAS  Google Scholar 

  22. Cordella C, Faucon JP, Cabrol-Bass D, Sbirrazzuoli N. Application of DSC as a tool for honey floral species characterization and adulteration detection. J Therm Anal Calorm. 2003;71:279–90.

    Article  CAS  Google Scholar 

  23. Schäffer B, Keller B, Szakály Z, Lőrinczy D. Examination of a coffee product enriched with calcium by the isoperibolic method. J Therm Anal Calorim. 2012;108:171–5.

    Article  Google Scholar 

  24. Tomassetti M, Campanella L, Aureli T. Thermogravimetric analysis of some spices and commercial food products: comparison with other analytical methods for moisture content determination. Thermochim Acta. 1989;143:15–23.

    Article  CAS  Google Scholar 

  25. Macêdo RO, Moura OM, Souza AG, Macêdo AMC. Comparative studies on some analytical methods: thermal decomposition of powder milk. J Therm Anal Calorim. 1997;49:857–62.

    Article  Google Scholar 

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Acknowledgments

The authors acknowledge the Brazilian agencies FAPEAM—Fundação de Amparo à Pesquisa do Estado do Amazonas, MCT, and FINEP for the financial support.

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Correspondence to I. A. A. Silva.

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Silva, I.A.A., Souza, A.L., Cordeiro, A.M.T.M. et al. Thermal degradation of honeys and evaluation of physicochemical properties. J Therm Anal Calorim 114, 353–358 (2013). https://doi.org/10.1007/s10973-012-2926-x

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  • DOI: https://doi.org/10.1007/s10973-012-2926-x

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