Skip to main content
Log in

Standard thermochemical characteristics of formation of triphenylantimony bis(acetophenoneoximate)

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

For the first time, the energy of combustion Δc U of crystalline triphenylantimony bis(acetophenoneoximate) Ph3Sb(ONCPhMe)2 has been measured at T = 298.15 K using the isothermal combustion calorimeter with a stationary bomb. The standard molar enthalpy of combustion Δc Hº, the standard molar enthalpy Δf Hº, and free Gibbs energy Δf Gº of formation of the above oximate have been calculated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. Smirnova NN, Letyanina IA, Larina VN, Markin AV, Sharutin VV, Senchurin VS. Thermodynamic properties of pentaphenylantimony Ph5Sb over the range from T → 0 K to 400 K. J Chem Thermodyn. 2009;41:46–50.

    Article  CAS  Google Scholar 

  2. Smirnova NN, Letyanina IA, Markin AV, Larina VN, Sharutin VV, Molokova OV. Thermodynamic properties of tetraphenylantimony benzophenoximate in the region of 0–450 K. Rus J Gen Chem. 2009;79:717–23.

    Article  CAS  Google Scholar 

  3. Letyanina IA, Smirnova NN, Markin AV, Ruchenin VA, Larina VN, Sharutin VV, Molokova OV. Thermodynamics of tetraphenylantimony acetophenoneoximate. J Therm Anal Calorim. 2011;103:355–63.

    Article  CAS  Google Scholar 

  4. Letyanina IA, Markin AV, Smirova NN, Gushchin AV, Shashkin DV. Thermodynamic characteristics of triphenylantimony diacrylate. Rus J Phys Chem. 2012;86:1189–95.

    Article  CAS  Google Scholar 

  5. Markin AV, Letyanina IA, Ruchenin VA, Smirnova NN, Gushchin AV, Shashkin DV. Heat capacity and standard thermodynamic functions of triphenylantimony dimethacrylate over the temperature range from (0 to 400) K. J Chem Eng Data. 2011;56:3657–62.

    Article  CAS  Google Scholar 

  6. Markin AV, Letyanina IA, Smirnova NN, Sharutin VV, Molokova OV. Thermodynamic characteristics of triphenylantimony bis(acetophenoneoximate). Rus J Phys Chem. 2011;85:1315–21.

    Article  CAS  Google Scholar 

  7. Gupta A, Sharma RK, Bohra R, Jain VK, Drake JE, Hursthouse MB, Light ME. Synthetic, spectroscopic and structural aspects of triphenylantimony(V) complexes with internally functionalized oximes: crystal and molecular structure of [Ph3Sb{ON = C(Me)C5H4N-2}2]. Polyhedron. 2002;21:2387–92.

    Article  CAS  Google Scholar 

  8. Dodonov VA, Gushchin AV, Gor’kaev DA, Fukin GK, Starostina TI, Zakharov LN, Kurskii YuA, Shavyrin AS. Synthesis and structures of triphenylantimony oximates. Rus Chem Bull. 2002;51:1051–7.

    Article  CAS  Google Scholar 

  9. Sharutin VV, Sharutina OK, Molokova OV, Pakusina AP, Gerasimenko AV, Sergienko AS, Bukvetskii BV, Popov DYu. Synthesis and structures of tetra- and triarylantimony oximates. Rus J Coord Chem. 2002;28:544–55.

    Article  CAS  Google Scholar 

  10. Rabinovich IB, Nistratov VP, Telnoy VI, Sheiman MS. Thermochemical and thermodynamic properties of organometallic compounds. New York: Begell House Inc. Publishers; 1999.

    Google Scholar 

  11. Sharutin VV, Sharutina OK, Molokova OV, Pakusina AP, Gerasimenko AV, Gerasimenko EA. Synthesis and structure of triphenylantimony bis(acetophenoneoximate). Rus J Coord Chem. 2002;28:464–7.

    Article  CAS  Google Scholar 

  12. Kir’yanov KV, Telnoy VI. Using the calorimeter B-08 for precision measuring of a combustion heat. Tr po Him i Him Tehnol. 1975;4:109–10.

    Google Scholar 

  13. Telnoy VI, Kir’yanov KV, Ermolaev VI, Rabinovich IB. Thermochemistry of dicyclopentadienil compounds of transition elements of the 3-d row in the periodic system. Dokl Akad Nauk SSSR. 1975;220:1088–91.

    Google Scholar 

  14. Simon A, Thaler E. Beiträge zur Kenntnis von Oxyden. Zur Kenntnis der Oxyde des Antimons. Zeitschrift für anorganische und allgemeine. Chemie. 1927;162:253–78.

    CAS  Google Scholar 

  15. Zotov AV, Shikina ND, Akinfiev NN. Thermodynamic properties of the Sb(III) hydroxide complex Sb(OH)3(aq) at hydrothermal conditions. G. Geochim Cosmochim Acta. 2003;67:1821–36.

    Article  CAS  Google Scholar 

  16. Washburh EW. Standard states for bomb calorimeter. J Res Natl Bur Standards. 1933;10:525–58.

    Google Scholar 

  17. Cox JD, Wagman DD, Medvedev VA. Codata key values for thermodynamics. New York; 1984 (database http://webbook.nist.gov/chemistry/).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. V. Markin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Markin, A.V., Letyanina, I.A., Smirnova, N.N. et al. Standard thermochemical characteristics of formation of triphenylantimony bis(acetophenoneoximate). J Therm Anal Calorim 111, 1499–1502 (2013). https://doi.org/10.1007/s10973-012-2479-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-012-2479-z

Keywords

Navigation