Abstract
SrSnO3 was synthesized by the polymeric precursor method with elimination of carbon in oxygen atmosphere at 250 °C for 24 h. The powder precursors were characterized by TG/DTA and high temperature X-ray diffraction (HTXRD). After calcination at 500, 600 and 700 °C for 2 h, samples were evaluated by X-ray diffraction (XRD), infrared spectroscopy (IR) and Rietveld refinement of the XRD patterns for samples calcined at 900, 1,000 and 1,100 °C. During thermal treatment of the powder precursor ester combustion was followed by carbonate decomposition and perovskite crystallization. No phase transition was observed as usually presented in literature for SrSnO3 that had only a rearrangement of SnO6 polyhedra.
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Azad AM, Shyan LLW, Yen PT. Synthesis, processing and microstructural characterization of CaSnO3 and SrSnO3 ceramics. J Alloy Compd. 1999;282:109–24.
Lu Z, Liu J, Tang J, Li Y. Hydrothermal synthesis of CaSnO3 cubes. Inorg Chem Commun. 2004;7:731–3.
Zhang W, Tang J, Ye J. Structural, photocatalytic, and photophysical properties of perovskite MSnO3 (M = Ca, Sr, and Ba) photocatalysts. J Mater Res. 2007;22:1859–71.
Mizoguchi H, Eng HW, Woodward PM. Probing the electronic structures of ternary perovskite and pyrochlore oxides containing Sn4+ or Sb5+. Inorg Chem. 2004;43:1667–80.
Mountstevens EH, Attfield JP, Redfern SAT. Cation-size control of structural phase transitions in tin perovskitas. J Phys. 2003;15:8315–26.
Azad A-M, Hashim M, Baptist S, Badri A, Ul Haq A. Phase evolution and microstructural development in sol-gel derived MSnO3 (M = Ca, Sr and Ba). J Mater Sci. 2000;35:5475–83.
Udawatte CP, Kakihana M, Yoshimura M. Low temperature synthesis of pure SrSnO3 and the (Bax Sr1-x)SnO3 solid solution by the polymerized complex method. Solid State Ion. 2000;128:217–26.
Alves MCF, Souza SC, Lima SJG, Longo E, Souza AG, Santos IMG. Influence of the precursors salts in the synthesis of CaSnO3 by the polymeric precursor method. J Therm Anal Calorim. 2007;87:763–6.
Rietveld HM. A profile refinement method for nuclear and magnetic structures. J Appl Crystallogr. 1969;2:65–71.
Larson AC, Von Dreele RB. GSAS-general structure analysis system. Los Alamos National Laboratory, EUA; 2000.
Finger LW, Cox LW, Jephcoat DE. A correction for powder diffraction peak asymmetry due to axial divergence. J Appl Crystallogr. 1994;27:892–900.
Glerup M, Knight KS, Poulsen FW. High temperature structural phase transitions in SrSnO3 perovskite. Mater Res Bull. 2005;40:507–20.
Nakamoto K. Infrared and Raman spectra of inorganic and coordination compounds. New York: Wiley; 1980.
Nyquist R, Kagel R. Infrared spectra of inorganic compounds. London: Academic Press; 1971.
Licheron M, Jouarf G, Hussona E. Characterization of BaSnO3, powder obtained by a modified sol-gel route. J Eur Ceram Soc. 1997;17:1453.
Vegas A, Vallet-Regý M, González-Calbet JM, Alario-Franco MA. The ASnO3 (A=Ca,Sr) perovskites. Acta Crystallogr B. 1986;42:167–72.
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The authors acknowledge CAPES and CNPq/MCT, PROINFRA/FINEP and CEPID/FAPESP for the financial support.
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Alves, M.C.F., Souza, S.C., Silva, M.R.S. et al. Thermal analysis applied in the crystallization study of SrSnO3 . J Therm Anal Calorim 97, 179–183 (2009). https://doi.org/10.1007/s10973-009-0242-x
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DOI: https://doi.org/10.1007/s10973-009-0242-x