Thermodynamic investigation of room temperature ionic liquid

Abstract

The molar heat capacities of the room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluoroborate (BMIPF₆) were measured by an adiabatic calorimeter in temperature range from 80 to 390 K. The dependence of the molar heat capacity on temperature is given as a function of the reduced temperature (X) by polynomial equations, C _P,m (J K⁻¹ mol⁻¹) = 204.75 + 81.421X − 23.828 X ² + 12.044X ³ + 2.5442X ⁴ [X = (T − 132.5)/52.5] for the solid phase (80–185 K), C _P,m (J K⁻¹ mol⁻¹) = 368.99 + 2.4199X + 1.0027X ² + 0.43395X ³ [X = (T − 230)/35] for the glass state (195 − 265 K), and C _P,m (J K⁻¹ mol⁻¹) = 415.01 + 21.992X − 0.24656X ² + 0.57770X ³ [X = (T − 337.5)/52.5] for the liquid phase (285–390 K), respectively. According to the polynomial equations and thermodynamic relationship, the values of thermodynamic function of the BMIPF₆ relative to 298.15 K were calculated in temperature range from 80 to 390 K with an interval of 5 K. The glass transition of BMIPF₆ was measured to be 190.41 K, the enthalpy and entropy of the glass transition were determined to be ΔH _g = 2.853 kJ mol⁻¹ and ΔS _g = 14.98 J K⁻¹ mol⁻¹, respectively. The results showed that the milting point of the BMIPF₆ is 281.83 K, the enthalpy and entropy of phase transition were calculated to be ΔH _m = 20.67 kJ mol⁻¹ and ΔS _m = 73.34 J K⁻¹ mol⁻¹.