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Effect of separation points on kinetic parameters in pseudo component separated stage model

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Abstract

In pseudo bi-component separated-stage model (PBSM), the effect of the TG value at separation points on the kinetic parameters is studied by residual and theoretical analysis. Simultaneously, a new method to determine the point that is the end of 1st reaction or the initial of 2nd reaction is developed. The investigations have improved the calculation procedure of PBSM. We performed thermogravimetry (TG) analysis on oil tea wood with two-step consecutive model and parallel model. Comparison between the results of the two models and improved PBSM shows well agreements. The influence of different separation points on kinetic parameters is presented.

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Acknowledgements

This research was supported by National Natural Science Foundation of China (Grant No: 50536030) and Program for New Century Excellent Talents in University (NCET-05-0551). The authors deeply appreciate the supports.

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Authors and Affiliations

  1. State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei, Anhui Province, 230026, China

    Jiakun Dai, Lizhong Yang, Yupeng Zhou & Yafei Wang

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  1. Jiakun Dai
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  2. Lizhong Yang
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  3. Yupeng Zhou
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  4. Yafei Wang
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Correspondence to Lizhong Yang.

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Dai, J., Yang, L., Zhou, Y. et al. Effect of separation points on kinetic parameters in pseudo component separated stage model. J Therm Anal Calorim 100, 599–605 (2010). https://doi.org/10.1007/s10973-009-0208-z

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  • DOI: https://doi.org/10.1007/s10973-009-0208-z

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