Skip to main content
Log in

The potential of ferric pyrophosphate for influencing the thermal degradation of cotton fabrics

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Ferric pyrophosphate (FePP) was used as additive to study its synergistic effect of thermal degradation on cotton fabrics. The microscale combustion calorimetry (MCC), thermogravimetric analysis (TG), Raman spectroscopy and Real Time Fourier transform infrared spectroscopy (RT-FTIR) were utilized to evaluate the synergistic effects of FePP on cotton/DIA. The MCC results revealed that cotton/DIA/FePP generated less combustion heat during heating than that of cotton/DIA. TG results showed that presence of FePP improved the thermal stability of materials. The Raman spectroscopy test showed that FePP can ameliorate the structural organization level of the carbon and the graphitization degree of the char. RT-FTIR data revealed the mechanism of the influence of FePP, which can catalyze the break of the flame retardant as well as promote the char forming.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Nie SB, Song L, Zhan J, Hu Y, Tai QL, Chen LJ. Synergistic effect of novel synergists-transition metal ion-incorporated nickel phosphates with intumescent flame retardants in polypropylene. J Macromol Sci A. 2009;46:554–9.

    Article  CAS  Google Scholar 

  2. Zhang P, Song L, Lu HD, Hu Y, Xing WY, Ni JX, Wang J. Synergistic effect of nanoflaky manganese phosphate on thermal degradation and flame retardant properties of intumescent flame retardant polypropylene system. Polym Degrad Stab. 2009;94:201–7.

    Article  CAS  Google Scholar 

  3. Davies PJ, Horrocks AR, Alderson A. The sensitisation of thermal decomposition of ammonium polyphosphate by selected metal ions and their potential for improved cotton fabric flame retardancy. Polym Degrad Stab. 2005;88:114–22.

    Article  CAS  Google Scholar 

  4. Hu S, Hu Y, Song L, Lu HD. Effect of modified organic–inorganic hybrid materials on thermal properties of cotton fabrics. J Therm Anal Calorim. doi:10.1007/s10973-010-1093-1.

  5. Mahltig B, Textor T. Combination of silica sol and dyes on textiles. J Sol-Gel Sci Technol. 2006;39:111–8.

    Article  CAS  Google Scholar 

  6. Ebdon JR, Guisti L, Hunt BJ, Jones MS. The effects of some transition-metal compounds on the flame retardance of poly(styrene-co-4-vinyl pyridine) and poly(methyl methacrylate-co-4-vinyl pyridine). Polym Degrad Stab. 1998;60:401–7.

    Article  CAS  Google Scholar 

  7. Hanna AA, Basta AH, El-Saied H, Abadir IF. Thermal properties of cellulose acetate and its complexes with some transition metals. Angew Makromol Chem. 1998;260:1–4.

    Article  CAS  Google Scholar 

  8. Tamor MA, Vassell WC. Raman fingerprinting of amorphous-carbon films. J Appl Phys. 1994;76:3823–30.

    Article  CAS  Google Scholar 

  9. Lespade P, Al-Jishi R, Dresselhaus MS. Model for Raman scattering from incompletely graphitized carbons. Carbon. 1982;20:427–31.

    Article  CAS  Google Scholar 

  10. Tuinstra F, Koenig JL. Raman spectrum of graphite. J Chem Phys. 1970;53:1126–30.

    Article  CAS  Google Scholar 

  11. Bourbigot S, Le Bras M, Delobel R, Tremillon JM. Synergistic effect of zeolite in an intumescence process. Study of the interactions between the polymer and the additives. J Chem Soc Faraday Trans. 1996;92:3435–44.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The work was financially supported by the Program for Specialized Research Fund for the Doctoral Program of Higher Education (200803580008) and the Program for Science and Technology of Su Zhou (SG-0841).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yuan Hu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hu, S., Hu, Y., Song, L. et al. The potential of ferric pyrophosphate for influencing the thermal degradation of cotton fabrics. J Therm Anal Calorim 109, 27–32 (2012). https://doi.org/10.1007/s10973-011-1732-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-011-1732-1

Keywords

Navigation