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Thermal and spectroscopic studies of sodium and light lanthanide (III) complexes with 2,4-pyridinedicarboxylate anion

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Abstract

Pyridine-2,4-dicarboxylic acid (lutidinic acid) is next one after pyridine-2,5-dicarboxylic acid of the six isomers which lanthanide complexes were studied thermally and spectrally. New complexes synthesized with light lanthanides (III) with general formula Ln2L3·nH2O, where n = 7.5; 8; 8.5; 9, were obtained. Sodium salt was obtained as hexahydrated compound. Hydrated complexes of La(III), Ce(III), Pr(III), Nd(III), Sm(III), Eu(III), and Gd(III) are thermally stable up to 303–313 K. Dehydration process run for all compounds in one stage, anhydrous compounds decompose through appropriate light lanthanides (III) oxalates, oxocarbonates, carbonates to metal oxides. Theoretical IR and Raman studies were carried out in order to identify precisely characteristic group bands vibrations present on IR and Raman spectra.

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Authors and Affiliations

  1. Department of General and Coordination Chemistry, Maria Curie-Skłodowska University, M. C. Skłodowskiej SQ 2, 20-031, Lublin, Poland

    Zofia Rzączyńska & Anna Danczowska-Burdon

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  1. Zofia Rzączyńska
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  2. Anna Danczowska-Burdon
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Correspondence to Zofia Rzączyńska.

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Rzączyńska, Z., Danczowska-Burdon, A. Thermal and spectroscopic studies of sodium and light lanthanide (III) complexes with 2,4-pyridinedicarboxylate anion. J Therm Anal Calorim 108, 991–999 (2012). https://doi.org/10.1007/s10973-011-1986-7

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