Skip to main content
Log in

Application of Brazilian sawdust samples for chromium removal from tannery wastewater

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Brazilian sawdust samples (Caryocar spp.; Manilkara spp.; and Tabebuia spp.) have been used for Cr(VI) adsorption from water. The series of adsorption isotherms were adjusted to modified Langmuir equation. Thermodynamic data of interactions were studied by the calorimetric titration of Cr(VI) in aqueous solution. All liquid/solid interface adsorptions were entalpically and entropically driven. These sawdust samples were also used to remove chromium from tannery wastewater. The application of Caryocar spp.; Manilkara spp.; and Tabebuia spp. reduced the amount of chromium from 2.11 ± 0.18 mg L−1 to 1.15 ± 0.10; 0.29 ± 0.02 and 0.26 ± 0.02 mg L−1, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Prado AGS. Green chemistry, the chemical challenges of the new millenium. Quim Nova. 2003;26:738–44.

    CAS  Google Scholar 

  2. Evangelista SM, Deoliveira E, Castro GR, Zara LF, Prado AGS. Hexagonal mesoporous silica modified with 2-mercaptothiazoline for removing mercury from water solution. Surf Sci. 2007;601:2194–202.

    Article  CAS  Google Scholar 

  3. Prado AGS, Miranda BS, Jacintho GVM. Interaction of indigo carmine dye with silica modified with humic acids at solid/liquid interface. Surf Sci. 2003;542:276–82.

    Article  CAS  Google Scholar 

  4. Prado AGS, Faria EA, Souzade JR, Torres JD. Ammonium complex of niobium as a precursor for the hydrothermal preparation of cellulose acetate/Nb2O5 photocatalyst. J Mol Catal A. 2005;237:115–9.

    Article  CAS  Google Scholar 

  5. Prado AGS, Miranda BS, Zara LE. Adsorption and thermochemical data of divalent cations onto silica gel surface modified with humic acid at solid/liquid interface. J Hazard Mater. 2005;120:243–7.

    Article  CAS  Google Scholar 

  6. Roldan PS, Alcantara IL, Castro GR, Rocha JC, Padilha CCF, Padilha PM. Determination of Cu, Ni, and Zn in fuel ethanol by FAAS after enrichment in column packed with 2-aminothiazole-modified silica gel. Anal Bioanal Chem. 2003;375:574–7.

    CAS  Google Scholar 

  7. Roldan PS, Alcântara IL, Padilha CCF, Padilha PM. Determination of copper, iron, nickel and zinc in gasoline by FAAS after sorption and preconcentration on silica modified with 2-aminotiazole groups. Fuel. 2005;84:305–9.

    Article  CAS  Google Scholar 

  8. Alvarez P, Blanco C, Granda M. The adsorption of chromium (VI) from industrial wastewater by acid and base-activated lignocellulosic residues. J Hazard Mater. 2007;144:400–5.

    Article  CAS  Google Scholar 

  9. Tiravanti G, Petruzzelli D, Passino R. Pretreatment of tannery wastewaters by an ion exchange process for Cr(III) removal and recovery. Water Sci Technol. 1997;36:197–207.

    CAS  Google Scholar 

  10. Torres JD, Faria EA, Prado AGS. Thermodynamic studies of the interaction at the solid/liquid interface between metal ions and cellulose modified with ethylenediamine. J Hazard Mater. 2006;129:239–43.

    Article  CAS  Google Scholar 

  11. Yu B, Zhang Y, Shukla A, Shukla SS, Dorris KL. The removal of heavy metal from aqueous solutions by sawdust adsorption—removal of copper. J Hazard Mater. 2000;80:33–42.

    Article  CAS  Google Scholar 

  12. Babel S, Kurniawan TA. Low-cost adsorbents for heavy metals uptake from contaminated water: a review. J Hazard Mater. 2003;97:219–43.

    Article  CAS  Google Scholar 

  13. Deydier E, Guilet R, Sharrock P. Beneficial use of meat and bone meal combustion residue: “an efficient low cost material to remove lead from aqueous effluent”. J Hazard Mater. 2003;101:55–64.

    Article  CAS  Google Scholar 

  14. Sen Gupta S, Bhattacharyya KG. Immobilization of Pb(II), Cd(II) and Ni(II) ions on kaolinite and montmorillonite surfaces from aqueous medium. J Environ Manag. 2008;87:46–58.

    Article  Google Scholar 

  15. El-Hamouz A, Hilal HS, Nassar N, Mardawi Z. Solid olive waste in environmental cleanup: oil recovery and carbon production for water purification. J Environ Manag. 2007;84:83–92.

    Article  CAS  Google Scholar 

  16. Tarley CRT, Arruda MAZ. Biosorption of heavy metals using rice milling by-products. Characterisation and application for removal of metals from aqueous effluents. Chemosphere. 2004;54:987–95.

    Article  Google Scholar 

  17. Ansari R, Fahim NK. Application of polypyrrole coated on wood sawdust for removal of Cr(VI) ion from aqueous solutions. React Func Polym. 2007;67:367–74.

    Article  CAS  Google Scholar 

  18. Karthikeyan T, Rajgopal S, Miranda LR. Chromium(VI) adsorption from aqueous solution by Hevea Brasilinesis sawdust activated carbon. J Hazard Mater. 2005;124:192–9.

    Article  CAS  Google Scholar 

  19. Djeribi R, Hamdaoui O. Sorption of copper(II) from aqueous solutions by cedar sawdust and crushed brick. Desalination. 2008;225:95–112.

