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Densities and excess molar volumes for mixtures of methanol with other alcohols at temperatures (288.15–313.15 K)

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Abstract

Densities have been measured for the binary mixtures of methanol with ethanol, isomers of propanol and butanol over the entire composition range at 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 K. The density data have been used to calculate the molar volumes, thermal expansion coefficients and their excess values. The excess parameters have been fitted to the Redlich–Kister polynomial equation. The values of the molar volumes, excess molar volumes, thermal expansion coefficients and excess thermal expansion coefficients have been analyzed as a function of the mole fraction and the carbon chain length.

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Acknowledgements

Research sponsored by Polish State Committee for Scientific Research (Grant No 505/241).

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  1. Department of Physical Chemistry of Solutions, University of Łódź, Pomorska 163, 90-236, Łódź, Poland

    Agnieszka Boruń, Małgorzata Żurada & Adam Bald

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  1. Agnieszka Boruń
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  2. Małgorzata Żurada
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  3. Adam Bald
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Correspondence to Adam Bald.

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Boruń, A., Żurada, M. & Bald, A. Densities and excess molar volumes for mixtures of methanol with other alcohols at temperatures (288.15–313.15 K). J Therm Anal Calorim 100, 707–715 (2010). https://doi.org/10.1007/s10973-009-0157-6

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  • DOI: https://doi.org/10.1007/s10973-009-0157-6

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