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Physico-chemical investigation on mixed-ligand manganese (II) and iron (II) complexes of 4-methylpiperazine-1-carbodithioate ligand and 1,10-phenanthroline or 2,2′-bipyridyl

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Abstract

Some new mixed-ligand complexes of 4-methylpiperazine-1-carbodithioate (4-MPipzcdt) of the general formula [M(4-MPipzcdtA) a (L) b ]X (L = 1,10-phenanthroline (phen) or 2,2′-bipyridyl (bipy); A = H, a = 2, b = 1 where M = Mn(II), X = Cl2, and M = Fe(II), X = SO4; A = nil where X = Cl when M = Mn(II), a = 1, b = 2 and X = nil when M = Mn(II), Fe(II), a = 2, b = 1) have been prepared and characterized by elemental analyses, molar conductance, infrared and electronic absorption and variable temperature Mössbauer spectral and room temperature as well as variable temperature magnetic susceptibility measurements. Manganese(II) complexes have high spin cis-distorted octahedral structures and all the iron(II) mixed-ligand complexes exhibit spin free–spin paired (5T2g ⇌ 1A1g) equilibrium in distorted octahedral structure.

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Authors and Affiliations

  1. Department of Chemistry, Himachal Pradesh University, Shimla, 171005, India

    Shashi B. Kalia,  Rojila & Dharvinder Kumar

  2. Department of Chemistry, Lyallpur Khalsa College, Jalandhar, 144001, India

    Geetanjli Kaushal

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  1. Shashi B. Kalia
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Correspondence to Shashi B. Kalia.

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Kalia, S.B., Kaushal, G., Rojila et al. Physico-chemical investigation on mixed-ligand manganese (II) and iron (II) complexes of 4-methylpiperazine-1-carbodithioate ligand and 1,10-phenanthroline or 2,2′-bipyridyl. J Therm Anal Calorim 109, 1463–1471 (2012). https://doi.org/10.1007/s10973-011-1925-7

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