    Article  CAS  Google Scholar 

  20. Larous S, Meniai AH, Lehocine MB. Experimental study of the removal of copper from aqueous solutions by adsorption using sawdust. Desalination. 2005;185:483–90.

    Article  CAS  Google Scholar 

  21. Deepa KK, Sathishkumar M, Binupriya AR, Murugesan GS, Swaminathan K, Yun SE. Sorption of Cr(VI) from dilute solutions and wastewater by live and pretreated biomass of Aspergillus flavus. Chemosphere. 2006;62:833–40.

    Article  CAS  Google Scholar 

  22. Garg UK, Kaur MP, Garg VK, Sud D. Removal of hexavalent chromium from aqueous solution by agricultural waste biomass. J Hazard Mater. 2007;140:60–8.

    Article  CAS  Google Scholar 

  23. Pandey AK, Pandey SD, Misra V, Srimal AK. Removal of chromium and reduction of toxicity to Microtox system from tannery effluent by the use of calcium alginate beads containing humic acid. Chemosphere. 2003;51:329–33.

    Article  CAS  Google Scholar 

  24. Hu J, Lo IMC, Chen G. Fast removal and recovery of Cr(VI) using surface-modified jacobsite (MnFe2O4) nanoparticles. Langmuir. 2005;21:11173–9.

    Article  CAS  Google Scholar 

  25. American Society for Testing Materials—ASTM D4749-87(1994)e1. Standard test method for performing the sieve analysis of coal and designating coal size. West Conshohocken, Pennsylvania, 1994.

  26. prado AGS, torres JD, Faria EA, Dias SCL. Comparative adsorption studies of indigo carmine dye on chitin and chitosan. J Colloid Interface Sci. 2004;277:43–7.

    Article  CAS  Google Scholar 

  27. Prado AGS, Deoliviera E. The interaction at the solid/liquid interface of 2, 4-dichlorophenoxyacetic acid with silica modified by reaction with ammonia gas. J Colloid Interface Sci. 2005;291:53–8.

    Article  CAS  Google Scholar 

  28. Cestari AR, Vieira EFS, Mattos CRS. Thermodynamics of the Cu(II) adsorption on thin vanillin-modified chitosan membranes. J Chem Thermodyn. 2006;38:1092–9.

    Article  CAS  Google Scholar 

  29. Vieira EFS, Cestari AR, Santos EB, Rezende CX. Measurement of cation binding to immobilized vanillin by isothermal calorimetry. J Colloid Interface Sci. 2006;298:74–8.

    Article  CAS  Google Scholar 

  30. Okuno Y, Yokoyama T, Yokoyama S, Kamikado S, Mashiko S. Theoretical study of benzonitrile clusters in the gas phase and their adsorption onto a Au(111) surface. J Am Chem Soc. 2002;124:7218–25.

    Article  CAS  Google Scholar 

  31. Rudzinski W, Charmas R, Piasecki W, Thomas F, Vilieras F, Prelot B, et al. Calorimetric effects accompanying ion adsorption at the charged metal oxide/electrolyte interfaces: effects of oxide surface energetic heterogeneity. Langmuir. 1998;14:5210–25.

    Article  CAS  Google Scholar 

  32. Dos Anjos FSC, Vieira EFS, Cestari AR. Interaction of indigo carmine dye with chitosan evaluated by adsorption and thermochemical data. J Colloid Interface Sci. 2002;253:243–6.

    Article  CAS  Google Scholar 

  33. Argun ME, Dursun S, Ozdemir C, Karatas M. Heavy metal adsorption by modified oak sawdust: thermodynamics and kinetics. J Hazard Mater. 2007;141:77–85.

    Article  CAS  Google Scholar 

  34. Aydin H, Buluta Y, Yerlikaya C. Removal of copper (II) from aqueous solution by adsorption onto low-cost adsorbents. J Environ Manag. 2008;87:37–45.

    Article  CAS  Google Scholar 

  35. Trivedi P, Axe L. Modeling Cd and Zn sorption to hydrous metal oxides. Environ Sci Technol. 2000;34:2215–23.

    Article  CAS  Google Scholar 

  36. Alcantara EFC, Faria EA, Rodrigues DV, Evangelista SM, Deoliveira E, Zara LF, et al. Modification of silica gel by attachment of 2-mercaptobenzimidazole for use in removing Hg(II) from aqueous media: a thermodynamic approach. J Colloid Interface Sci. 2007;311:1–7.

    Article  CAS  Google Scholar 

  37. Arakaki LNH, Da Fonseca MG, Da Silva EC, Alves APM, De Sousa KS, Silva ALP. Extraction of Pb(II), Cd(II), and Hg(II) from aqueous solution by nitrogen and thiol functionality grafted to silica gel measured by calorimetry. Thermochim Acta. 2006;450:12–5.

    Article  CAS  Google Scholar 

  38. Vieira EFS, Cestari AR, Oliveira CS, Lima PS, Almeida LE. Thermodynamics of pyrimethamine and sulfadiazine binding to a chitosan derivative. Thermochim Acta. 2007;459:9–11.

    Article  CAS  Google Scholar 

  39. National Environment Comission—CONAMA. Resolution no. 357/2005. Brazilian Environment Ministry, Brasilia, Brazil, 2005 (in Portuguese).

Download references

Acknowledgements

The authors thank FAPDF for financial support and CNPq for fellowships.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Alexandre G. S. Prado.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Prado, A.G.S., Moura, A.O., Andrade, R.D.A. et al. Application of Brazilian sawdust samples for chromium removal from tannery wastewater. J Therm Anal Calorim 99, 681–687 (2010). https://doi.org/10.1007/s10973-009-0284-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-009-0284-0

Keywords

Navigation