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Chemical and phase transformation in the V2O5–(NH4)2Mo2O7 system during the mechanochemical treatment in various media

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Abstract

Mechanochemical treatment (MChT) in various media (water, air, ethanol) of the V2O5/ammonium dimolybdate composition at the ratio V:Mo = 0.7:0.3 has been carried out. Physicochemical transformations in this system have been studied by means of X-ray powder diffraction (XRD) and thermal analysis as well as FTIR spectroscopy. Ammonium dimolybdate undergoes hydration with formation of 4-aqueous ammonium paramolybdate during the MChT in water. Changes of phase and chemical composition at activation are determined first of all by nature of medium in which milling was carried out. Maximal interaction of components occurs during modification of the studied system in water.

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Acknowledgements

This study was partially supported by International Visegrad Fund (Contract No 50810086).

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Authors and Affiliations

  1. Institute for Sorption and Problems of Endoecology, National Academy of Sciences of Ukraine, Naumova Str., 13, Kyiv, 03164, Ukraine

    S. V. Khalameida & V. A. Zazhigalov

  2. Maria Curie-Skłodowska University, M. Curie-Skłodowskej Sq. 3, 20-031, Lublin, Poland

    J. Skubiszewska-Zięba & R. Leboda

  3. Faculty of Engineering Chemistry and Technology, Cracow University of Technology, Warszawska 24, 31-155, Cracow, Poland

    K. Wieczorek-Ciurowa

Authors
  1. S. V. Khalameida
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  2. J. Skubiszewska-Zięba
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  3. V. A. Zazhigalov
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  5. K. Wieczorek-Ciurowa
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Correspondence to J. Skubiszewska-Zięba.

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Khalameida, S.V., Skubiszewska-Zięba, J., Zazhigalov, V.A. et al. Chemical and phase transformation in the V2O5–(NH4)2Mo2O7 system during the mechanochemical treatment in various media. J Therm Anal Calorim 101, 823–832 (2010). https://doi.org/10.1007/s10973-010-0839-0

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  • DOI: https://doi.org/10.1007/s10973-010-0839-0

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