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Synthesis, thermal degradation, and kinetic parameters studies of some coordination polymers

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Abstract

This article describes synthesis and route of thermal degradation and studies of kinetic parameters of some coordination polymers of first transition series metal ions viz. Mn(II), Co(II), Ni(II), Cu(II), and Zn(II). The newly synthesized ligand and its coordination polymers have been characterized by various instrumental techniques. The thermal degradation studies have been studied at different heating rates to determine the apparent activation energy, order of reaction, entropy change, free energy change, apparent entropy change, and frequency factor using Sharp–Wentworth and Freeman–Carroll methods. Thermo gravimetric analysis (TGA) has been used to determine the thermal stability of coordination polymers. The decomposition temperatures of the polymers were defined by half decomposition curve technique.

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References

  1. Issa RM, Amer SA, Mansour IA, Abdel-Monsef AI. Thermal studies of bis salicylidene adipic dihydrazone derivatives and their complexes with divalent ions of Mn, Co, Ni, Cu and Zn. J Therm Anal Calorim. 2007;90:261–7.

    Article  CAS  Google Scholar 

  2. Lu JY. Crystal of Cu-containing metal-organic coordination polymers under hydrothermal conditions. Coord Chem Rev. 2003;246:345–65.

    Article  Google Scholar 

  3. Shrivastava SA, Ukey VV, Juneja HD. Thermal analysis of some coordination polymers of adipyl bis hydrazide and succinyl bis phenyl hydrazide with transition with metal ions. Indian J. 2005;1(12):759–62.

    CAS  Google Scholar 

  4. Moulton B, Zaworotka MJ. Molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids. Chem Rev. 2001;101:1629–58.

    Article  CAS  Google Scholar 

  5. Fieden J, Sprott J, Long De-Liang, Kogerler P, Cronnin L. Controlling aggregation of Cu(II) based coordination compounds: from mononuclear to dinuclear, tetranuclear and polymeric copper complexes. Am Chem Soc Inorg Chem. 2006;45(7):2886–95.

    Article  Google Scholar 

  6. Silversteen RM, Webster FX. Spectrometric identification of organic compounds. 6th ed. New York: Wiley; 1997. p. XiV+482. (pp. 97, 98, 125).

    Google Scholar 

  7. Silversteen RM, Webster FX. Spectrometric identification of organic compounds. 6th ed. New York: Wiley; 1997. p. XiV+482. (pp. 97, 117).

    Google Scholar 

  8. Silversteen RM, Webster FX. Spectrometric identification of organic compounds. 6th ed. New York: Wiley; 1997. p. XiV+482. (pp. 97, 128).

    Google Scholar 

  9. Borkar SD, Ukey VV, Juneja HD. Synthesis, spectral and thermogravimetric analysis of some coordination polymers of sebacoyl bis p-tolyl carbamide. Indian J. 2005;1(12):754–8.

    CAS  Google Scholar 

  10. Silversteen RM, Webster FX. Spectrometric identification of organic compounds. 6th ed. New York: Wiley; 1997. p. XiV+482. (pp. 97, 98, 113).

    Google Scholar 

  11. Rai HC, Kumar A, Kumari A. Synthesis of macrocyclic ligand, ph4-[14]-tetrazene-N4 and its metal complexes with chromium, iron, cobalt and nickel (II). Am J Chem. 2000;12:1189–92.

    CAS  Google Scholar 

  12. Chaudhary CK, Chaudhary Ratan, Mishra LK. Complexes of manganese (III) and cobalt (III) with some salicylidene-4, 4-disubstituted-3-thiosemicarbazides. J Indian Chem Soc. 2003;80:693–5.

    Google Scholar 

  13. Roy SM, Juneja HD, Munshi KN. Synthesis and structural features of some first row transition series metal bis (biuret) polymeric chelates. Synth React Inorg Met-Org Chem. 2001;31(9):1611–21.

    Article  CAS  Google Scholar 

  14. Konstautinovic SS, Radovanovic BC, Krkljes A. Thermal behaviour of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) complexes with isatin-β-thiosemicarbazone. J Therm Anal Calorim. 2007;90:525–31.

    Article  Google Scholar 

  15. Chandra S, Gautam A, Tyagi M. Synthesis and spectroscopic characterization of transition metal complexes of a 12-membered tetra-aza [N4] macrocyclic ligand and their biological activity. Trans Met Chem. 2007;32:1079–84.

    Article  CAS  Google Scholar 

  16. Singh BK, Mishra P, Garg BS. Nickel (II) complexes of new polydentate carboxamides, spectroscopic, kinetics of thermal decomposition and X-ray powder diffraction studies. Trans Met Chem. 2007;32:603–14.

    Article  CAS  Google Scholar 

  17. Bansod AD, Aswar AS. Coordination chain polymers of transition metals with salen type Schiff base and their oxidation catalysis. J Saudi Chem Soc. 2007;11:243–52.

    CAS  Google Scholar 

  18. Freeman ES, Carroll B. The application of thermoanalytical techniques to reaction kinetics, the thermogravimetric evaluation of the kinetics of the decomposition of calcium oxalate monohydrate. J Phys Chem. 1958;62:394–7.

    Article  CAS  Google Scholar 

  19. Sharp JH, Wentworth SA. Kinetic analysis of thermogravimetric data. Anal Chem. 1969;41:2060–2.

    Article  CAS  Google Scholar 

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Acknowledgements

Authors are thankful to the Head of the Department of Chemistry; Rashtrasant Tukadoji Maharaj Nagpur University, Nagpur, for providing the laboratory facilities to carry out this study.

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Authors and Affiliations

  1. Department of Chemistry, Tulsiramji Gaikwad-Patil College of Engineering and Technology, Nagpur, India

    Geeta S. Padole Gaikwad

  2. Department of Chemistry, Rashtrasant Tukadoji Maharaj Nagpur University, Nagpur, 440033, India

    H. D. Juneja

Authors
  1. Geeta S. Padole Gaikwad
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  2. H. D. Juneja
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Correspondence to Geeta S. Padole Gaikwad.

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Padole Gaikwad, G.S., Juneja, H.D. Synthesis, thermal degradation, and kinetic parameters studies of some coordination polymers. J Therm Anal Calorim 100, 645–650 (2010). https://doi.org/10.1007/s10973-009-0510-9

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  • DOI: https://doi.org/10.1007/s10973-009-0510-9

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