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Thermodynamic analysis of AuIn–Sb system using Oelsen calorimetry and predicting methods

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Abstract

The results of comparative thermodynamic analysis of AuIn–Sb section in ternary Au–In–Sb system are presented in this paper. Investigation was carried out experimentally, using Oelsen calorimetry at the temperature 873 K and analytically, applying different predicting methods––Toop and Muggianu in the temperature interval from 873 K to 1673 K. The values for integral molar Gibbs excess energies and antimony activities have been determined and compared at temperature of 873 K, which indicated to good agreement between experimental results and results obtained using Toop predicting model.

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Acknowledgements

The authors are grateful to the Ministry of Science and Environmental Protection of the Republic of Serbia (Project No. 142043) for financial support.

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Authors and Affiliations

  1. Mining and Metallurgy Institute, Zeleni bulevar 33, 19210, Bor, Serbia

    Lidija Gomidželović

  2. University of Belgrade, Technical Faculty, VJ 12, 19210, Bor, Serbia

    Dragana Živković

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  1. Lidija Gomidželović
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  2. Dragana Živković
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Correspondence to Dragana Živković.

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Gomidželović, L., Živković, D. Thermodynamic analysis of AuIn–Sb system using Oelsen calorimetry and predicting methods. J Therm Anal Calorim 98, 743–748 (2009). https://doi.org/10.1007/s10973-009-0212-3

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  • DOI: https://doi.org/10.1007/s10973-009-0212-3

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